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    Preparation of porous substrates having well defined morphology
    173.
    发明授权
    Preparation of porous substrates having well defined morphology 失效
    制备具有良好定义形态的多孔基材

    公开(公告)号：US4954381A

    公开(公告)日：1990-09-04

    申请号：US171497

    申请日：1988-03-21

    Applicant: Israel Cabasso ,  Moshe Levy

    Inventor： Israel Cabasso ,  Moshe Levy

    IPC: B01D67/00 ,  B01D69/02 ,  C08J3/00 ,  C08J9/28

    CPC classification number: B01D67/0006 ,  B01D67/0004 ,  B01D67/003 ,  B01D69/02 ,  C08J3/005 ,  C08J9/28 ,  B01D2323/12 ,  B01D2323/40 ,  C08J2201/05 ,  Y10S260/31 ,  Y10S424/07 ,  Y10S514/963 ,  Y10S977/773 ,  Y10S977/788 ,  Y10S977/896 ,  Y10T428/24149 ,  Y10T428/2985 ,  Y10T428/2987

    Abstract: A membrane of defined pore structure and controlled pore diameter and a method of preparing the membrane which comprises dispersing in a water soluble polymer solution (A) an organic polymer solution (B), the water-soluble polymer solution (A) being a non-solvent for the polymer solution (B), to form micro-spherical droplets of the polymer solution (A) which are enveloped by a solid phase consisting of a coagulated or cross-linked polymer solution (B); evenly casting the dispersion on a flat surface; and evaporating the solvent for the polymer solution (B) to form a microporous membrane comprised of the polymer (B), the porosity, pore size, and void volume of the microporous membrane being a function of the polymer (A) concentration, the microsphere dimensions and the temperature and evaporation rate. The water-soluble polymer (A) is selected from polyethyleneimine, gelatin, polyvinyl-pyrrolidone, polyvinyl pyridinium halide, polyacrylic acid, polyhydroxyethylmethacrylate (HEMA), dextran, or polyvinyl acetate. The continuous phase polymer (B) is selected from a brominated polyphenylene oxide, polyphenylene oxide, polyacetic acid, polystyrene, polyglycol acrylate (PGA), polymethylmethacrylate, cellulose acetate, polyvinyl acetate, polycarbonate and polyvinylidene fluoride.

    Abstract translation: 一种限定孔结构和受控孔径的膜和一种制备膜的方法，其包括将水溶性聚合物溶液（A）分散在有机聚合物溶液（B）中，所述水溶性聚合物溶液（A） 用于聚合物溶液（B）的溶剂，以形成聚合物溶液（A）的微球形液滴，其被由凝结或交联的聚合物溶液（B）组成的固相包围; 均匀地将分散体浇铸在平坦的表面上; 并蒸发聚合物溶液（B）的溶剂以形成由聚合物（B）组成的微孔膜，微孔膜的孔隙率，孔径和空隙体积是聚合物（A）浓度的函数，微球体 尺寸和温度和蒸发速率。 水溶性聚合物（A）选自聚乙烯亚胺，明胶，聚乙烯吡咯烷酮，聚氯乙烯吡啶鎓卤化物，聚丙烯酸，聚羟基乙基甲基丙烯酸酯（HEMA），葡聚糖或聚乙酸乙烯酯。 连续相聚合物（B）选自溴化聚苯醚，聚苯醚，聚乙酸，聚苯乙烯，聚乙二醇丙烯酸酯（PGA），聚甲基丙烯酸甲酯，乙酸纤维素，聚乙酸乙烯酯，聚碳酸酯和聚偏二氟乙烯。

    Anisotropic organosilicon polymer membrane
    174.
    发明授权
    Anisotropic organosilicon polymer membrane 失效
    各向异性有机聚合物膜

    公开(公告)号：US3754375A

    公开(公告)日：1973-08-28

    申请号：US3754375D

    申请日：1971-03-02

    Applicant: RHONE POULENC SA

    Inventor： BOUCHILLOUX J ,  FABRE A ,  FAURE A

    IPC: B05D1/38 ,  B01D71/44 ,  C08F130/08 ,  C08J5/22 ,  C08J9/28 ,  C08L83/04 ,  B01D53/22 ,  C08C17/08

    CPC classification number: B01D71/44 ,  C08J9/28 ,  C08J2201/05 ,  C08J2201/0542

    Abstract: An anisotropic membrane is provided having excellent mechanical properties combined with good permeation characteristics which comprises a vinyltriorganosilane polymer or copolymer consisting of a dense layer, of average thickness between 0.01 and 10 Mu , and a porous layer with open pores, of thickness up to 500 Mu in which the volume of the interstitial spaces in the porous layer represents 20 to 80 percent of the total volume of the membrane.

    Abstract translation: 提供具有优异的机械性能和良好的渗透特性的各向异性膜，其包括乙烯基三有机硅烷聚合物或由致密层组成的共聚物，其平均厚度为0.01至10微米，和具有至多500微米厚度的开孔的多孔层 其中多孔层中的间隙空间的体积占膜的总体积的20至80％。

    Porous elastomeric coating
    176.
    发明授权
    Porous elastomeric coating 失效
    多孔弹性体涂料

    公开(公告)号：US3445272A

    公开(公告)日：1969-05-20

    申请号：US41957664

    申请日：1964-12-18

    Applicant: UNITED SHOE MACHINERY CORP

    Inventor： NEWTON CHARLES G JR

    IPC: B05D7/24 ,  C08G18/08 ,  C08J3/03 ,  C08J9/28 ,  C08L1/28 ,  C08L75/04 ,  C08L89/00 ,  C09D127/06 ,  C09D133/08 ,  D06M15/693 ,  D06N3/00 ,  C23C13/04 ,  C09D3/72 ,  C09D5/00

    CPC classification number: B05D7/24 ,  C08G18/0866 ,  C08J3/03 ,  C08J9/28 ,  C08J9/283 ,  C08J2201/05 ,  C08K5/01 ,  C08L1/10 ,  C08L1/28 ,  C08L9/02 ,  C08L27/06 ,  C08L75/04 ,  C08L89/00 ,  C08L89/005 ,  C09D127/06 ,  C09D133/08 ,  D06M15/693 ,  D06N3/0052 ,  Y10S428/904 ,  Y10T428/249978 ,  Y10T428/249981 ,  Y10T428/264 ,  Y10T428/31935 ,  Y10T442/2139 ,  C08L2666/02 ,  C08L2666/26 ,  C08L2666/28

    Abstract: 1,135,649. Coating compositions. UNITED SHOE MACHINERY CORP. 15 Dec., 1965 [18 Dec., 1964], No. 53160/65. Headings C3C, C3P and C3R. [Also in Division B2] Coating compositions suitable for depositing porous films comprise an aqueous dispersion of a film-forming polymeric material and fine droplets, of which from 30-60% have dimensions in the range of 0À001-0À003 mm. and substantially the remainder of said droplets have dimensions in the range of 0À003-0À010 mm., of a water-immiscible volatile organic liquid in which the polymeric material is insoluble or substantially insoluble, said liquid being suspended in the aqueous phase of said dispersion and being present in an amount of 25-300% based on the weight of said polymeric material. Preferred organic liquids are petroleum hydrocarbon fractions, e.g. mineral spirits, petroleum naphtha and kerosene; others mentioned are halogenated hydrocarbons and nitroparaffins. The polymeric material may be, for example, a latex of a butadiene-acrylonitrile copolymer which may be carboxylated, an acrylic ester polymer or copolymer emulsion, a latex of polyvinyl chloride or copolymer of vinyl chloride with e.g. vinyl acetate, or a latex of an elastomeric polyurethane, formed by reacting a polyester or polyether polyol with excess of a polyisocyanate and then chain extending the -NCO terminated condensate by reaction with a compound such as a polyol, polyamine or amino-alcohol. The composition may include a modifier to improve gel strength of the coatings, e.g. casein rendered water-soluble by treatment with an alkaline material, polyvinyl alcohol, methyl cellulose, and the insoluble resinous residue obtained from the distillation of pine tar resin. Other components which may be added include waxes or wax-like substances, gums, colouring agents, e.g. carbon black or zinc oxide, and mineral fillers. After a coating has been deposited on a surface, it is coalesced by evaporating water whereby the polymer particles gel; and when the solvent droplets are evaporated a porous coating is obtained.

    HUMINS-CONTAINING FOAM
    177.
    发明申请
    HUMINS-CONTAINING FOAM 审中-公开
    含有人体腐蚀性的泡沫

    公开(公告)号：WO2017074183A8

    公开(公告)日：2017-06-22

    申请号：PCT/NL2016050742

    申请日：2016-10-26

    Applicant: AVANTIUM KNOWLEDGE CENTRE B V

    Inventor： MIJA ALICE CRISTINA ,  DE JONG EDSERD ,  VAN DER WAAL JAN CORNELIS ,  VAN KLINK GERARDUS PETRUS MARIA

    IPC: C08J9/00 ,  C08K5/00 ,  C08L99/00

    CPC classification number: C08L99/00 ,  C08J9/0085 ,  C08J9/142 ,  C08J9/28 ,  C08J2201/05 ,  C08J2203/12 ,  C08J2205/04 ,  C08J2205/044 ,  C08J2399/00 ,  C08K5/0008

    Abstract: The invention provides a foam, comprising a cellular structure and having a density of at most 0.50 g/cm3, wherein the cellular structure is provided by a solid material that comprises humins. Such a foam is prepared in a process, which comprises: - providing a starting material containing humins; and - heating the starting material to a temperature in the range of 150 to 450 °C. The foam can be used in articles for a variety of applications such as substrate for plant growth, as adsorbent for treating waste water or waste gases, as support for solid catalysts, as insulation material, or packaging material.

    Abstract translation: 本发明提供了一种泡沫，其包含多孔结构并具有至多0.50g / cm 3的密度，其中该多孔结构由包含腐殖质的固体材料提供。 这种泡沫体的制备方法包括： - 提供含有腐殖质的起始材料; 和 - 将起始材料加热到150-450℃的温度。 泡沫可用于各种用途的制品中，如用于植物生长的基质，用作处理废水或废气的吸附剂，用作固体催化剂的载体，作为绝缘材料或包装材料。

    HUMINS-CONTAINING FOAM
    178.
    发明申请
    HUMINS-CONTAINING FOAM 审中-公开
    含有人体腐蚀性的泡沫

    公开(公告)号：WO2017074183A1

    公开(公告)日：2017-05-04

    申请号：PCT/NL2016/050742

    申请日：2016-10-26

    Applicant: VANTIUM KNOWLEDGE CENTRE B.V.

    Inventor： MIJA, Alice Cristina ,  DE JONG, Edserd ,  VAN DER WAAL, Jan Cornells ,  VAN KLINK, Gerardus Petrus Maria

    IPC: C08J9/00 ,  C08K5/00 ,  C08L99/00

    CPC classification number: C08L99/00 ,  C08J9/0085 ,  C08J9/142 ,  C08J9/28 ,  C08J2201/05 ,  C08J2203/12 ,  C08J2205/04 ,  C08J2205/044 ,  C08J2399/00 ,  C08K5/0008

    Abstract: The invention provides a foam, comprising a cellular structure and having a density of at most 0.50 g/cm3, wherein the cellular structure is provided by a solid material that comprises humins. Such a foam is prepared in a process, which comprises: - providing a starting material containing humins; and - heating the starting material to a temperature in the range of 150 to 450 °C. The foam can be used in articles for a variety of applications such as substrate for plant growth, as adsorbent for treating waste water or waste gases, as support for solid catalysts, as insulation material, or packaging material.

    Abstract translation: 本发明提供了一种泡沫，其包含多孔结构并具有至多0.50g / cm 3的密度，其中该多孔结构由包含腐殖质的固体材料提供。 这种泡沫体的制备方法包括： - 提供含有腐殖质的起始材料; 和 - 将起始材料加热至150至450℃的温度。 该泡沫可用于各种用途的制品中，如用于植物生长的基材，用作处理废水或废气的吸附剂，用作固体催化剂的载体，作为绝缘材料或包装材料。

    SYMMETRISCH PORÖSE MEMBRANEN AUS ALDEHYDVERNETZTEM THERMOPLASTISCHEN SILICONELASTOMER
    180.
    发明申请
    SYMMETRISCH PORÖSE MEMBRANEN AUS ALDEHYDVERNETZTEM THERMOPLASTISCHEN SILICONELASTOMER 审中-公开
    平衡多孔膜ALDEHYDVERNETZTEM热塑性弹性体硅

    公开(公告)号：WO2015003957A1

    公开(公告)日：2015-01-15

    申请号：PCT/EP2014/063943

    申请日：2014-07-01

    Applicant: WACKER CHEMIE AG

    Inventor： HALBACH, Tobias ,  BALL, Peter

    IPC: B01D67/00 ,  B01D71/76 ,  C08J3/24 ,  C08G77/38

    CPC classification number: B01D71/76 ,  B01D67/0006 ,  B01D67/0009 ,  B01D67/0093 ,  B01D71/54 ,  B01D71/56 ,  B01D71/70 ,  B01D2323/22 ,  B01D2323/30 ,  C08G77/26 ,  C08J9/28 ,  C08J2201/026 ,  C08J2201/05 ,  C08J2383/10 ,  C08L83/08

    Abstract: Gegenstand der Erfindung ist eine symmetrisch poröse Membran M aus mindestens zwei Amino NH-Gruppen pro Molekül aufweisendem thermoplastischen Siliconelastomer S1, das mittels Aldehyd vernetzt ist; zwei Verfahren zur Herstellung der mittels Aldehyd vernetzten symmetrisch porösen Membran M, bei dem in einem ersten Schritt eine Lösung oder Suspension aus einem thermoplastischen Siliconelastomer S1, das mindestens zwei Amino NH-Gruppen pro Molekül aufweist, in einem Gemisch aus Lösungsmittel L1 und Lösungsmittel L2 gebildet wird, in einem zweiten Schritt die Lösung oder Suspension in eine Form gebracht wird, in einem dritten Schritt Lösungsmittel L1 aus der Lösung oder Suspension entfernt wird bis die Löslichkeit des thermoplastischen Siliconelastomers S1 im Gemisch unterschritten wird, wobei sich eine an thermoplastischem Siliconelastomer S1 reiche Phase A und eine an thermoplastischen Siliconelastomer S1 arme Phase B ausbildet und damit die Strukturbildung durch die Phase A erfolgt, in einem vierten Schritt das Lösungsmittel L2 und Reste des Lösungsmittels L1 entfernt werden, wobei eine Membran entsteht und in einem fünften Schritt die Membran aus dem thermoplastischen Siliconelastomer S1 vernetzt wird, wobei die Membran M entsteht, wobei beim ersten Verfahren im ersten Schritt und beim zweiten Verfahren im fünften Schritt ein Aldehyd enthaltendes Aldehydreagenz (AR) zugesetzt wird; sowie Verwendungen der porösen Membran M.

    Abstract translation: 本发明是每个分子NH aufweisendem热塑性硅氧烷弹性体S1，它是由醛交联的至少两个氨基基团的对称多孔膜M; 两种方法用于制备交联的由醛对称多孔膜M，其中形成在第一步骤中，热塑性硅氧烷弹性体S1的溶液或悬浮液，其在溶剂S1和溶剂L2的混合物每分子具有至少两个氨基NH基团， 在溶液或悬浮液被放置在模具中的第二步骤中，从溶液或悬浮液到热塑性硅氧烷弹性体S1的溶解度的第三步骤溶剂L1除去未在该混合物中，其特征在于，富热塑性硅氧烷弹性体S1相达到 形成和在热塑性硅氧烷弹性体S1相B和在第四步骤中的溶剂L2和溶剂L1被除去的残留差由相位一个，其中，膜中产生和在第五步骤中进行结构的形成，所述热塑性塑料的膜 S1的硅酮弹性体是交联的，膜片M形成，所述含醛的试剂在第一步骤中的第一方法和在第五步骤中第二方法中，醛（AR）被添加; 和多孔膜M的使用

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