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    PROCESS FOR THE PREPARATION OF NAPROXENE NITROXYALKYLESTERS
    162.
    发明公开
    PROCESS FOR THE PREPARATION OF NAPROXENE NITROXYALKYLESTERS 有权
    制备NAPROXENE NITROXYALKYLESTERS的方法

    公开(公告)号：EP1200386A1

    公开(公告)日：2002-05-02

    申请号：EP00951456.3

    申请日：2000-07-27

    Applicant: NICOX S.A.

    Inventor： BENEDINI, Francesca ,  OLDANI, Erminio ,  CASTALDI, Graziano ,  TARQUINI, Antonio

    IPC: C07C203/04

    CPC classification number: C07C201/02 ,  C07C203/04

    Abstract: A process for obtaining nitroxyalkylesters of the 2-(S)-(6-methoxy-2-naphthyl)-propanoic acid having an enantiomeric excess higher than or equal to 95 %, preferably higher than or equal to 98 %, characterized in that an halide of the 2-(S)-(6-methoxy-2-naphthyl)-propanoic acid of formula A-Hal, wherein A is the acid acyl residue, is reacted in an inert organic solvent with an aliphatic nitroxyalkanol HO-Y-ONO2, wherein Y is a C2-C20 alkylene or a cycloalkylene from 3 to 8 carbon atoms, or an alkylene as defined containing a cycloalkylene as defined, in the presence of an inorganic base.

    Abstract translation: 一种获得对映体过量高于或等于95％，优选高于或等于98％的2-（S） - （6-甲氧基-2-萘基） - 丙酸的硝酰氧基烷基酯的方法，其特征在于， 其中A是酸性酰基残基的式A-Hal的2-（S） - （6-甲氧基-2-萘基） - 丙酸的卤化物在惰性有机溶剂中与脂肪族硝基氧基烷醇HO-Y- ONO2（其中Y是C2-C20亚烷基或3至8个碳原子的亚环烷基）或含有如所定义的亚环烷基的亚烷基在无机碱存在下反应。

    Method of synthesizing diglycerol tetranitrate, and solid rocket motor propellant containing the same
    163.
    发明公开
    Method of synthesizing diglycerol tetranitrate, and solid rocket motor propellant containing the same 审中-公开
    一种用于制备和Diglyceroltetranitrat固体火箭发动机的推进装置，包括该处理

    公开(公告)号：EP1136468A3

    公开(公告)日：2001-11-14

    申请号：EP01302508.5

    申请日：2001-03-19

    Applicant: Cordant Technologies, Inc.

    Inventor： Sanderson, Andrew ,  Martins, Laura

    IPC: C07C203/04 ,  C06B45/10 ,  C06B25/10

    CPC classification number: C06B25/10 ,  C06B45/105 ,  C07C201/02 ,  C07C203/04

    Abstract: Diglyercol tetranitrate is an energetic nitrate ester plasticizer having no freezing point, making the nitrate ester plasticizer especially suited for use in solid rocket motor propellants that are subjected to low temperature storage and operational environments, which can reach as low as -54°C in temperature. In order to avoid problems associated with fume-off that characterize the conventional synthesis method of making diglycerol tetranitrate, synthesis is performed in a medium including a mixed acid phase and an inert organic phase. The mixed acid phase contains, as ingredients, at least one nitronium ion source and at least one acid having sufficient strength to generate nitronium ions from the nitronium ion source. The nitronium ions in the mixed acid nitrated diglycerol to form diglycerol tetranitrate, which is then received into the organic liquid. The organic liquid, which preferably is a chlorocarbon such as dichloromethane, is insoluble with diglycerol but soluble with diglycerol tetranitrate. The inert organic phase is then treated to neutralize any acid contained in the inert organic phase, and the diglycerol tetranitrate is separated from the inert organic phase.

    Method of synthesizing diglycerol tetranitrate, and solid rocket motor propellant containing the same
    164.
    发明公开
    Method of synthesizing diglycerol tetranitrate, and solid rocket motor propellant containing the same 审中-公开
    一种用于制备和Diglyceroltetranitrat固体火箭发动机的推进装置，包括该处理

    公开(公告)号：EP1136468A2

    公开(公告)日：2001-09-26

    申请号：EP01302508.5

    申请日：2001-03-19

    Applicant: Cordant Technologies, Inc.

    Inventor： Sanderson, Andrew ,  Martins, Laura

    IPC: C07C203/04 ,  C06B45/10 ,  C06B25/10

    CPC classification number: C06B25/10 ,  C06B45/105 ,  C07C201/02 ,  C07C203/04

    Abstract: Diglyercol tetranitrate is an energetic nitrate ester plasticizer having no freezing point, making the nitrate ester plasticizer especially suited for use in solid rocket motor propellants that are subjected to low temperature storage and operational environments, which can reach as low as -54°C in temperature. In order to avoid problems associated with fume-off that characterize the conventional synthesis method of making diglycerol tetranitrate, synthesis is performed in a medium including a mixed acid phase and an inert organic phase. The mixed acid phase contains, as ingredients, at least one nitronium ion source and at least one acid having sufficient strength to generate nitronium ions from the nitronium ion source. The nitronium ions in the mixed acid nitrated diglycerol to form diglycerol tetranitrate, which is then received into the organic liquid. The organic liquid, which preferably is a chlorocarbon such as dichloromethane, is insoluble with diglycerol but soluble with diglycerol tetranitrate. The inert organic phase is then treated to neutralize any acid contained in the inert organic phase, and the diglycerol tetranitrate is separated from the inert organic phase.

    Abstract translation: Diglyercol四硝酸酯是具有高能硝酸盐酯增塑剂没有凝固点，使得硝酸盐酯增塑剂的爱特别适用于固体火箭发动机推进剂使用并经受低温储存和操作环境，它可以达到低至在温度-54°C ， 为了避免与通风断相关联并表征制造二甘油四硝酸酯的常规合成方法的问题，合成在一个介质，包括一个混合酸相和在惰性有机相中进行。 所述混合酸相含有作为成分，至少一种硝离子源和至少一种酸具有足够的强度，以产生从所述硝离子源硝离子。 在混合酸硝化二甘油的硝离子以形成双甘油四硝酸酯，所有其然后接收到有机液体中。 将有机液体，优选其中一个是含氯烃：如二氯甲烷，是不溶于二甘油但具有二甘油四硝酸酯可溶。 然后将惰性有机相进行处理以中和包含在惰性有机相中的任何酸，和二甘油四硝酸酯从惰性有机相分离。

    PROCESS FOR THE PREPARATION OF NITRO COMPOUNDS AND METHOD FOR THE REMOVAL OF NITROGEN DIOXIDE
    165.
    发明公开
    PROCESS FOR THE PREPARATION OF NITRO COMPOUNDS AND METHOD FOR THE REMOVAL OF NITROGEN DIOXIDE 审中-公开
    用于生产硝基化合物和对废水二氧化氮方法

    公开(公告)号：EP1099684A1

    公开(公告)日：2001-05-16

    申请号：EP00927772.4

    申请日：2000-05-16

    Applicant: Daicel Chemical Industries, Ltd.

    Inventor： ISHII, Yasutaka ,  NAKANO, Tatsuya

    IPC: C07C201/06 ,  C07C205/02 ,  C07C205/05 ,  C07C205/06 ,  C07B61/00 ,  B01D53/34 ,  B01D53/56 ,  B01D53/77

    CPC classification number: C07C201/08 ,  B01D53/56 ,  C07B43/02 ,  C07C201/02 ,  C07C2601/14 ,  C07C2601/18 ,  C07C2601/20 ,  C07C2603/74 ,  Y02A50/2345 ,  C07C205/05 ,  C07C205/02 ,  C07C205/06 ,  C07C205/04 ,  C07C205/55 ,  C07C203/08

    Abstract: In the invented process for producing a nitro compound, an organic substrate and nitrogen dioxide are reacted in the presence of oxygen or are reacted in a molar ratio of nitrogen dioxide to the organic substrate of less than 1 to yield a corresponding nitro compound. The reaction may be performed in the presence of N-hydroxyphthalimide or other imide compounds. Such organic substrates include (a) aliphatic hydrocarbons, (b) alicyclic hydrocarbons, (c) non-aromatic heterocyclic compounds each having a carbon atom on a ring, which carbon atom is bonded to a hydrogen atom, (d) compounds each having a carbon-hydrogen bond at the adjacent position to an aromatic ring, and (e) compounds each having a carbon-hydrogen bond at the adjacent position to a carbonyl group. This process can efficiently nitrate an organic substrate even under relatively mild conditions.

    Abstract translation: 在用于制备硝基化合物的有机基板和二氧化氮本发明的方法中反应在氧的存在下或在二氧化氮到小于1的有机底物的摩尔比反应以产生相应的硝基化合物。 该反应可以在N-羟基或其他酰亚胺化合物的存在下进行。 搜索有机基板包括：（a）脂族烃，（b）中脂环族烃，（c）中每一个都具有一个环，其碳原子键合到氢原子上的碳原子的非芳族杂环化合物，（d）化合物每一个都具有 在芳族环，和（e）在邻近位置的碳 - 氢键的化合物每一个具有在相邻的位与羰基的碳 - 氢键。 此过程可以有效硝酸盐有机基材，即使在相对温和的条件。

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