Abstract:
Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts wherein the catalytic component is of the form (ligand) 2 -M-X 2 where X is a halogen, M is selected from the group of Ti, Zr, and Hf and ligand is selected from the group consisting of cyclopentadienyl, substituted cyclopentadienyl, indenyl, and substituted indenyl, wherein the two ligands may be the same or different compound are provided.
Abstract:
The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or pH of the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.
Abstract:
Method, devices and systems are provided for measuring deformation in subterranean formations. Such methods include introduction of spaced-apart depth magnetic markers along the longitudinal length of a well bore and measuring the position of each depth marker over time so as to determine deformation of the subterranean formation. In certain embodiments, depth markers comprise rare earth magnets. In further embodiments, orientation of each magnetic bullet is determined over time to determine the change in orientation of each magnetic bullet. Advantages of the methods and devices herein include, but are not limited to, improved accuracy and reliability of deformation measurements and reduced environmental impact due to the avoidance of radioactive markers used by the present invention.
Abstract:
Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts, wherein the catalytic component is of the formula (I) where M is selected from the group of Ti, Zr, Hg, Ni, and V and R and R' are selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkinyl, alkyloxy, substituted aryl, and halogens, are provided.
Abstract:
The invention is directed to crosslinked water-soluble swellable polymers, methods for making same and their various uses. More particularly, the invention relates to a composition comprising expandable polymeric particles being made with 0.1-5% hydrophobic monomers and labile crosslinkers and stable crosslinkers, said particles mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a well and when the heat and/or pH of the target zones in the formation cause degradation of the labile crosslinker and when the particle expands, the hydrophobic groups associate to form a hydrophobically associative polymer, thus diverting water to lower permeability regions and improving oil recovery.
Abstract:
A method of making a heterogenously supported catalyst useful in dimerization, oligomerization or polymerization is provided in which a catalyst precursor containing a metal and an aromatic group are alkylated onto an oligomeric support having at least one terminal unsaturated group by Friedel Crafts alkylation.
Abstract:
The present invention relates generally to a method for removing contaminants from a fluid stream and chemically upgrading the stream at the same time. More particularly, the invention relates to a catalytic moving bed filter for removing contaminants from a gas or vapor stream and to compositions comprising both moving bed filter materials and one or more catalysts intimately admixed therewith.
Abstract:
The invention is directed to stable crosslinked water-soluble swellable polymers and methods for making same. More particularly, the invention relates to a composition comprising expandable polymeric particles having anionic sites and labile crosslinkers and stable crosslinkers, said particle mixed with a fluid and a cationic crosslinker that is capable of further crosslinking the particle on degradation of the labile crosslinker and exposure of the anionic sites so as to form a gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into target zone and when the heat and/or pH of the target zone cause degradation of the labile crosslinker and the particle expands, the cationic crosslinker crosslinks the polymer to form a gel, thus diverting water to lower permeability regions and improving oil recovery.
Abstract:
The invention is directed to delayed gelation agents comprising a degradable polymeric cage containing therein one or more gelation agents. The cage degrades in situ, e.g, in an oil reservoir, thus releasing the gelation agent(s), which can then crosslink second polymers in situ to form a gel.
Abstract:
The present invention relates to a high-pressure quartz crystal microbalance sensor that is capable of measuring adsorption and diffusion characteristics of nanoporous materials and thin films at high pressures.