Abstract:
Described herein are open celled foams including a matrix of interconnected spheres. Also described herein are methods of making open celled foams as well as making composite members with open celled foam coatings covering at least a portion of the composite member. The open celled foams described herein are silicone based materials and can be used to coat implants such as breast implants and function to encourage tissue ingrowth and reduce capsular formation.
Abstract:
A nanoporous material is disclosed having a plurality of lamellae. Through each lamella is an array of penetrating pores. Adjacent lamellae are spaced apart by an intervening spacing layer. The spacing layer comprises an array of spacing elements integrally formed with and extending between the adjacent lamellae. The spacing layer has interconnected porosity extending within the spacing layer. Such a nanoporous material can be manufactured using block copolymer materials. First, a morphology is formed comprising a three dimensional array of isolated islands in a continuous matrix. The islands are formed of at least one island component of the block copolymer and the matrix is formed of at least one matrix component of the block copolymer. Next, channels are formed in the matrix between at least some of the islands. The island component is then selectively removed to leave the matrix with an array of interconnected pores.
Abstract:
A process for preparing a polymer composite that includes reacting (a) a multi-functional monomer and (b) a block copolymer comprising (i) a first block and (ii) a second block that includes a functional group capable of reacting with the multi-functional monomer, to form a crosslinked, nano-structured, bi-continuous composite. The composite includes a continuous matrix phase and a second continuous phase comprising the first block of the block copolymer.
Abstract:
Porous infusible polymer (IP) parts are made by incorporating 0.2 to 10 volume percent organic fibers, preferably with short lengths, into the particulate IP, consolidating the mixture under pressure and optionally heating, and then “burning off” the fibers. After the fibers are burned off the resulting part has porosity in which the pores are elongated, usually retaining the shape of the organic fibers. When these parts are exposed to moisture (which they usually absorb) and then suddenly heated they tend not to blister from vaporization of the water. This makes them useful as parts for aircraft (jet) and other engines and other applications where sudden temperature increase may occur.
Abstract:
A process for preparing a polymer composite that includes reacting (a) a multi-functional monomer and (b) a block copolymer comprising (i) a first block and (ii) a second block that includes a functional group capable of reacting with the multi-functional monomer, to form a crosslinked, nano-structured, bi-continuous composite. The composite includes a continuous matrix phase and a second continuous phase comprising the first block of the block copolymer.
Abstract:
Provided is a microphase-separated structure membrane including a block copolymer in which a hydrophilic polymer component and a hydrophobic polymer component are coupled to each other via a structural unit having a reactive group, an electron acceptor or electron donor, or a dye. In the microphase-separated structure membrane, a cylinder structure composed of the hydrophilic polymer component lies in a matrix composed of the hydrophobic polymer component and is oriented in the direction perpendicular to the membrane surface, and the structural unit having a reactive group, an electron acceptor or electron donor, or a dye lies between the matrix and the cylinder structure.
Abstract:
An optically clear, porous polymer composition, an article incorporating the composition, and methods for making and using the composition for cell culture including, for example, regulating or promoting cell function or gene expression as defined herein.
Abstract:
The present invention relates to a polymeric porous material characterized in that: the porous material has a bimodal pore size distribution attributable to macropores having a pore size of at least 50 nm and mesopores having a pore size of from 2 nm to less than 50 nm, the proportion of the specific surface area of the macropores to the specific surface area of all pores of the porous material is at least 10%, and the porous material is produced by (1) polymerizing a monomer in the presence of a polymerization initiator using as a porogen a solution obtained by dissolving a polymer having a weight-average molecular weight of at least 100,000 and a molecular weight distribution Mw/Mn of not more than 1.5 in a good solvent for the monomer, and (2) removing the porogen from the resultant product.
Abstract:
A low-k organic dielectric material having stable nano-sized porous is provided as well as a method of fabricating the same. The porous low-k organic dielectric material is made from a composition of matter having a vitrification temperature (Tv-comp) which includes a b-staged thermosetting resin having a vitrification temperate (Tv-resin), a pore generating material, and a reactive additive. The reactive additive lowers Tv-comp below Tv-resin.
Abstract:
A low-k organic dielectric material having stable nano-sized porous is provided as well as a method of fabricating the same. The porous low-k organic dielectric material is made from a composition of matter having a vitrification temperature (Tv-comp) which includes a b-staged thermosetting resin having a vitrification temperate (Tv-resin), a pore generating material, and a reactive additive. The reactive additive lowers Tv-comp below Tv-resin.