Abstract:
Verfahren zur Herstellung von 2-Chlormethyl-phenylessigsäurederivaten der Formel (I), in der X für C l -C 4 -Alkoxy oder Methylamino steht, durch Etherspaltung von Verbindungen der Formel (II), in der R C l -C 4 -Alkyl, C 1 -C 4 -Alkoxy, C l -C 2 -Halogenalkyl, C 1 -C 4 -Alkylcarbonyl, C l -C 4 -Alkylcarbonyloxy, Halogen, Nitro oder Cyano bedeutet und X die obengenannte Bedeutung besitzt, dadurch gekennzeichnet, dass die Umsetzung in Gegenwart von Chlorwasserstoff und einem inerten Lösungsmittel stattfindet, und dem Reaktionsgemisch ein Katalysator ausgewählt aus der Gruppe: Eisen, Indium oder deren Halogenide, Oxide oder Triflate zugesetzt wird.
Abstract:
The invention relates to pyrazoles of formula (I) wherein said variables can represent the following: R = hydrogen, nitro, halogen, cyano, rhodano or an aliphatic radical; R = a substituted sulphur, nitrogen or phosphor atom; R = hydrogen, halogen or an alliphatic radical; R , R = hydrogen, nitro, halogen, cyano, rhodano ar an aliphatc radical; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R , R , R = hydrogen, C1-C6-alkyl, whereby at the most R , R , R represent hydrogen; in addition to the tautomers and agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as pesticides.
Abstract translation:本发明提供了式(I)的吡唑类,其中变量尤其包括:R 1氢,硝基,卤素,氰基,罗多诺或脂肪族基团; R 2是取代的硫,氮或磷原子; R 3是氢,卤素或脂族基团; R 4,R 5是氢,硝基,卤素,氰基,rhodano或脂族基团; R 6是氢,卤素,C 1 -C 6烷基,C 1 -C 6烷氧基,C 3 -C 8环烷基; R 7,R 8,R 9,氢,C 1 -C 6烷基,其中基团R 7,R 8,R 9中至多一个是氢; 和它们的互变异构体和农业上有用的盐。 此外,本发明涉及制备式(I)化合物的方法,含有它们的组合物,以及式(I)化合物和组合物用于防治含有它们的有害植物的用途。
Abstract:
The invention relates to tricyclic pyrazolone derivatives of the formula (I) in which the variables have the following meaning: R is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-haloalkoxy, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro or C1-C3-alkylsulfonyl, phenylsulfonyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro; R , R are hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, NR R , C2-C6-alkoxyalkyl, C1-C6-alkoxycarbonyl, C1-C6-alkylcarbonyl, halogen, cyano, nitro, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4-alkyl; R is hydrogen, C1-C6-alkyl or halogen; R is hydrogen or C1-C6-alkyl; R is C1-C6-alkyl or C1-C6-alkoxy; l is 0, 1 or 2; n is 1 or 2; R is a rest of the formulas (IIa) or (IIb), in which the variables have the meanings stated in claim I. The invention also relates to methods for the preparation of said tricyclic pyrazolone derivatives, preparations containing same and the use of said derivatives or of preparations containing same as herbicides.
Abstract:
The invention relates to cycloalkyl-substituted benzoyl pyrazoles of formula (I) wherein said variables can, for example, have the following meanings: R = hydrogen, nitro, halogen, cyano, rhodano or an optionally substituted aliphatic radical; R = an optionally substituted aliphatic radical, halogen, nitro, in addition to substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-halogenalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C6-alkinyl; R , R = hydrogen, nitro, halogen, cyano, rhodano, an optionally substituted aliphatic radical or substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R = a cyclic ring system with 3 - 14 ring atoms; R = hydroxy or a substituted hydroxy group; in addition to tautomers or agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as pesticides.
Abstract:
The invention relates to a method for producing pyrazolylbenzoyl derivatives of formula (I), wherein the substituents have the meanings given in the description; characterised in that a pyrazolylbenzoyl derivative of formula (II), wherein the substituents R , R , R , A, B and D have the meanings given above, is treated with an inorganic or organic acid at a pH value
Abstract:
The invention relates to 3-(heterocyclyl)-benzoylpyrazole derivatives of formula (I), wherein the variables have the following meanings: X is O, NH or N-alkyl; R is nitro, halogen, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkyl-sulfonyl; R , R , R , R are hydrogen, alkyl or halogenalkyl; R is halogen, nitro, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkylsulfonyl; R is hydroxy, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarbonyloxy, (alkylthio)carbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, and the phenyl radical can be substituted; R , R are alkyl; R is hydrogen or alkyl; and R is hydrogen or alkyl; and to their agriculturally useable salts. The invention also relates to a method for producing these compounds and to their use or the use of products containing them for combating undesirable plants.
Abstract:
Die vorliegende Erfindung betrifft eine kristalline Form von 2-Chlor-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluormethyl)-1-(2H)-pyrimidinyl]-4-fluor-N-[[methyl-(1-methyl-ethyl)amino]sulfonyl]benzamid. Die Erfindung betrifft auch ein Verfahren zur Herstellung dieser kristallinen Form sowie Formulierungen für den Pflanzenschutz, welche diese kristalline Form des Phenyluracils enthalten.
Abstract:
The invention relates to a method for producing compounds of formula (I), whereby: a) a bicyclic olefin of formula (II) is reacted with haloform in the presence of a base to produce the ring-enlarged product of formula (III); b) the compound of formula (III) is hydrolyzed to produce the allyl alcohol of formula (IV); c) the allyl alcohol of formula (IV) is oxidized to produce the unsaturated ketone of formula (V); d) the ketone of formula (V) is reacted with a nucleophilic ion Y, which stabilizes a negative charge, to produce the ketone of formula (VI), and; e) the ketone of formula (VI) is hydrolyzed to produce the bicyclic 1,3-diketone of formula (I). In formulas (I) to (VI), R -R , X, Y and Z have the meanings as cited in the description. The invention also relates to novel intermediate products and to novel methods for producing these intermediate products.
Abstract:
The invention relates to tricyclic benzoylcyclohexanedione derivatives of formula (I), wherein the variables have the following meanings: X is oxygen, sulphur, S=O, S(=O)2, CR R , NR or a bond; y forms a saturated, partially saturated or unsaturated 5- or 6-membered heterocycle with the two carbons to which it is bonded; R , R , R , R is hydrogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is halogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, C1-C6- alkylthio halide, alkylsulfinyl, alkylsulfinyl halide, alkylsulfonyl, alkylsulfonyl halide, optionally substituted aminosulfonyl, or optionally substituted sulfonylamino; R is hydrogen, alkyl or halogen; m is 0, 1 or 2; R is hydrogen, alkyl, alkyl halide, alkylcarbonyl, formyl, alkoxycarbonyl, alkoxycarbonyl halide, alkylsulfonyl or alkylsulfonyl halide; and R is substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl)-methylidene; and to agriculturally useable salts thereof. The invention also relates to a method for producing the tricyclic benzoylcyclohexanedione derivatives, to products containing them and to the use of said derivatives or said products containing them for combating unwanted vegetation.
Abstract:
The invention relates to 3-(heterocyclyl)-substituted benzoylpyrazols of formula (I), wherein the variables have the following meanings: X is O, NH or N-alkyl; R is alkyl; R , R , R , R are hydrogen, alkyl or alkyl halide; R is halogen, nitro, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkylsulfonyl; R is hydroxy, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarbonyloxy, alkylthiocarbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, and the phenyl radical can be substituted; R , R are alkyl; R is hydrogen or alkyl; and R is hydrogen or alkyl; and to their agriculturally useable salts. The invention also relates to intermediate products and methods for producing the inventive compounds and to the use of these compounds or products containing them for combating undesirable plants.
Abstract translation:本发明涉及式(I)的3-(杂环基) - 取代的苯甲酰基吡唑,其中各变量具有以下含义:X为O,NH或N-烷基; R 1烷基; R 2,R 3,R 4,R 5,氢,烷基或卤代烷基; R 6是卤素,硝基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,烷基磺酰基或卤代烷基磺酰基; R 7是羟基,烷氧基,烯氧基,烷基磺酰氧基,烷基羰基氧基,烷基硫代羰基氧基,苯基磺酰氧基或苯基羰基氧基,其中苯基可以被取代; R 8,R 9烷基; R 10是氢或烷基; R 11是氢或烷基; 及其农业上有用的盐。 中间体及其制备过程; 以及这些化合物或含有它们的药剂用于防治有害植物的用途。