3-AMINOMETHYL-1-CYCLOHEXYLAMIN UND EIN VERFAHREN ZU DESSEN HERSTELLUNG
    11.
    发明申请
    3-AMINOMETHYL-1-CYCLOHEXYLAMIN UND EIN VERFAHREN ZU DESSEN HERSTELLUNG 审中-公开
    3-氨基甲基环己基胺1 AND METHOD FOR MAKING

    公开(公告)号:WO2010009994A2

    公开(公告)日:2010-01-28

    申请号:PCT/EP2009/058887

    申请日:2009-07-13

    CPC classification number: C07C211/36 C07B2200/09 C07C2601/14

    Abstract: Die vorliegende Erfindung betrifft 3-Aminomethyl-1-cyclohexylamin sowie ein Verfahren zu dessen Herstellung durch a) Umsetzung von Cyclohexenon mit Cyanwasserstoff in Gegenwart eines basischen Katalysators, b) durch Umsetzung des in Stufe a) erhaltenen Cyclohexanonnitrils mit Ammoniak in Gegenwart eines Iminbildungskatalysators, und c) Umsetzung des in Stufe b) erhaltenen 3-Cyanocyclohexylimin-haltigen Reaktionsgemisches mit Wasserstoff und Ammoniak an Hydrierkatalysatoren. Die vorliegende Erfindung betrifft weiterhin die Verwendung von 3-Aminomethyl-1-cyclohexylamin als Härter für Epoxyharze, als Zwischenprodukt bei der Herstellung von Diisocyanaten, als Starter bei der Herstellung von Polyetherolen und/oder als Monomer für die Polyamidherstellung.

    Abstract translation: 本发明涉及3-氨基甲基-1-环己基胺和用于通过其制备方法)在碱性催化剂的存在下反应与氰化氢环己烯酮,b)通过在步骤a)Cyclohexanonnitrils与氨在亚胺形成催化剂的存在下得到的产物反应,和 c))的步骤b中获得的产物进行反应与氢气和氨的加氢催化剂的反应混合物含有3- Cyanocyclohexylimin-。 本发明进一步涉及使用3-氨基甲基-1-环己基胺的作为固化剂的环氧树脂,如二异氰酸酯的制造中的中间体,如在聚醚多元醇和/或作为用于聚酰胺的制造的单体的制造中的起动器。

    PHENOLIC COMPLEXING AGENTS
    15.
    发明申请
    PHENOLIC COMPLEXING AGENTS 审中-公开
    酚醛复合状况

    公开(公告)号:WO1995006095A2

    公开(公告)日:1995-03-02

    申请号:PCT/EP1994002720

    申请日:1994-08-16

    Abstract: Phenolic derivatives have formulas (I) or (II), in which R stands for C6-C20-alkyl or -alkenyl that may be interrupted by one or several non-adjacent oxygen atoms, or for a group having the formulas: -O-CO-R , -CO-O-R -, -NH-CO-R , -NR -CO-R , -CO-NH-R , -CO-NR -R , -NH-SO2-R , -NR -SO2-R , -SO2-NH-R or -SO2-NR -R , in which R stands for C6-C20-alkyl or alkenyl that may be interrupted by one or several non-adjacent oxygen atoms, and R stands for C1-C4-alkyl; R and R stand for hydrogen or a group having the formula: -CH2-N(CH2COOM)2, in which M stands for hydrogen, an alkaline metal, ammonium or substitued ammonium, whereas at least one of the residues R or R must stand for a group having the formula: -CH2-N(CH2)COOM)2; and R stands for a group having the formulas: -CO-O-R , -CO-NH-R or CO-NR -R . These phenolic derivatives having formulas (I) or (II) are used as alkaline earth and heavy metal ion complexing agents in (a) powdery textile washing compositions; (b) technical detergent compositions for hard surfaces made of metal, plastics, lacquer or glass; (c) alkaline detergent compositions for the beverage and food processing industry; (d) dish-washing compositions; (e) bleaching baths for the paper and cellulose industry; (f) photographic bleaching and bleach-hardening baths; (g) pre-processing, bleaching and dyeing baths in the textile industry; (h) galvanisation baths and (i) fertilisers.

    Abstract translation: 酚衍生物(I)或用(II)其中R <1>的C6-C20烷基或烯基,其被一个或多个不相邻的氧原子可被中断,或下式基团:-O-CO- [R <5>,-CO-OR <5>,-NH-CO-R <5>,-NR <6> -CO-R <5>,-CO-NH-R <5>,-CO-NR <6> -R <5>,-NH-SO-R <5>,-NR <6> -SO 2 -R <5>,-SO 2 -NH-R <5>或-SO 2 NR <6> - [R <5>,其中R <5>是C6至C20的烷基或链烯基,其被一个或多个不相邻的氧原子取代可以被中断,并且R <6>是C1-C4烷基,R < 2>和R <3>是氢或下式基团:-CH 2 N(CH 2 COOM)2,其中M是氢,碱金属,铵或取代的铵,简称,其中R中的至少一个<2>或R <3>的基团,式:向-CH 2 -N(CH 2 COOM)2分别和R <4>是一个式的基团:-CO-或<5>,-CO-NH-R <5>,或CO- NR <6> -R <5>是,作为碱土金属和在(a)的粉末Textilwasc重金属离子络合剂 hmittelformulierungen,(b)工业清洗剂配方对于由金属,塑料,油漆或玻璃,(c)碱清洗剂配方用于饮料和食品工业硬表面,(d)中洗碟洗涤剂制剂,(E)在造纸和纸浆工业中的漂白浴,(F) 照相漂白和漂白定影液,在纺织工业中(克)预处理,漂白和染色浴,(H)电镀液,以及植物营养的(i)中。

    USE OF THIOUREA SALTS AS BRIGHTENERS FOR AQUEOUS-ACID GALVANIC NICKEL BATHS
    16.
    发明申请
    USE OF THIOUREA SALTS AS BRIGHTENERS FOR AQUEOUS-ACID GALVANIC NICKEL BATHS 审中-公开
    USE硫脲盐的ALS增白剂用于水性-ACID GALVANIC镍BATHS

    公开(公告)号:WO1994013862A1

    公开(公告)日:1994-06-23

    申请号:PCT/EP1993003383

    申请日:1993-12-02

    CPC classification number: C07C335/32 C25D3/12

    Abstract: Nickel-plated shaped parts are produced by galvanic precipitation of nickel from aqueous-acid baths which contain as essential constituents one or several nickel salts, one or several inorganic acids and one or several brighteners. As brighteners are used thiourea salts having general formula (I), in which R to R stand for hydrogen, C1 to C18-alkyl, which may be substituted by carboxyl groups, C1 to C4-alkoxycarbonyl groups or cyano groups, C2 to C12-alkenyl, C2 to C12-alkinyl, C5 to C8-cycloalkyl, C7 to C12-phenylalkyl or phenyl, which may be substituted by one or two C1 to C4-alkyl residues, C1 to C4-alkoxy residues, halogen atoms, hydroxyl groups, phenyl groups, phenyl residues or C1 to C4 alkoxycarbonyl groups; Y stands for a chemical bond or for linear or branched alkylene, alkenylene or alkinylene having each up to 20 C atoms; A stands for hydrogen or a group having the formulae: -CO-H, -CO-R , -CO-OH, -CO-OR , -CO-NR R , -CO-CH2-CO-OR , -O-CO-H, -O-CO-R , -NR -CO-R , -NR -CO-R , -OR , -SO2-R , -SO2-OH, -SO2-OR , -PO(PH)2, -PO(OH)(OR ), -PO(OR )2, OPO(OH)2, -OPO(PH)(PR ) or -OPO(OR )2 in which R stands for C1 to C12-alkyl, C2 to C12-alkenyl, C2 to C12-alkinyl, C5 to C8-cycloalkyl, C7 to C12-phenylalkyl or phenyl, which may be substituted by one or two C1 to C4-alkyl residues, halogen atoms, hydroxyl groups, phenyl residues or C1 to C4-alkoxycarbonyl groups; and R and R stand for hydrogen or C1 to C4-alkyl; n is a number from 1 to 4 and X stands for a water solubility-promoting, n-valent inorganic or organic anion.

    GRANULAR BLEACHING ACTIVATOR COMPOSITION WITH VARIOUSLY SHAPED GRAINS
    17.
    发明申请
    GRANULAR BLEACHING ACTIVATOR COMPOSITION WITH VARIOUSLY SHAPED GRAINS 审中-公开
    颗粒漂白活化剂组成与各种形状的谷物

    公开(公告)号:WO1993016161A1

    公开(公告)日:1993-08-19

    申请号:PCT/EP1993000181

    申请日:1993-01-27

    CPC classification number: C11D3/3935 C11D3/392 C11D17/0039

    Abstract: Granular bleaching activator composition with variously shaped grains containing as the core: A) 30 to 98 wt %, in relation to the total quantity of granular bleaching activator composition, of one or more 4H-3,1-benzo-oxazin-4- one derivatives of general formula (I) in which R is C1 to C4-alkyl, C1 to C4-alkoxy, chloromethyl, methoxy methyl, dimethylamino phenyl, o-, m- or p-tolyl, p-chlorophenyl, m-nitrophenyl, m-methoxy phenyl or m-methyl sulphonyl phenyl and R' is hydrogen, methyl, chloro, nitro, acetoxy or hydroxy, or a mixture of compounds (I) and other usual bleaching activators; and as the casing: B) 2 to 70 wt %, in relation to the total quantity of the granular bleaching activator composition, of one or more additives from the classes of substances: (1) anionic tensides; (3) non-ionic tensides; (3) hybrid ionic tensides; (4) carboxyl-group-containing polymers; (5) polysaccharides; (6) polyalkylene glycols; (7) acid alkaline and alkaline earth metal salts of inorganic acids; (8) aliphatic C8 to C18-monocarboxylic acids, aliphatic di and tricarboxylic acids, aromatic mono and dicarboxylic acids, the aforementioned carboxylic acids possibly also containing hydroxyl and amino groups in the molecule, and aliphatic C3 to C7-monohydroxycarboxylic acids.

    USE OF HETEROCYCLIC COMPOUNDS AS BLEACH ACTIVATORS OR OPTICAL LIGHTENERS IN WASHING AND CLEANING AGENTS
    18.
    发明申请
    USE OF HETEROCYCLIC COMPOUNDS AS BLEACH ACTIVATORS OR OPTICAL LIGHTENERS IN WASHING AND CLEANING AGENTS 审中-公开
    在洗涤和清洁剂中使用杂环化合物作为漂白活化剂或光学增亮剂

    公开(公告)号:WO1991008279A2

    公开(公告)日:1991-06-13

    申请号:PCT/EP1990001897

    申请日:1990-11-13

    CPC classification number: C07D265/22 C11D3/392 C11D3/42

    Abstract: Heterocyclic compounds of formula (I), where X stands for O, S or the N-R grouping, in which R stands for hydrogen, C1-C25 alkyl, C1-C25 acyl or an aryl group with up to 12 carbon atoms, Y stands for CH or N, R stands for X = S or N-R , hydrogen, a C1-C25 alkyl or C2-C25 alkenyl group or a phenyl residue which can be additionally substituted by one or two C1-C4 alkyl, C1-C4 alkoxy, hydroxyl, carboxyl, sulpho, amino, C1-C4 acylamino, nitro or cyano groups or chlorine or bromine atoms, whereby for two substituents these may be the same or different, R stands for X = O, phenyl, o-, m- or p-tolyl, p-chlorphenyl, m-nitrophenyl, m-methoxyphenyl or m-methylsulphonylphenyl, R stands for X = S or NR , hydrogen, a C1-C4 alkyl, C1-C4 alkoxy, hydroxyl, carboxyl, sulpho, amino or C1-C4 acylamino group or a chlorine or bromine atom and R stands for X = O or hydrogen, can be used as bleach activators or optical lighteners in washing and cleaning agents.

    Abstract translation: 式(I)的杂环化合物,其中X代表O,S或NR 3基团,其中R 3代表氢,C 1 -C 25烷基,C 1 -C 25酰基或芳基,最多12个 碳原子,Y代表CH或N,R 1代表X = S或NR 3,氢,C 1 -C 25烷基或C 2 -C 25烯基或苯基残基,其可以另外被一个或多个 两个C 1 -C 4烷基,C 1 -C 4烷氧基,羟基,羧基,磺基,氨基,C 1 -C 4酰基氨基,硝基或氰基或氯或溴原子,其中两个取代基可以相同或不同,R 1, 代表X = O,苯基,邻,间或对甲苯基,对氯苯基,间硝基苯基,间甲氧基苯基或间甲基磺酰基苯基,R 2代表X = S或NR 3,氢 ,C 1 -C 4烷基,C 1 -C 4烷氧基,羟基,羧基,磺基,氨基或C 1 -C 4酰氨基或氯或溴原子,R 2代表X = O或氢,可用作漂白活化剂 或洗涤剂和清洁剂中的光学增亮剂。

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