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    公开(公告)号:KR100396361B1

    公开(公告)日:2003-09-02

    申请号:KR1020007002961

    申请日:1999-07-15

    Abstract: To provide a polyalkylene glycol-based refrigerant oil for refrigerators using ammonia as a refrigerant. The present invention provides a lubricant for refrigerators using ammonia refrigerant, comprising polyethers serected from the group consisting of a polyether represented by the following general formula (1) X-ä-O-(AO)n-Hüp (wherein X is a residue of a monool or polyol from which a hydroxyl group is eliminated; (AO)n is a polyoxyalkylene group formed by copolymerization of EO and an AO having 3 or more carbon atoms; n is 2 or more; and p is a valence of X) and having 50% or more of secondary hydroxyl groups among the hydroxyl groups located at the terminal of the structure based on the total hydroxyl groups, or a polyether represented by the following general formula (2) X-ä-O-(AO )a-(AO )b-Hüp (wherein X is a residue of a monool or polyol from which a hydroxyl group is eliminated; (AO )n is a polyoxyalkylene group formed by copolymerization of ethylene oxide and propylene oxide and/or butylene oxide; AO is an oxyalkylene group having 3 or more carbon atoms; a is 2 or more; b is 1 or more; and p is a valence of X).

    Abstract translation: 本发明提供一种使用氨作为制冷剂的冰箱用聚亚烷基二醇类冷冻机油。 本发明提供一种使用氨制冷剂的冰箱用润滑剂,其包含由下列通式(1)表示的聚醚构成的组中选出的聚醚:-O-(AO)n -H uuml; p(其中X是 (AO)n是由EO与碳原子数3以上的AO共聚而成的聚氧化烯基,n为2以上,p为 (2)表示的聚醚,或者以下述通式(2)表示的聚醚中的一种或两种以上,且位于结构末端的羟基中的羟基的50%以上具有仲羟基, (AO 1)a - (AO 2)b -H uu1 p(其中X是从中除去羟基的一元醇或多元醇的残基;(AO 1)n是由以下物质形成的聚氧化烯基团: 环氧乙烷和环氧丙烷和/或环氧丁烷的共聚; AO 2是氧化烯基团havi ng 3个或更多个碳原子; a是2或更多; b是1以上; 和p是X的化合价)。

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