PROCESS FOR THE PREPARATION OF CYCLOHEXANONE OXIME

    公开(公告)号:PT65812B

    公开(公告)日:1978-05-12

    申请号:PT6581276

    申请日:1976-11-09

    Applicant: ALLIED CHEM

    Abstract: This invention relates to a process for the production of cyclohexanone oxime by reacting cyclohexanone with excess aqueous hydroxylamine in the presence of excess ammonia. More specifically, the invention relates to improving yields of the oxime while reducing undesirable by-product formation by use of two or more stages of reaction with correlated adjustment of reaction conditions in each stage. The invention also involves improved recovery of the unreacted hydroxylamine reactant for recycle in the process.

    PROCESS FOR THE PREPARATION OF CYCLOHEXANONE OXIME

    公开(公告)号:PT65812A

    公开(公告)日:1976-12-01

    申请号:PT6581276

    申请日:1976-11-09

    Applicant: ALLIED CHEM

    Abstract: This invention relates to a process for the production of cyclohexanone oxime by reacting cyclohexanone with excess aqueous hydroxylamine in the presence of excess ammonia. More specifically, the invention relates to improving yields of the oxime while reducing undesirable by-product formation by use of two or more stages of reaction with correlated adjustment of reaction conditions in each stage. The invention also involves improved recovery of the unreacted hydroxylamine reactant for recycle in the process.

    164.
    发明专利
    未知

    公开(公告)号:DE2135085B2

    公开(公告)日:1976-07-22

    申请号:DE2135085

    申请日:1971-07-14

    Abstract: Caprolactam is recovered from a mixture which contains caprolactam and oligomers of the same by distillation at temperatures above the melting point of the oligomers or mixture thereof contained in the residue at atmospheric or slightly increased pressure. The process is of importance for removing residues of caprolactam oligomer residues and thus for effluent pollution control.

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