VERFAHREN ZUR HERSTELLUNG VON 2-CHLORMETHYLPHENYLESSIGSÄUREDERIVATEN
    11.
    发明申请
    VERFAHREN ZUR HERSTELLUNG VON 2-CHLORMETHYLPHENYLESSIGSÄUREDERIVATEN 审中-公开
    工艺制备2-CHLORMETHYLPHENYLESSIGSÄUREDERIVATEN

    公开(公告)号:WO2003072538A1

    公开(公告)日:2003-09-04

    申请号:PCT/EP2003/001160

    申请日:2003-02-06

    CPC classification number: C07C249/12 C07C251/48

    Abstract: Verfahren zur Herstellung von 2-Chlormethyl-phenylessigsäurederivaten der Formel (I), in der X für C l -C 4 -Alkoxy oder Methylamino steht, durch Etherspaltung von Verbindungen der Formel (II), in der R C l -C 4 -Alkyl, C 1 -C 4 -Alkoxy, C l -C 2 -Halogenalkyl, C 1 -C 4 -Alkylcarbonyl, C l -C 4 -Alkylcarbonyloxy, Halogen, Nitro oder Cyano bedeutet und X die obengenannte Bedeutung besitzt, dadurch gekennzeichnet, dass die Umsetzung in Gegenwart von Chlorwasserstoff und einem inerten Lösungsmittel stattfindet, und dem Reaktionsgemisch ein Katalysator ausgewählt aus der Gruppe: Eisen, Indium oder deren Halogenide, Oxide oder Triflate zugesetzt wird.

    Abstract translation: 一种制备的式(I)的2-氯甲基苯乙酸衍生物,其中X代表氯-C 4烷氧基或甲氨基,由式(II)的化合物的醚裂解,其中R是C1-C4烷基,C1-C4过程 烷氧基,CL-C2卤代烷基,C1-C4烷基羰基,CL-C4烷基羰基氧基,卤素,硝基或氰基,X具有上述定义,其特征在于,在氯化氢的存在下和惰性溶剂中发生反应, 和选自反应混合物中选出的催化剂:铁,铟或它们的卤化物,氧化物,或三氟甲磺酸加入。

    TRICYCLIC PYRAZOLONE DERIVATIVES
    13.
    发明申请
    TRICYCLIC PYRAZOLONE DERIVATIVES 审中-公开
    三环吡唑啉酮

    公开(公告)号:WO0059910A3

    公开(公告)日:2001-04-26

    申请号:PCT/EP0002564

    申请日:2000-03-23

    CPC classification number: C07D495/04 A01N43/90

    Abstract: The invention relates to tricyclic pyrazolone derivatives of the formula (I) in which the variables have the following meaning: R is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-haloalkoxy, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro or C1-C3-alkylsulfonyl, phenylsulfonyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro; R , R are hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, NR R , C2-C6-alkoxyalkyl, C1-C6-alkoxycarbonyl, C1-C6-alkylcarbonyl, halogen, cyano, nitro, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4-alkyl; R is hydrogen, C1-C6-alkyl or halogen; R is hydrogen or C1-C6-alkyl; R is C1-C6-alkyl or C1-C6-alkoxy; l is 0, 1 or 2; n is 1 or 2; R is a rest of the formulas (IIa) or (IIb), in which the variables have the meanings stated in claim I. The invention also relates to methods for the preparation of said tricyclic pyrazolone derivatives, preparations containing same and the use of said derivatives or of preparations containing same as herbicides.

    Abstract translation: 式(I),其中,所述Viarablen具有以下含义的吡唑啉酮三环衍生物; [R <1>是氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6烷硫基,C1-C6卤代烷硫基,C1-C6烷基亚磺酰基,C 1 -C C6-卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基亚磺酰,卤素,氰基或硝基; X是O或NR <2>; [R <2>的氢,C1-C6烷基,C1-C6-烷氧基,C1-C6卤代烷基,C1-C6-卤代烷氧基,任选地被C1-C3烷基,卤素,氰基,硝基或C1-C3烷基磺酰基取代的取代的 苯基或任选地被C1-C3烷基,卤素,氰基或硝基取代的苯磺酰基; [R <3>,R <4>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6烷硫基,C1-C6卤代烷硫基,C1-C6 烷基亚磺酰基,C1-C6-卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,NR <7> - [R <8>,C2-C6烷氧基烷基,C1-C6烷氧羰基,C1-C6烷基羰基,卤素, 氰基,硝基,任选地被C1-C3烷基,卤素,氰基或硝基subsitutiertes; [R <5>是氢或C1-C4烷基; [R <6>为氢,C1-C6烷基或卤素; [R <7>是氢或C1-C6烷基; [R <8> C1-C6烷基或C1-C6烷氧基; 1 0,1或2; n是1或2; [R <9>为基团(IIa)或(IIb)中,其中的变量具有权利要求1中所示的含义,用于制备三环吡唑啉酮衍生物,包含它们和使用这些衍生物或包含它们用于控制杂草的组合物的组合物的方法。

    N-CYCLOALKYL-3-ALKENYLBENZOYL-PYRAZOLE DERIVATIVES
    14.
    发明申请
    N-CYCLOALKYL-3-ALKENYLBENZOYL-PYRAZOLE DERIVATIVES 审中-公开
    N-环烷基-3- ALKENYLBENZOYL-吡唑衍生物

    公开(公告)号:WO0104096A2

    公开(公告)日:2001-01-18

    申请号:PCT/EP0005860

    申请日:2000-06-23

    CPC classification number: A01N43/56 C07D231/20

    Abstract: The invention relates to cycloalkyl-substituted benzoyl pyrazoles of formula (I) wherein said variables can, for example, have the following meanings: R = hydrogen, nitro, halogen, cyano, rhodano or an optionally substituted aliphatic radical; R = an optionally substituted aliphatic radical, halogen, nitro, in addition to substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-halogenalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C6-alkinyl; R , R = hydrogen, nitro, halogen, cyano, rhodano, an optionally substituted aliphatic radical or substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R = a cyclic ring system with 3 - 14 ring atoms; R = hydroxy or a substituted hydroxy group; in addition to tautomers or agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as pesticides.

    Abstract translation: 本发明的目的是式(I),其中变量具有环烷基取代的benzoylpyrazoles,例如,以下的含义:R t <1>为氢,硝基,卤素,氰基,氰硫基或任选取代的脂族基团; [R <2>是任选取代的脂族基,卤素,硝基,和取代的磺酰基或氨基; [R <3>是氢,卤素,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C2-C6烯基或C2-C6炔基; [R <4>,R <5>为氢,硝基,卤素,氰基,氰硫基,任选取代的脂族基或取代的磺酰基或氨基基团; [R <6>是氢,卤素,C1-C6烷基,C1-C6烷氧基,C3-C8环烷基; [R <7>具有3-14个环原子的环状环体系; [R <16>为羟基或取代羟基; 和互变异构体或可农用盐。 此外,本发明提供了制备式(I)的化合物的方法,是指含有它们,并使用式(I)和组合物的化合物的包含它们用于控制有害植物而言。

    TRICYCLIC BENZOYLCYCLOHEXANEDIONE DERIVATIVES
    19.
    发明申请
    TRICYCLIC BENZOYLCYCLOHEXANEDIONE DERIVATIVES 审中-公开
    三环benzoylcyclohexanedione衍生物

    公开(公告)号:WO0073311A3

    公开(公告)日:2001-04-19

    申请号:PCT/EP0004806

    申请日:2000-05-26

    CPC classification number: C07D495/04

    Abstract: The invention relates to tricyclic benzoylcyclohexanedione derivatives of formula (I), wherein the variables have the following meanings: X is oxygen, sulphur, S=O, S(=O)2, CR R , NR or a bond; y forms a saturated, partially saturated or unsaturated 5- or 6-membered heterocycle with the two carbons to which it is bonded; R , R , R , R is hydrogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is halogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, C1-C6- alkylthio halide, alkylsulfinyl, alkylsulfinyl halide, alkylsulfonyl, alkylsulfonyl halide, optionally substituted aminosulfonyl, or optionally substituted sulfonylamino; R is hydrogen, alkyl or halogen; m is 0, 1 or 2; R is hydrogen, alkyl, alkyl halide, alkylcarbonyl, formyl, alkoxycarbonyl, alkoxycarbonyl halide, alkylsulfonyl or alkylsulfonyl halide; and R is substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl)-methylidene; and to agriculturally useable salts thereof. The invention also relates to a method for producing the tricyclic benzoylcyclohexanedione derivatives, to products containing them and to the use of said derivatives or said products containing them for combating unwanted vegetation.

    Abstract translation: 式(I),其中各变量具有以下含义的三环benzoylcyclohexanedione衍生物:X是氧,硫,S = O,S(= O)2,CR <6> - [R <7>,NR <8>或键 ; Y共同与两个碳其所结合的,饱和,部分饱和或不饱和5或6元杂环; [R <1>,R <2>,R <6> - [R <7>是氢,烷基,卤代烷基,烷氧基或卤代烷氧基; [R <3>为卤素,烷基,卤代烷基,烷氧基或卤代烷氧基; [R <4>为氢,硝基,卤素,氰基,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,C1-C6卤代烷硫基,烷基亚磺酰基,卤代烷,烷基磺酰基,卤代烷基磺酰基,任选子氨基磺酰基,磺酰氨基或可能子..; [R <5>是氢,烷基或卤素; m是0,1或2; [R <8>是氢,烷基,卤代烷基,烷基羰基,甲酰基,烷氧基羰基,卤代烷氧基羰,烷基磺酰基或卤代烷基磺酰基; [R <9>取代的(3-氧代-1-环己烯-2-基) - 羰基,或取代的(1,3-二氧代-2-环己基)亚甲基; 及其可农用盐; 一种用于三环benzoylcyclohexanedione衍生物的制备方法; 含有它们并使用这些衍生物或包含它们用于控制不希望的植物的组合物的组合物。

Patent Agency Ranking