Abstract:
Golf ball comprising a non-dissolvable layer having a spherical outer surface; and a dissolvable tie layer or dissolvable layer, dispersible in water heated to a heating temperature of about 80° C.-90° C. or greater, disposed concentrically about the spherical outer surface and being bonded with the first non-dissolvable layer at an interface there between. The dissolvable tie layer/dissolvable layer may be formed from a composition consisting of a 1-50 percent aqueous mono-valent high acid ionomer dispersion, or, from an ionomer resin composition. The ionomer of either composition has an acid level greater than 18%; has more than 45% of acid groups that are neutralized with a monovalent cation; and is formed from an acid copolymer having a starting melt index of greater than 180 g/10 min. @ 190° C. with a 2160 g load. The dissolvable tie layer/dissolvable layer may have a thickness of less than about 0.010 inches, and up to about 0.090 inches in some embodiments.
Abstract:
A golf ball includes a thermoplastic HNP inner core layer having a center hardness less than the surface hardness to define a positive hardness gradient. An outer core layer is disposed about the inner core and is formed from a thermoset rubber composition. The core layer has an inner surface hardness less than the outer surface hardness to define a positive hardness gradient. Inner and outer cover layers are disposed about the outer core layer. The HNP composition includes an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid; a non-acid polymer comprising polyolefins, polyamides, polyesters, polyethers, polyurethanes, metallocene-catalyzed polymers, single-site catalyst polymerized polymers, ethylene propylene rubber, ethylene propylene diene rubber, styrenic block copolymer rubbers, alkyl acrylate rubbers, or functionalized derivatives thereof; an organic acid or salt thereof; and a cation source in an amount sufficient to neutralize at least about 80% of the acid groups.
Abstract:
Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The outer core layer is preferably formed from a non-foamed thermoset composition such as polybutadiene rubber. The core layers have different hardness and specific gravity levels. The specific gravity (density) of the foam inner core is preferably less than the density of the outer core layer. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency.
Abstract:
Multi-layered golf balls containing a two or three-layered core assembly are provided. In one embodiment, the core assembly includes an inner core (center) comprising a thermoset composition, an intermediate core layer; and surrounding outer core layer. Preferably, the thermoplastic composition comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. A second thermoset composition such as polybutadiene rubber may be used to form the outer core layer. The core layers have different hardness levels. In another embodiment, a two-layered core structure is provided. For example, the inner core and/or outer core layer may be made of the plasticized thermoplastic composition. The core structure and resulting ball have relatively good resiliency at given compressions.
Abstract:
Multi-layered golf balls having at least one layer made of polyamide/acid anhydride-modified polyolefin blended compositions are provided. Preferably, a transparent polyamide is used. In one version, the composition comprises a blend of polyamide, acid anhydride-modified polyolefin, and plasticizer. The golf ball includes a core having at least one layer and a cover having at least one layer. The polyamide/acid anhydride-modified polyolefin composition may be used to form any core, cover, or other layer in the golf ball. In one version, the polyamide/acid anhydride-modified polyolefin composition is used to form the outer core layer, and a rubber composition is used to form the inner core.
Abstract:
Golf balls having a solid multi-layered core and a cover are provided. The ball contains an inner core made of a foam composition, an intermediate core layer, and surrounding outer core layer. Preferably, foamed polyurethane is used to form the inner core and polybutadiene rubber is used to make the intermediate and outer cores. The specific gravity (density) of the inner core is preferably less than the density of the intermediate core, which is less than the outer core. The outer surface of the inner core preferably has a non-uniform structure and includes projecting members. The ball preferably has a high Moment of Inertia (MOI). The ball includes a single or multi-layered cover surrounding the core assembly.
Abstract:
A golf ball includes a core and a three-layer cover disposed adjacent the core. The three-layer cover includes an inner cover, an intermediate cover, and an outer cover. The inner cover includes a non-ionomeric E/Y copolymer where E is an olefin and Y is a carboxylic acid. The inner cover has a hardness of about 45 to 68 Shore D. The outer cover includes a castable thermoset polyurethane and has a hardness of about 40 to 62 Shore D. The intermediate cover layer, disposed between the inner and outer cover layers, is formed from a polyester composition including about 40 wt % to about 99 wt % of a polyester thermoplastic elastomer and about 1 wt % to about 60 wt % of a plasticizer.
Abstract:
Multi-layered golf balls having at least one layer made of a polyamide composition containing a transparent polyamide polymer are provided. The transparent polyamide may be blended with other transparent or non-transparent polyamides. Thermoplastic polyamide elastomers such as polyether-amide block copolymers may be used. In one version, the composition comprises a blend of transparent polyamide, acid anhydride-modified polyolefin, and plasticizer. The golf ball includes a core having at least one layer and a cover having at least one layer. The polyamide composition may be used to form any core, cover, or other layer in the golf ball. In one version, the polyamide composition is used to form the inner cover layer.
Abstract:
Golf balls consisting of a multi-layer core and a cover are disclosed. The multi-layer core comprises at least one intermediate core layer formed from a thermoset composition other than diene rubber.
Abstract:
The present invention generally relates to golf balls and more particularly to golf balls having multi-layered cores comprising a thermoset rubber center, a thermoplastic intermediate core layer, and a thermoset rubber outer core layer. A cover layer is disposed about the multi-layered core. At least one of the center, intermediate core layer, and outer core layer comprises a polyalkenamer rubber. In one preferred embodiment, the center, intermediate core, and outer core layers have positive hardness gradients. The core layers preferably have different specific gravities. The polyalkenamer rubber may be blended with other rubbers such as polybutadiene, polyisoprene, ethylene propylene diene, and styrene-butadiene rubbers. The polyalkenamer rubber composition helps improve resiliency of the core and provides the ball with a comfortable and soft feel.