Enhanced oxygen-scavenging polymers, and packaging made therefrom
    171.
    发明申请
    Enhanced oxygen-scavenging polymers, and packaging made therefrom 审中-公开
    增强的清除氧气的聚合物,以及由此制成的包装

    公开(公告)号:US20040043172A1

    公开(公告)日:2004-03-04

    申请号:US10647276

    申请日:2003-08-26

    Abstract: Oxygen-scavenging polymers and packaging for holding oxygen-sensitive products. A heat treatment process has been found to significantly increase the oxygen-scavenging performance of the polymer. The enhanced scavenging polymer can be effectively incorporated into various packaging, including transparent multilayer containers for beer and juice. In one embodiment, a multilayer package made from the scavenger provides an actual reduction in oxygen content of a contents of the package, over a long period of time (e.g., 24 weeks). The package can be stored unfilled for an extended period (without significant loss of scavenging capability) and will scavenge substantially immediately upon filling with a liquid product. The package may incorporate a relatively low weight percentage of the scavenger, thus providing enhanced scavenging in a cost-effective manner.

    Abstract translation: 含氧清除聚合物和用于保存氧敏感产品的包装。 已经发现热处理工艺显着地提高了聚合物的清除氧气的性能。 增强的清除聚合物可以有效地结合到各种包装中,包括用于啤酒和果汁的透明多层容器。 在一个实施方案中,由清除剂制成的多层包装在长时间(例如24周)内提供包装内容物的氧含量的实际降低。 包装可以长时间储存​​(不会显着损失清除能力),并且在填充液体产品时将基本上立即清除。 包装可以包含相对较低重量百分比的清除剂,从而以成本有效的方式提供增强的清除。

    Epoxy-, melamine- and isocyanate cured oxygen scavenging compositions and methods of preparing the same
    173.
    发明授权
    Epoxy-, melamine- and isocyanate cured oxygen scavenging compositions and methods of preparing the same 失效
    环氧,三聚氰胺和异氰酸酯固化除氧组合物及其制备方法

    公开(公告)号:US06527976B1

    公开(公告)日:2003-03-04

    申请号:US09722373

    申请日:2000-11-27

    Abstract: An oxygen scavenging composition that can be either thermoplastic or thermoset, and that comprises at least one oxygen scavenging polymer and at least one curing agent is disclosed. The oxygen scavenging polymer comprises a polymeric backbone, at least two curing functional groups that are terminal groups and at least one oxygen scavenging cyclic moiety having from 5 to 9 carbon atoms in its ring and at least one carbon-carbon double bond in its ring. The curing functional groups of the oxygen scavenging polymer can be independently selected from hydroxyl groups, amino groups, carboxylic groups, sulfonic groups, and epoxy groups. The curing agent comprises at least two functional groups that are capable of reacting with the curing functional groups of the oxygen scavenging polymer.

    Abstract translation: 公开了可以是热塑性或热固性的,并且包含至少一种除氧聚合物和至少一种固化剂的除氧组合物。 除氧聚合物包含聚合物骨架,至少两个固化官能团,其为端基和至少一个在其环中具有5-9个碳原子的氧清除性环状部分及其环中的至少一个碳 - 碳双键。 除氧聚合物的固化官能团可以独立地选自羟基,氨基,羧基,磺酸基和环氧基。 固化剂包含至少两个能够与除氧聚合物的固化官能团反应的官能团。

    Polyether containing polymers for oxygen scavenging
    174.
    发明授权
    Polyether containing polymers for oxygen scavenging 失效
    用于除氧的聚醚聚合物

    公开(公告)号:US06455620B1

    公开(公告)日:2002-09-24

    申请号:US09630519

    申请日:2000-08-02

    Abstract: The present invention relates to oxygen scavenging compositions comprising an oxidation catalyst and at least one polyether selected from the group consisting of unsubstituted poly(alkylene glycol)s having alkylene chains of 1 to 3 carbon atoms, substituted or unsubstituted poly(alkylene glycol)s having alkylene chains of at least 4 carbon atoms, copolymers of poly(alkylene glycol)s, blends containing poly(alkylene glycol)s and mixtures thereof. The invention further relates to polymers containing said oxygen scavenging compounds and articles made therefrom.

    Abstract translation: 本发明涉及包含氧化催化剂和至少一种选自具有1至3个碳原子的亚烷基链的未取代的聚(亚烷基二醇),取代或未取代的聚(亚烷基二醇)的聚醚的氧清除组合物,其具有 至少4个碳原子的亚烷基链,聚(亚烷基二醇)的共聚物,含有聚(亚烷基二醇)的共混物及其混合物。 本发明还涉及含有所述除氧化合物和由其制成的制品的聚合物。

    Non-extractable polymeric metal salt useful in catalyzing oxygen scavenging
    175.
    发明授权
    Non-extractable polymeric metal salt useful in catalyzing oxygen scavenging 失效
    不可萃取的聚合金属盐可用于催化除氧

    公开(公告)号:US06437086B1

    公开(公告)日:2002-08-20

    申请号:US09680337

    申请日:2000-10-05

    CPC classification number: C08G79/00 C08K5/098 C08K2201/012 C08L23/20

    Abstract: Herein are disclosed polymeric metal salts useful in catalyzing oxygen scavenging by oxygen scavenging polymers. The polymeric metal salts comprise structure I: wherein R is selected from C1--C20 alkyl, C5-C20 cycloalkyl, C2-C40 branched alkyl, C2-C40 branched alkyl acid or diacid, C2-C12 alkenyl, C5-C12 cycloalkenyl, C2-C40 branched alkenyl, or C2-C40 branched alkenyl acid or diacid; and M is selected from manganese, iron, cobalt, nickel, copper, rhodium, or ruthenium. These polymeric metal salts are substantially non-extractable from a packaging article comprising the metal salts. Also disclosed are packaging articles comprising the polymeric metal salts, and methods of synthesizing the polymeric metal salts.

    Abstract translation: 本文公开了可用于催化氧清除聚合物除氧的聚合金属盐。 聚合金属盐包含结构I:其中R选自C 1 -C 20烷基,C 5 -C 20环烷基,C 2 -C 40支链烷基,C 2 -C 40支链烷基酸或二酸,C 2 -C 12烯基,C 5 -C 12环烯基,C 2 -C40支链烯基或C2-C40支链烯基酸或二酸; M选自锰,铁,钴,镍,铜,铑或钌。 这些聚合金属盐基本上不能从包含金属盐的包装制品中提取出来。 还公开了包含聚合物金属盐的包装制品以及合成聚合物金属盐的方法。

    산소 제거수단이 구비된 포장지의 제조방법
    178.
    发明授权
    산소 제거수단이 구비된 포장지의 제조방법 有权
    带有除氧装置的包装纸的制造方法

    公开(公告)号:KR101826624B1

    公开(公告)日:2018-02-07

    申请号:KR1020160148283

    申请日:2016-11-08

    Inventor: 홍현기

    Abstract: 본발명은식품등 특히일정함량의습이함유되어진식품등의포장을위하여밀봉가능하게사용되는포장용포대에별도의산소제거제팩을사용치아니하고산소제거제가일체로형성된포장용포대를제공하기위한포장지의제조방법에관한것이다. 이를위하여본 발명에서는탈 산소제를습이있을경우에만반응할수 있는각종무기계재료로이루어지는것과유기계재료로이루어지는것 중에서무기계재료의주제로서는철 등의금속분말, 아황산염, 아황산수소염, 아이티온산염등의어느하나또는그 이상을사용하거나유기계재료의주제로서는 L-아스코르브산, 에리소르브산및 그들의염, 글루코스등의당류, 카테콜, 피로갈롤등의환원성다가알코올류등의어느하나또는그 이상을일정한크기의입도로분말화하여분말상의 llDPE와일정비율로혼합하여 1차로압출성형하여입자로성형토록한 후상기입자를 2차로포장용포대의내피를형성하는필름으로제조하기위하여 LDPE와혼합하여사용하거나또는내피를형성하기위하여용융에의한코팅의바식으로구현토록한 것이다.

    Abstract translation: 本发明涉及一种用于提供包装袋的包装纸,其中氧气清除剂一体地形成,而不用单独的氧气清除剂包​​装在可用于密封的包装袋中,例如食品, 及其制造方法。 在本发明中,脱氧jereul s的由多种无机材料的,只能反应如果从那些由金属粉末的有机材料,如铁,亚硫酸根的无机材料的主体,可以亚硫酸盐为此,如抗炎,连二亚硫酸盐 其使用一种或多种有机材料,或作为L-抗坏血酸,异抗坏血酸及其盐,糖类如葡萄糖,邻苯二酚,恒定为任何一个或多个这样的还原性多元醇,如焦棓酚的受试者 然后将该混合物与预定比例的llDPE混合挤出形成颗粒,然后将颗粒与LDPE混合以形成形成用于二次使用的袋子内表层的膜 或者作为通过融化形成内皮的涂层棒。

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