PHENYLESSIGSÄUREDERIVATE, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ALS SCHÄDLINGSBEKÄMPFUNGSMITTEL UND FUNGIZIDE
    172.
    发明授权
    PHENYLESSIGSÄUREDERIVATE, VERFAHREN ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG ALS SCHÄDLINGSBEKÄMPFUNGSMITTEL UND FUNGIZIDE 失效
    苯乙酸衍生物,其制造方法相同,并且它们作为杀虫剂和杀菌剂

    公开(公告)号:EP0876334B1

    公开(公告)日:2000-08-23

    申请号:EP96934490.2

    申请日:1996-09-30

    CPC classification number: C07D213/53 A01N37/50 C07C251/88 C07D261/08

    Abstract: The invention concerns phenylacetic acid derivatives of formula (I) in which the substituents and the indices have the following meanings: X denotes NOCH3, CHOCH3 and CHCH3; Y denotes oxygen or NRa; Ra denotes hydrogen or alkyl; R denotes cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m stands for 0, 1 or 2, wherein the rests R can be different if m is 2; R1 denotes hydrogen or alkyl; R?2 and R3¿, independently of each other, denote hydrogen, cyano, nitro, hydroxy, amino, halogen, optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino and N-hetaryl-N-alkylamino; R4 denotes one of the groups mentioned in the case of R2 or a CRd=NORe group; Rd denotes one of the groups mentioned in the case of R?2; and Re¿ denotes hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, alkylsulphonyl, aryl, arylcarbonyl, arylsulphonyl, hetaryl, hetarylcarbonyl or hetarylsulphonyl. The invention also concerns their salts, a process for the preparation of these substances and their use.

    IMINOOXYPHENYLESSIGSÄUREDERIVATE, VERFAHREN UND ZWISCHENPRODUKTE ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG
    173.
    发明公开
    IMINOOXYPHENYLESSIGSÄUREDERIVATE, VERFAHREN UND ZWISCHENPRODUKTE ZU IHRER HERSTELLUNG UND IHRE VERWENDUNG 失效
    IMINOOXYPHENYLESSIGSÄUREDERIVATE,工艺和中间产品和使用

    公开(公告)号:EP1019366A1

    公开(公告)日:2000-07-19

    申请号:EP96943969.4

    申请日:1996-12-16

    CPC classification number: C07C251/60 C07C2601/10 C07C2601/14

    Abstract: The invention relates to 2-imino oxyphenyl acetic acid derivatives of formula (I) in which the substituents and the index have the following meanings: R1 is C(CO¿2?CH3)=NOCH3 (Ia), C(CONHCH3)=NOCH3 (Ib), C(CONH2)=NOCH3 (Ic), C(CO2CH3)=CHOCH3 (Id), or C(CO2CH3)=CHCH3 (Ie); R?2¿ is cyano, nitro, halogen, alkyl, alkyl halide or alkoxy; m is 0,1 or 2; R3 is hydrogen, cyano, hydroxy, halogen, alkyl, alkyl halide, alkoxy alkyl, alkoxy, alkoxy halide, alkylthio, cyclopropyl, alkenyl, optionally substituted aryloxy alkyl, benzyl or benzyloxy; R4 is hydrogen, cyano, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, heterocyclyl, aryl and hetaryl, optionally substituted alkoxy, alkenyloxy, alkinyloxy, cycloalkoxy, heterocyclyloxy, aryloxy and hetaryloxy, optionally substituted arylthio and hetarylthio; -Q-C(R?5)=N-Y1-R6¿ or -Q-O-N=CR?7R8; R3 and R4¿ together with the carbon atom to which they are bound, are an optionally substituted four to eight-membered ring which can contain in addition to carbon atoms one or two oxygen atoms and/or sulphur atoms and/or NH- and/or N(C¿1?-C4-alkyl)groups; wherein R?3 and R4¿ are not simultaneously bound via heteroatoms to the carbon atom. The invention also relates to the salts of said derivatives, methods and intermediates for their preparation and use thereof.

    Abstract translation: 本发明涉及式(I),其中取代基和指数具有以下含义的2-亚氨基氧苯基乙酸衍生物:R t <1>是C(CO2CH3)= NOCH 3(Ia)中,C(CONHCH 3)= NOCH 3( Ib)中,C(CONH 2)= NOCH 3(Ic)中,C(CO2CH3)= CHOCH 3(Id)的,或C(CO2CH3)= CHCH3(IE); [R <2>是氰基,硝基,卤素,烷基,烷基卤或烷氧基; m是0,1或2; [R <3>为氢,氰基,羟基,卤素,烷基,烷基卤化物,烷氧基烷基,烷氧基,烷氧基卤化物,烷硫基,环丙基,烯基,任选substituiertem芳氧基烷基,苄基或苄氧基; [R <4>为氢,氰基,任选substituiertem烷基,烯基,炔基,环烷基,杂环基,芳基和杂芳基,任选substituiertem烷氧基,烯氧基,炔氧基,环烷氧基,杂环氧基,芳氧基和杂芳氧基,任选substituiertem芳硫基和杂芳硫基; -Q-C(R <5>)= N-Y <1> -R <6>或-Q-O-N = CR <7> - [R <8>; [R <3>和R <4>的碳原子一起与它们所结合的,是在OPTIONALLY substituiertem 4到8元环,其可以在除碳原子的一个或两个氧原子和/或硫原子和包含/ 或NH和/或N(C1-C4烷基)基团; worin - [R <3>和R <4>不通过杂原子与碳原子同时结合。 因此,本发明涉及的所述衍生物,方法和中间体及其制备和使用它们的盐。

    NEUE 1-AMINO-3-BENZYLURACILE
    174.
    发明公开

    公开(公告)号:EP0971904A1

    公开(公告)日:2000-01-19

    申请号:EP98916984.2

    申请日:1998-03-18

    CPC classification number: C07D239/54 A01N43/54 C07C281/02 C07C281/06

    Abstract: The invention relates to benzyl uracils of formula (I) wherein R1 represents H, halogen, CH¿3?; R?2 and R3¿ represent H, CN, SCN, halogen, C¿1?-C4-halogen alkyl, C1-C4-halogen alkoxy, C1-C4-halogen alkylthio; R?4¿ represents R3 + C1-C4-alkyl, C1-C4-alkoxy, C1-C6-alkyl-NH-CO-; R5 represents C¿1?-C4 alkyls bonded via O or S at position α or β, carrying a group -C(=NOR?7)-R8, R7¿ having the same meaning as R?20 and R8¿ representing H, C¿1?-C3-alkyl, optionally substituted CHO, COOH, COSH or amino carbonyl; and R?6¿ in position α or β, and their salts. The invention also relates to a method for producing the benzyl uracils and to their use as herbicides and/or for desiccating/defoliating plants.

    Abstract translation: 本发明涉及式(I)的苄基尿嘧啶,其中R 1表示H,卤素,CH 3。 R 2和R 3代表H,CN,SCN,卤素,C 1 -C 4卤代烷基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基; R 4'代表R 3 + C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 6烷基-NH-CO-; R5代表在α或β位通过O或S键合的C 1 -C 4烷基,其带有与R 20相同含义的基团-C(= NOR 7)-R 8,R 7和代表H的R 8' C 1 -C 3烷基,任选取代的CHO,COOH,COSH或氨基羰基; 和α或β位的R 6和它们的盐。 本发明还涉及生产苄基尿嘧啶的方法,以及它们作为除草剂和/或用于干燥/脱叶植物的用途。

    SUBSTITUIERTE 2-BENZOYL-CYCLOHEXAN-1,3-DIONE MIT HERBIZIDER WIRKUNG
    177.
    发明公开
    SUBSTITUIERTE 2-BENZOYL-CYCLOHEXAN-1,3-DIONE MIT HERBIZIDER WIRKUNG 失效
    替代二-2-苯甲酰基环己烷-1,3二酮麻醉剂治疗剂WIRKUNG

    公开(公告)号:EP0958276A1

    公开(公告)日:1999-11-24

    申请号:EP97953895.0

    申请日:1997-12-19

    Abstract: The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR?5, -OCOR6¿, -OSO¿2R?6, -SH, -S(O)¿n?R?7, -SO¿2OR5, -SO2NR?5R8, -NR8SO¿2R?6 or -NR8COR6; R3¿ stands for hydrogen, cyano, alkyl, halogen alkyl, -OR?7, -SR7 or -NR7R10; R4¿ stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R?9, -COSR9¿ or -CONR8R9; X stands for oxygen or NR8; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for an optionally substituted cyclohexan-1,3-dione ring linked in position 2. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

    Abstract translation: 本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮,其中R1,R2各自为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基,-OR5,-OCOR6,-OSO2R6, -SH,-S(O)nR7,-SO2OR5,-SO2NR5R8,-NR8SO2R6或-NR8COR6; R3是氢,氰基,烷基,卤代烷基,-OR7,-SR7或-NR7R10; R4是氢,取代或未取代的烷基, 环烷基,烯基,环烯基,炔基,-COR 9,-CO 2 R 9,-COSR 9或-CONR 8 R 9; X是氧或NR 8; n是0,1或2; R 5是氢,烷基,卤代烷基,烷氧基烷基,烯基或炔基; 烷基或卤代烷基; R 7是烷基,卤代烷基,烷氧基烷基,烯基或炔基; R 8是氢或烷基; R 9是烷基,烯基,炔基,苯基或苄基; R 10是烷基,卤代烷基,链烯基或炔基; Q是环己烷-1 具有或不具有取代基的2-二酮环,其位置2;及其农业上有用的盐;制备式I化合物的方法和中间体; 包含它们的组合物; 以及使用这些衍生物或包含它们的组合物来控制不期望的植物。

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