Fluorinated ether compound, fluorinated ether composition, coating liquid and article

    公开(公告)号:US10550288B2

    公开(公告)日:2020-02-04

    申请号:US15877489

    申请日:2018-01-23

    Applicant: AGC Inc.

    Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1-Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.

    Method of forming antifouling coating film
    165.
    发明授权
    Method of forming antifouling coating film 有权
    形成防污涂膜的方法

    公开(公告)号:US08936854B2

    公开(公告)日:2015-01-20

    申请号:US13576865

    申请日:2011-06-14

    Abstract: Provided is a method of forming an antifouling coating film including the steps of [1] preparing a colored antifouling paint containing a prescribed Si-containing hydrolyzable resin and a color pigment such that a coating film having a target dry film thickness T completely hides a surface of an object to be coated, the colored antifouling paint has a color difference ΔE1 between the coating film having the thickness T and a coating film having a dry film thickness of 0.8 T, at least 2.0, and preferably the colored antifouling paint has a color difference ΔE2 between the coating film having the thickness T and a coating film having a dry film thickness of 1.2 T, less than 1, and [2] coating a surface of the object with the colored antifouling paint until the surface of the object is completely hidden by the coating film formed from the colored antifouling paint.

    Abstract translation: 提供一种形成防污涂膜的方法,包括以下步骤:[1]制备含有规定的含Si水解性树脂和着色颜料的着色防污涂料,使得具有目标干膜厚度T的涂膜完全隐藏表面 被涂物的颜色防污涂料具有厚度T的涂膜与干膜厚度为0.8T,至少为2.0的涂膜之间的色差&Dgr; E1,优选着色防污涂料具有 具有厚度T的涂膜和干膜厚度为1.2T,小于1的涂膜之间的色差&Dgr; E2,和[2]用着色防污漆涂覆物体的表面直到表面 该物体被由着色防污涂料形成的涂膜完全隐藏。

    Curable resin composition for use in water based paint
    168.
    发明授权
    Curable resin composition for use in water based paint 失效
    用于水性涂料的可固化树脂组合物

    公开(公告)号:US06072000A

    公开(公告)日:2000-06-06

    申请号:US661012

    申请日:1996-06-10

    CPC classification number: C09D133/062 C09D139/08

    Abstract: The present invention proposes highly practical curable resin compositions for use in water based paints, which contain no, or much less organic solvent when compared with current organic solvent based paints, and which produce painted surfaces which have excellent curability and weather resistant properties, as well as excellent resistance to solvents, chemicals and water. These curable resin compositions include a compound combining both epoxy and hydrolyzable silyl groups, and a water based product obtained by dispersing or dissolving in water, a tertiary amino vinyl polymer, a vinyl polymer containing both tertiary amino and acidic groups, or an acidic vinyl polymer, which has been either partially or completely neutralized by an acidic or basic compound.

    Abstract translation: 本发明提出了用于水性涂料的高度实用的可固化树脂组合物,其与当前的有机溶剂基涂料相比不含或少得多的有机溶剂,并且产生具有优异的固化性和耐候性的涂漆表面 作为优异的耐溶剂,化学品和水。 这些可固化树脂组合物包括结合环氧和可水解甲硅烷基的化合物,以及通过分散或溶解在水中获得的水基产物,叔氨基乙烯基聚合物,含有叔氨基和酸性基团的乙烯基聚合物,或酸性乙烯基聚合物 ,其已经被酸性或碱性化合物部分或完全中和。

    Aqueous silylated polymer curable compositions
    170.
    发明授权
    Aqueous silylated polymer curable compositions 失效
    水性甲硅烷基化聚合物可固化组合物

    公开(公告)号:US5621038A

    公开(公告)日:1997-04-15

    申请号:US452163

    申请日:1995-05-26

    CPC classification number: C09D167/00 C08K5/5415 C09D143/04 C09D201/10

    Abstract: Curable composition comprising a stable, water dispersible, curable polymer containing a sterically hindered alkoxylated silane group at 0.1 to 75 weight percent of the total composition; a water dispersible or water soluble, hydrolytically stable organometallic catalyst, at 0.1 to 10 weight percent of the total composition; and water at 99.8 to 24.9 weight percent of the total composition are taught herein. These compositions are useful as adhesives, sealants and paints. The compositions have improved properties including solvent resistance, adhesion, hardness, abrasion resistance and mar resistance.Particular catalysts for use herein include dihydroxy bis [2-hydroxypropanato (2-)-O.sup.1,O.sup.2 ] titanate, mixed titanium ortho ester complexes, acetylacetonate chelate, bis(ethyl-3-oxobutanolato-O.sup.1,O.sup.3) bis(2-propanolato) titanium, alkanolamine complex of titanium and mercaptoalcohol, mercaptide or sulfide forms of diorganotins having either a Sn--S or Sn.dbd.S bond.

    Abstract translation: 包含稳定的水分散性可固化聚合物的可固化组合物,其含有占总组合物重量百分比为0.1-75重量%的空间位阻烷氧基化硅烷基团; 水分散或水溶性,水解稳定的有机金属催化剂,占总组合物的0.1至10重量% 并且在本文中教导了总组合物的99.8至24.9重量%的水。 这些组合物可用作粘合剂,密封剂和油漆。 该组合物具有改进的性能,包括耐溶剂性,粘合性,硬度,耐磨性和耐擦伤性。 用于本文的具体催化剂包括二羟基双[2-羟基丙酸酯(2 - ) - O1,O 2]钛酸酯,混合钛原酸酯络合物,乙酰丙酮化合物螯合物,双(乙基-3-氧代丁醇酰-O1,O3)双(2-丙醇) 钛,巯基醇的链烷醇胺络合物,硫醇盐或硫化物形式的具有Sn-S或Sn = S键的二有机锡。

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