公开(公告)号：US06677047B2

公开(公告)日：2004-01-13

申请号：US09773887

申请日：2001-02-02

Applicant: Kazuyuki Matsumura ,  Masaaki Yamaya ,  Koichi Higuchi ,  Muneo Kudo ,  Yoshifumi Kato ,  Takashi Komori ,  Toshihisa Shimo

Inventor： Kazuyuki Matsumura ,  Masaaki Yamaya ,  Koichi Higuchi ,  Muneo Kudo ,  Yoshifumi Kato ,  Takashi Komori ,  Toshihisa Shimo

IPC: C08G7726

CPC classification number: C09D201/10 ,  C08J7/04 ,  C08J2479/06 ,  C08J2483/00 ,  C09D4/00 ,  C09D5/002 ,  C09D143/04 ,  C09D183/08 ,  Y10T428/31663 ,  C08G77/26 ,  C08F220/14

Abstract: A coating composition comprising the reaction product of a benzotriazole compound having a polymerizable vinyl group and a hydroxyl group with a silane compound and/or a (partial) hydrolyzate thereof is applied to plastic substrates, typically polycarbonate resin substrates to form transparent coatings having improved mar, weather and chemical resistance.

Abstract translation: 将包含具有可聚合乙烯基和羟基的苯并三唑化合物与羟基的反应产物与硅烷化合物和/或其（部分）水解产物组合的涂料组合物施用于塑料基材，通常为聚碳酸酯树脂基材以形成具有改进的马克 ，耐候性和耐化学性。

公开(公告)号：US06541562B1

公开(公告)日：2003-04-01

申请号：US09677882

申请日：2000-10-03

Applicant: Ryuichi Aoki ,  Tadashi Hatakeyama ,  Hiroharu Sasaki ,  Kazuyoshi Tsuneta

Inventor： Ryuichi Aoki ,  Tadashi Hatakeyama ,  Hiroharu Sasaki ,  Kazuyoshi Tsuneta

IPC: C08L8300

CPC classification number: C09D201/10 ,  C09D183/10 ,  C08L2666/44

Abstract: An aqueous paint composition comprising: (i) an aqueous dispersion obtained by neutralizing with a neutralizing agent a hydrolytic condensation reaction product of (a) 100 parts by weight of an organosilane of the formula (1) R1nSi(OR2)4-n, wherein R1 is a C1-8 organic group, R2 is a C1-5 alkyl group, and n is 1 or 2, and/or its partially hydrolyzed condensate, with (b) from 5 to 200 parts by weight of a silyl group-containing vinyl resin having hydrolyzable silyl groups or silyl groups having silicon atoms bonded to hydroxyl groups and having an acid value of from 20 to 150 mgKOH/g, and adding water thereto, (ii) an amino group-containing alkoxysilane compound, and (iii) an epoxy group-containing compound.

Abstract translation: 一种水性涂料组合物，其包含：（i）通过用中和剂中和（a）100重量份式（1）的有机硅烷R 1 n Si（OR 2）4-n的水解缩合反应产物得到的水分散体，其中 R 1为C 1-8有机基团，R 2为C 1-5烷基，n为1或2，和/或其部分水解缩合物，（b）5〜200重量份含甲硅烷基 具有可水解的甲硅烷基的乙烯基树脂或具有与羟基键合的硅原子并具有20〜150mgKOH / g的酸值的甲硅烷基，向其中加入水，（ii）含氨基的烷氧基硅烷化合物，和（iii） 含环氧基的化合物。

公开(公告)号：US20020146573A1

公开(公告)日：2002-10-10

申请号：US10058423

申请日：2002-01-30

Applicant: JSR CORPORATION

Inventor： Mibuko Shimada ,  Nakaatsu Yoshimura ,  Yuichi Hashiguchi

IPC: B32B009/04 ,  C08G077/00

CPC classification number: G03F7/0758 ,  C08L43/04 ,  C09D143/04 ,  C09D201/10 ,  G03F7/0755 ,  G03F7/0757 ,  Y10T428/24388 ,  Y10T428/24405 ,  Y10T428/31663 ,  C08L2666/44

Abstract: A polymer composition containing a specific silyl group-containing polymer, in which the maximum size of particles contained therein is 2 nullm or less, and the number of particles having a size of 0.2 nullm to 2 nullm is 1,000 particles/ml or less. The composition may further contain a specific compound or at least one component selected from an organosilane represented by (R1)nSi(X)4-n, a hydrolyzate of the organosilane and a condensate of the organosilane. The composition is excellent in storage stability, high in hardness and excellent in mechanical strength such as wear resistance, so that a coating film having good taking-up properties even when no lubricant is contained, extremely smooth and having no difference in film thickness can be formed.

Abstract translation: 含有特定含甲硅烷基的聚合物的聚合物组合物，其中包含的颗粒的最大尺寸为2μm或更小，并且具有0.2μm至2μm的尺寸的颗粒的数量为1,000个/ ml或更小。 该组合物还可以含有选自（R 1）n Si（X）4-n表示的有机硅烷，有机硅烷的水解产物和有机硅烷的缩合物中的至少一种成分。 该组合物的保存稳定性，硬度高，耐磨性等机械强度优异，因此即使不含润滑剂也具有良好的卷取性的涂膜，非常光滑，膜厚无差别 形成。

公开(公告)号：US06451930B1

公开(公告)日：2002-09-17

申请号：US09524830

申请日：2000-03-14

Applicant: John W. Burgman ,  David C. Martin ,  Soner Kilic ,  Jane N. Valenta

Inventor： John W. Burgman ,  David C. Martin ,  Soner Kilic ,  Jane N. Valenta

IPC: C08G7718

CPC classification number: C08G18/6295 ,  C09D175/04 ,  C09D201/025 ,  C09D201/10 ,  C08L2666/16

Abstract: A film-forming composition, typically a topcoat, having improved adhesion to certain commercially available adhesives. The composition includes a curable film-forming polymer, typically an acrylic and/or a polyester polymer, with carbamate and/or urea groups. The composition further includes a material containing one or more hydrolyzable silyl groups. The hydrolyzable silyl group-containing material optionally can be a polymeric or oligomeric. Also disclosed are a method of applying the above-described film-forming composition to a substrate and the coated article prepared by such a method.

Abstract translation: 一种成膜组合物，通常为顶涂层，具有改进的粘合性。 该组合物包括具有氨基甲酸酯和/或脲基团的可固化成膜聚合物，通常为丙烯酸和/或聚酯聚合物。 组合物还包含含有一个或多个可水解甲硅烷基的材料。 可水解的含甲硅烷基的材料任选地可以是聚合的或低聚的。 还公开了将上述成膜组合物施用于通过这种方法制备的基材和涂布制品的方法。

公开(公告)号：US20010047056A1

公开(公告)日：2001-11-29

申请号：US09820701

申请日：2001-03-30

Applicant: Kaneka Corporation

Inventor： Toshihiko Okamoto ,  Makoto Chiba ,  Junji Takase

IPC: C08F008/00

CPC classification number: C09J5/02 ,  C08L83/04 ,  C09D201/10 ,  C09J2483/00 ,  Y10T428/31663

Abstract: A primer composition showing good adhesion to the surface of a substrate, such as a glass substrate, and excellent in weather resistance and water resistance as well as a method of effecting adhesion is provided. The primer composition is characterized by comprising a saturated hydrocarbon polymer having at least one silicon-containing group which has hydroxyl or hydrolyzable group bound to the silicon atom and capable of crosslinking under formation of a siloxane bond.

Abstract translation: 提供了对玻璃基板等基板的表面具有良好的粘合性，耐候性和耐水性优异的底漆组合物以及附着的方法。 底漆组合物的特征在于包含具有至少一个含硅基团的饱和烃聚合物，其具有与硅原子结合的羟基或可水解基团，并且能够在形成硅氧烷键的情况下交联。

公开(公告)号：US5977202A

公开(公告)日：1999-11-02

申请号：US935059

申请日：1997-09-22

Applicant: Chander P. Chawla ,  Paul E. Snowwhite ,  Edward P. Zahora

Inventor： Chander P. Chawla ,  Paul E. Snowwhite ,  Edward P. Zahora

IPC: C03C25/10 ,  C08F2/46 ,  C09D201/10

CPC classification number: C03C25/106 ,  C03C25/1065 ,  C09D201/10 ,  Y10T428/2938

Abstract: A radiation-curable composition for use as an optical fiber material or coating comprising the combination of the following pre-mixture ingredients:(A) about 5 wt. % to about 95 wt. % of one or more radiation-curable oligomers,(B) about 5 wt. % to about 95 wt. % of one or more monomer diluents,(C) optionally, one or more photoinitiators,(D) about 0.1 wt. % to about 30 wt. % of one or more adhesion promoters represented by:(R.sup.1 --L).sub.4-X --Si(OR.sup.2).sub.Xwherein R.sup.1 is a group comprising an ethylenically unsaturated radiation-curable group; and said three R.sup.2 groups independently of each other are C.sub.1 -C.sub.10 groups; wherein X=1-3; and L is a linking group which comprises one or more alkoxy or branched propoxy groups.

Abstract translation: 用作光纤材料或涂层的可辐射固化组合物，其包含以下预混合物成分的组合：（A）约5重量％ ％至约95wt。 ％的一种或多种可辐射固化的低聚物，（B）约5wt。 ％至约95wt。 ％的一种或多种单体稀释剂，（C）任选的一种或多种光引发剂，（D）约0.1wt。 ％至约30wt。 ％的一种或多种粘合促进剂由（R1-L）4-X-Si（OR2）X表示，其中R1是包含烯属不饱和辐射固化基团的基团; 并且所述三个R2基彼此独立地为C1-C10基团; 其中X = 1-3; L是包含一个或多个烷氧基或支链丙氧基的连接基团。

公开(公告)号：US5827922A

公开(公告)日：1998-10-27

申请号：US808113

申请日：1997-02-28

Applicant: Ming J. Chen ,  Frederick D. Osterholtz

Inventor： Ming J. Chen ,  Frederick D. Osterholtz

IPC: C08K5/5415 ,  C09D143/04 ,  C09D167/00 ,  C09D201/10 ,  C08L83/00

CPC classification number: C08K5/5415 ,  C09D143/04 ,  C09D167/00 ,  C09D201/10

Abstract: Curable composition comprising a stable, water dispersible, curable polymer containing a sterically hindered alkoxylated silane group at 0.1 to 75 weight percent of the total composition; a water dispersible or water soluble, hydrolytically stable organotin catalyst, at 0.1 to 10 weight percent of the total composition; and water at 99.8 to 24.9 weight percent of the total composition are taught herein. These compositions are useful as adhesives, sealants and paints. The compositions have improved properties including solvent resistance, adhesion, hardness, abrasion resistance and mar resistance. Particular catalysts for use herein include mercaptoalcohol, mercaptide and sulfide forms of diorganotins having either a Sn--S or Sn.dbd.S bond, and include dibutyltin dimercaptide and dibutyltin bis(1-thioglycerol).

Abstract translation: 包含稳定的水分散性可固化聚合物的可固化组合物，其含有占总组合物重量百分比为0.1-75重量％的空间位阻烷氧基化硅烷基团; 水分散或水溶性，水解稳定的有机锡催化剂，占总组合物的0.1至10重量％ 并且在本文中教导了总组合物的99.8至24.9重量％的水。 这些组合物可用作粘合剂，密封剂和油漆。 该组合物具有改进的性能，包括耐溶剂性，粘合性，硬度，耐磨性和耐擦伤性。 用于本文的具体催化剂包括具有Sn-S或Sn = S键的二有机锡的巯基醇，硫醇盐和硫化物形式，并且包括二辛基二锡和二丁基锡双（1-硫代甘油）。

公开(公告)号：US5686523A

公开(公告)日：1997-11-11

申请号：US540142

申请日：1995-10-06

Applicant: Ming J. Chen ,  Frederick D. Osterholtz ,  Eric R. Pohl ,  Antonio Chaves ,  Phil E. Ramadatt

Inventor： Ming J. Chen ,  Frederick D. Osterholtz ,  Eric R. Pohl ,  Antonio Chaves ,  Phil E. Ramadatt

IPC: C08L83/06 ,  C08J3/215 ,  C08J3/24 ,  C08K5/5415 ,  C08L43/04 ,  C08L101/10 ,  C09D143/04 ,  C09D167/00 ,  C09D201/10

CPC classification number: C09D143/04 ,  C08K5/5415 ,  C09D167/00 ,  C09D201/10

Abstract: Stable alkoxy silane containing compositions and methods for the preparation of a stable silane containing compositions comprising: (I) a water insoluble or slightly soluble alkoxy silane; (II) emulsifier; (III) water; and (IV) water dispersible or emulsified polymer containing an alkoxy silane functional group. Also provided are two part systems such that an alkoxy silane emulsion comprising components (I)-(III) are combined and the component (IV) may be added upon use of components (I) to (III). Moreover, additional components, (V), such as catalysts and pH buffers may be added.

Abstract translation: 含有稳定的烷氧基硅烷的组合物和制备含硅烷的组合物的方法，包括：（I）水不溶性或微溶性烷氧基硅烷; （II）乳化剂; （三）水; 和（IV）含有烷氧基硅烷官能团的水分散性或乳化性聚合物。 还提供了两部分系统，使得包含组分（I） - （III）的烷氧基​​硅烷乳液合并，并且组分（IV）可以在使用组分（I）至（III）时加入。 此外，可以加入另外的组分（V），例如催化剂和pH缓冲剂。

公开(公告)号：US5663215A

公开(公告)日：1997-09-02

申请号：US634221

申请日：1996-04-18

Applicant: Brian D. Milligan

Inventor： Brian D. Milligan

IPC: C09D5/16 ,  C09D183/04 ,  C09D201/10 ,  C09D143/04

CPC classification number: C09D183/04 ,  C09D201/10 ,  C09D5/1675 ,  Y10T428/31511 ,  Y10T428/31551 ,  Y10T428/31663

Abstract: A composition suitable for the production of an antifouling coating which comprises: (A) a polymer carrying pendent and/or terminal curable functional groups, at least a major proportion of the repeating units in the polymer (A) being other than siloxane units and (B) a curable organohydrogen polysiloxane or polydiorganosiloxane, the curable functional groups in component (A) being capable of undergoing a condensation curing reaction with component (B). The composition provides antifouling coating having good adhesion and mechanical durability and are used in aquatic or marine environments.

Abstract translation: 一种适于生产防污涂料的组合物，其包括：（A）携带侧链和/或末端可固化官能团的聚合物，聚合物（A）中至少大部分重复单元不是硅氧烷单元和（ B）可固化的有机氢聚硅氧烷或聚二有机硅氧烷，组分（A）中的可固化官能团能够与组分（B）进行缩合固化反应。 该组合物提供具有良好粘附性和机械耐久性的防污涂料，并用于水生或海洋环境中。

公开(公告)号：US5654360A

公开(公告)日：1997-08-05

申请号：US572614

申请日：1995-12-14

Applicant: Peter David Palasz

Inventor： Peter David Palasz

IPC: C09D133/04 ,  C09D133/06 ,  C09D143/04 ,  C09D163/00 ,  C09D167/00 ,  C09D175/00 ,  C09D201/10 ,  C08K5/04 ,  C08K5/05 ,  C08L43/04 ,  C08L63/02

CPC classification number: C09D143/04 ,  C09D133/06 ,  C09D133/068 ,  C09D201/10

Abstract: The invention provides a water-based coating composition in two pack form comprising:i) in a first pack a substantially non-aqueous solution of a silicon-containing polymer which is soluble in water miscible organic solvents and essentially soluble in aqueous media, the silicon groups on the polymer being of formula (1):--SiR.sup.1.sub.a R.sub.3-a (1) in which a is 0 to 2, R.sup.1 is Cl-6 alkyl and R is OH or a hydrolysable group, andii) in a second pack a polymer in dispersion in an aqueous liquid carrier for the composition,where the non-volatile binder solids content of the composition is at least 5% by weight and the molar concentration of silicon in the composition is greater than 0 and less than 0.5.

Abstract translation: 本发明提供了两种包装形式的水性涂料组合物，其包括：i）在第一包装中，基本上是含水聚合物的非水溶液，其可溶于水可混溶的有机溶剂并且基本上可溶于含水介质中，所述硅 聚合物上具有式（1）的基团：-SiR1aR3-a（1）其中a是0-2，R1是C1-6烷基，R是OH或可水解基团，和ii）在第二个包装中，聚合物 在组合物的水性液体载体中分散，其中组合物的非挥发性粘合剂固体含量为至少5重量％，组合物中硅的摩尔浓度大于0且小于0.5。