公开(公告)号：WO2007142641A1

公开(公告)日：2007-12-13

申请号：PCT/US2006/022181

申请日：2006-06-06

Applicant: QUANTUM GROUP INC. ,  GOLDSTEIN, Mark, K. ,  OUM, Michelle, Sunly

Inventor： GOLDSTEIN, Mark, K. ,  OUM, Michelle, Sunly

IPC: B01J23/89 ,  B01J31/02 ,  B01D53/62 ,  G01N31/22

CPC classification number: B01J23/8993 ,  B01D53/864 ,  B01D53/885 ,  B01D2255/20761 ,  B01D2257/502 ,  B01J31/0201 ,  B01J31/065

Abstract: The present invention provides an apparatus and method for removing CO gas from gas streams or static air. One application of interest in removing CO from air to provide clean air to breathe or other application such as CO monitoring instruments for calibration, to the air side of the fuel cell and to the reformate stream that is employed for a PEM fuel cell. This invention protects the fuel cell catalyst by a means to controlling CO in the reformate stream. The control system is designed to minimize the CO concentration using the novel CO oxidation catalysts described above. One preferred embodiment catalyzes and monitors the CO to indicate the effectiveness; and further comprising two alternate chambers containing catalyst, which is made of high surface area substrate with supramolecular chemistry coated onto that substrate. These supramolecular catalyst converts CO gas to CO2 and at least one CO sensor monitors each catalyst chamber and control the process to maximize the fuel cell efficiency or to trigger a signal for service. Many other applications to reduce CO in static air as well as in gas stream are feasible including ultra zero air for CO measuring instruments, diving air, ultra-high purity laboratory air and air cleaners and air purifiers designed to reduce health impact to people in homes, hotels, health facilities, transportation systems, workplaces and in other enclosed structures.

Abstract translation: 本发明提供一种从气流或静电空气中除去CO气体的装置和方法。 感兴趣的一种应用是从空气中除去CO以提供清洁空气呼吸或其它应用，例如用于校准的CO监测仪器，燃料电池的空气侧和用于PEM燃料电池的重整产品流。 本发明通过控制重整产品流中的CO的手段来保护燃料电池催化剂。 控制系统设计成使用上述新型CO氧化催化剂使CO浓度最小化。 一个优选实施例催化和监测CO以指示有效性; 并且还包括两个包含催化剂的交替室，所述催化剂由涂覆在该基材上的超分子化学物质的高表面积底物制成。 这些超分子催化剂将CO气体转化为CO 2，并且至少一个CO传感器监测每个催化剂室并控制该过程以最大化燃料电池效率或触发服务信号。 用于减少静电空气和气流中CO的许多其他应用是可行的，包括用于CO测量仪器的超零空气，潜水空气，超高纯度实验室空气和空气净化器以及旨在减少对家庭健康的影响的空气净化器 ，酒店，保健设施，交通系统，工作场所和其他封闭结构。

公开(公告)号：WO2007074804A1

公开(公告)日：2007-07-05

申请号：PCT/JP2006/325854

申请日：2006-12-26

Applicant: 三菱レイヨン株式会社 ,  姫野 嘉之 ,  大谷内 健 ,  安川 隼也

Inventor： 姫野 嘉之 ,  大谷内 健 ,  安川 隼也

IPC: B01J23/44 ,  B01J37/16 ,  C07B61/00 ,  C07C51/235 ,  C07C51/25 ,  C07C57/045

CPC classification number: B01J37/16 ,  B01J23/002 ,  B01J23/44 ,  B01J27/0576 ,  B01J31/0201 ,  B01J35/1019 ,  B01J35/1042 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/64 ,  B01J2523/828

Abstract: Disclosed is a palladium-containing catalyst for producing an a,ß-unsaturated carboxylic acid from an olefin or an a,ß-unsaturated aldehyde with high productivity. Also disclosed are a method for producing such a catalyst, and a method for producing an a,ß-unsaturated carboxylic acid with high productivity. Specifically, a palladium-containing catalyst is produced by a method which has a step wherein palladium in the oxidation state is reduced by a compound (A) represented by the following formula (1).

Abstract translation: 公开了一种用于以高生产率从烯烃或α，β-不饱和醛生产α，β-不饱和羧酸的含钯催化剂。 还公开了这种催化剂的制造方法，以及高生产率的β-不饱和羧酸的制造方法。 具体而言，通过具有以下述式（1）所示的化合物（A）将氧化态的钯还原的方法制造含钯催化剂。

公开(公告)号：WO2007043062A1

公开(公告)日：2007-04-19

申请号：PCT/IN2006/000393

申请日：2006-10-03

Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH

Inventor： SRINIVAS, Darbha ,  SRIVASTAVA, Rajendra ,  RATNASAMY, Paul

IPC: B01J27/26 ,  C11C3/10 ,  C10G3/00 ,  C07C68/06

CPC classification number: C07C68/065 ,  B01J27/26 ,  B01J31/0201 ,  C07C67/03 ,  C11C3/003 ,  Y02P30/20 ,  C07C69/52 ,  C07C69/24 ,  C07C69/96

Abstract: The present invention provides a novel transesterification catalyst having the general formula: Zn 3 M 2 (CN) n (ROH).xZnCl 2 .yH 2 O wherein R is tertiary-butyl and M is a transition metal ion selected from Fe, Co and Cr, x varies from O to 0.5, y varies from 3-5 and n is 10 or 12. The above said catalyst is useful for an efficient transesterification of glycerides, fatty acid esters and cyclic carbonates on reactions with alcohols.

Abstract translation: 本发明提供了一种新型的酯交换催化剂，其具有以下通式：Zn 3 N（CN）n（ROH）xZnCl < 2其中R是叔丁基，M是选自Fe，Co和Cr的过渡金属离子，x从0变化到0.5，y从3-5变化 并且n为10或12.上述催化剂可用于甘油酯，脂肪酸酯和环状碳酸酯与醇反应的有效酯交换。

公开(公告)号：WO2005072868A1

公开(公告)日：2005-08-11

申请号：PCT/US2005/000306

申请日：2005-01-05

Applicant: UNIVERSITY OF CHICAGO ,  JAPAN SCIENCE AND TECHNOLOGY AGENCY ,  YAMAMOTO, Hisashi ,  BASAK, Arindrajit ,  ZHANG, Wei

Inventor： YAMAMOTO, Hisashi ,  BASAK, Arindrajit ,  ZHANG, Wei

IPC: B01J31/18

CPC classification number: C07D303/14 ,  B01J31/006 ,  B01J31/0201 ,  B01J31/2213 ,  B01J31/2226 ,  B01J31/2234 ,  B01J2231/70 ,  B01J2231/72 ,  B01J2531/0266 ,  B01J2531/56 ,  B01J2531/64 ,  B01J2540/34 ,  C07D301/14

Abstract: The present invention relates to the synthesis of chiral epoxides via a catalytic asymmetric oxidation of olefins. Additionally, the methodology provides a method of asymmetrically oxidizing sulfides and phosphines. This asymmetric oxidation employs a catalyst system composed of a metal and a chiral bishydroxamic acid ligand, which, in the presence of a stoichiometric oxidation reagent, serves to asymmetrically oxidize a variety of substrates.

Abstract translation: 本发明涉及通过烯烃的催化不对称氧化合成手性环氧化物。 另外，该方法提供了一种不对称氧化硫化物和膦的方法。 这种不对称氧化采用由金属和手性双硅氧酸配体组成的催化剂体系，其在化学计量氧化试剂的存在下用于不对称地氧化各种底物。

公开(公告)号：WO2005035691A1

公开(公告)日：2005-04-21

申请号：PCT/EP2004/010982

申请日：2004-09-30

Applicant: ALBEMARLE NETHERLANDS B.V. ,  NIPPON KETJEN CO., LTD. ,  JANSEN, Marcel, Adriaan ,  VAN HOUTERT, Franciscus, Wilhelmus ,  ADO, Toshiyuki ,  KAMO, Tetsuro ,  NISHIMOTO, Naohiro

Inventor： JANSEN, Marcel, Adriaan ,  VAN HOUTERT, Franciscus, Wilhelmus ,  ADO, Toshiyuki ,  KAMO, Tetsuro ,  NISHIMOTO, Naohiro

IPC: C10G45/08

CPC classification number: B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/94 ,  B01J31/0201 ,  B01J37/0203 ,  B01J38/52 ,  B01J38/60 ,  B01J38/62 ,  C10G45/08 ,  C10G2300/703

Abstract: The invention pertains to a process for activating an hydrotreating catalyst comprising a Group VIB metal oxide and a Group VIII metal oxide which process comprises contacting the catalyst with an acid and an organic additive which has a boiling point in the range of 80-500 °C and a solubility in water of at least 5 grams per liter (20 °C, atmospheric pressure), optionally followed by drying under such conditions that at least 50% of the additive is maintained in the catalyst. The hydrotreating catalyst may be a fresh hydrotreating catalyst or a used hydrotreating catalyst which has been regenerated.

Abstract translation: 本发明涉及一种活化加氢处理催化剂的方法，该催化剂包含VIB族金属氧化物和VIII族金属氧化物，该方法包括使催化剂与沸点在80-500℃范围内的酸和有机添加剂接触 和在水中的溶解度至少为5克/升（20℃，大气压）），任选地在使至少50％的添加剂保持在催化剂中的条件下干燥。 加氢处理催化剂可以是新鲜的加氢处理催化剂或已经再生的使用的加氢处理催化剂。

公开(公告)号：WO02041978A1

公开(公告)日：2002-05-30

申请号：PCT/GB2001/005093

申请日：2001-11-19

IPC: B01D61/02 ,  B01D61/14 ,  B01J31/40 ,  C07D211/88 ,  C07D213/64

CPC classification number: C07D213/64 ,  B01D61/025 ,  B01D61/027 ,  B01D61/145 ,  B01D61/147 ,  B01J31/0201 ,  B01J31/0239 ,  B01J31/0247 ,  B01J31/0268 ,  B01J31/26 ,  B01J31/4015 ,  B01J31/4053 ,  B01J31/4061 ,  B01J2231/4277 ,  B01J2231/4283 ,  B01J2531/96 ,  B01J2531/98 ,  C07D211/88 ,  Y02P20/584

Abstract: There is provided a process for separating at least one phase transfer agent (PTA) from an organic liquid mixture containing at least one organic solvent and at least one PTA, in which the organic liquid mixture is brought into contact with one surface of a selectively permeable membrane and pressure is applied to the organic liquid mixture which causes a fraction of the organic liquid to permeate through the membrane and exit at the other surface, such that the concentration of the at least one PTA in the fraction of organic liquid which does not permeate the membrane increases while the concentration of the at least one PTA in the fraction of organic liquid which permeates through the membrane is less than the concentration of the at least one PTA in the original mixture.

Abstract translation: 提供了一种从含有至少一种有机溶剂和至少一种PTA的有机液体混合物中分离至少一种相转移剂（PTA）的方法，其中有机液体混合物与选择性可渗透的一个表面接触 膜和压力被施加到有机液体混合物上，这导致有机液体的一部分渗透通过膜并在另一个表面离开，使得不渗透的有机液体部分中的至少一种PTA的浓度 膜渗透到有机液体的部分中的至少一种PTA的浓度小于原始混合物中的至少一种PTA的浓度。

公开(公告)号：WO01025177A1

公开(公告)日：2001-04-12

申请号：PCT/EP2000/009494

申请日：2000-09-26

IPC: B01J38/00 ,  B01J31/30 ,  B01J31/40 ,  C07B61/00 ,  C07C17/278 ,  C07C17/38 ,  C07C19/01

CPC classification number: B01J31/0201 ,  B01J31/0237 ,  B01J31/0267 ,  B01J31/28 ,  B01J31/30 ,  B01J31/403 ,  B01J31/4053 ,  B01J2231/32 ,  B01J2531/16

Abstract: The invention concerns a method for recovering a co-catalyst of an aqueous phase by treatment with a base and a step which consists in separating the co-catalyst whereby the co-catalyst is isolated from the aqueous phase treated with the base, typically by steam distillation or by distillation.

Abstract translation: 本发明涉及通过用碱处理回收水相助催化剂的方法和步骤，该方法包括分离助催化剂，由此将助催化剂从用碱处理的水相中分离，通常通过蒸汽 蒸馏或蒸馏。

公开(公告)号：WO1994025157A1

公开(公告)日：1994-11-10

申请号：PCT/US1994004394

申请日：1994-04-21

Applicant: CRI INTERNATIONAL, INC.

Inventor： CRI INTERNATIONAL, INC. ,  SEAMANS, James, Dallas ,  PARTIN, John, Alexander ,  SAMONTE, Edward, Roy ,  LOCKEMEYER, John, Robert

IPC: B01J33/00

CPC classification number: B01J33/00 ,  B01J23/85 ,  B01J31/0201 ,  B01J37/0203 ,  B01J37/12 ,  B01J37/20 ,  C10G49/02

Abstract: Self-heating characteristics of a spontaneously combustible catalyst are reduced by treating the catalyst with an oxygen-containing hydrocarbon having at least 12 carbon atoms. The treatment is particularly suitable for reducing the self-heating characteristics of sulfidable metal oxide(s)-containing catalysts, presulfurized catalysts, presulfided catalysts or reduced catalysts. When applied to sulfur-containing catalysts, the treatment gives a catalyst that has suppressed self-heating properties without substantially compromising sulfur retention or activity. Further hydrocracking catalysts treated by the oxygen-containing hydrocarbons give improved product yield. Further, a method of safely unloading a catalyst from a reactor is provided where the catalyst in the reactor is treated with a liquid mixture containing the oxygen-containing hydrocarbon to wet the catalyst.

Abstract translation: 通过用具有至少12个碳原子的含氧烃处理催化剂来减少自发燃烧的催化剂的自热特性。 该处理特别适用于降低含硫化金属氧化物催化剂，预硫化催化剂，预硫化催化剂或还原催化剂的自加热特性。 当应用于含硫催化剂时，该处理产生抑制自热性能而不显着损害硫保留或活性的催化剂。 通过含氧烃处理的其它加氢裂化催化剂提高了产物产率。 此外，提供了一种从反应器中安全卸载催化剂的方法，其中用含有含氧烃的液体混合物处理反应器中的催化剂以润湿催化剂。

公开(公告)号：WO2013177546A2

公开(公告)日：2013-11-28

申请号：PCT/US2013/042712

申请日：2013-05-24

Applicant: NOVOMER, INC.

Inventor： FARMER, Jay, J.

IPC: C08G59/02

CPC classification number: C08G64/34 ,  B01J31/0201 ,  B01J31/0202 ,  B01J31/183 ,  B01J31/184 ,  B01J31/22 ,  B01J31/2217 ,  B01J31/2243 ,  B01J2231/14 ,  B01J2531/0238 ,  B01J2531/025 ,  B01J2531/0252 ,  B01J2531/845 ,  C08G18/44 ,  C08G64/0208 ,  C08G64/0216 ,  C08G65/2603 ,  C08G65/266 ,  Y02P20/52

Abstract: In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO 2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO 2 , wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of -OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent.

Abstract translation: 一方面，本公开内容涵盖用于CO 2和环氧化物共聚的聚合体系，其包括1）包含具有永久性配体组的金属配位化合物和至少一种作为聚合引发剂的配体的催化剂，和2）链转移剂 具有能够引发环氧化物和CO 2共聚的一个或多个位点，其中链转移剂含有一个或多个掩蔽的羟基。 在第二方面，本发明包括使用本发明聚合体系合成聚碳酸酯多元醇的方法。 在第三方面，本公开内容包括聚碳酸酯多元醇组合物，其特征在于聚合物链具有高百分比的-OH端基，高百分比的碳酸酯键，并且基本上所有具有羟基端基的聚碳酸酯链都没有嵌入链转移剂 。

公开(公告)号：WO2013143841A1

公开(公告)日：2013-10-03

申请号：PCT/EP2013/055014

申请日：2013-03-12

Applicant: HUNTSMAN INTERNATIONAL LLC

Inventor： ESBELIN, Christian ,  VERBEKE, Hugo ,  VERBEKE, Hans, Godelieve, Guido

IPC: B01J31/02 ,  C08G18/09 ,  C08G18/22 ,  C08G18/28 ,  C08G18/38 ,  C08G18/48 ,  C08G18/58 ,  C08G18/72 ,  C08G18/76 ,  C08G18/79 ,  C08K5/21

CPC classification number: B01J31/0247 ,  B01J31/0201 ,  B01J31/04 ,  C08G18/092 ,  C08G18/10 ,  C08G18/225 ,  C08G18/285 ,  C08G18/3829 ,  C08G18/4829 ,  C08G18/58 ,  C08G18/725 ,  C08G18/7664 ,  C08G18/7671 ,  C08G18/794 ,  C08G18/797 ,  C08G2105/02 ,  C08K5/21

Abstract: A trimerization catalyst composition comprising a trimerization catalyst compound selected from one or more organic metal salt, preferably alkali or earth alkali metal salts, and one or more compounds selected from compounds which comprise a carboxamide group having the structure -CO-NH 2 and/or from compounds which comprise a group having the structure -CO-NH-CO- is disclosed. Further a stable polyisocyanate composition comprising the catalyst composition and a process for making the polyisocyanate composition is disclosed. A curable polyisocyanate composition is obtained comprising the catalyst composition, a polyisocyanate composition, an epoxy resin and optionally a polyol/monool composition and a polyisocyanurate comprising material made by allowing the curable composition to react at elevated temperature and a process for making the polyisocyanurate comprising material.

Abstract translation: 一种三聚催化剂组合物，其包含选自一种或多种有机金属盐，优选碱金属或碱土金属盐的三聚催化剂化合物和一种或多种选自包含具有结构-CO-NH 2的羧酰胺基和/或 公开了包含具有结构-CO-NH-CO-的基团的化合物。 此外，公开了包含该催化剂组合物的稳定的多异氰酸酯组合物和制备多异氰酸酯组合物的方法。 得到包含催化剂组合物，多异氰酸酯组合物，环氧树脂和任选的多元醇/一元醇组合物的可固化多异氰酸酯组合物和包含通过使可固化组合物在升高的温度下反应制备的包含材料的聚异氰脲酸酯和制备聚异氰脲酸酯的方法 。