METHOD FOR SEPARATING HYDROGEN SULFIDE AND AMMONIA DISSOLVED IN SOUR WATERS
    12.
    发明申请
    METHOD FOR SEPARATING HYDROGEN SULFIDE AND AMMONIA DISSOLVED IN SOUR WATERS 审中-公开
    在水中分离硫化氢和氨水的方法

    公开(公告)号:US20160347625A1

    公开(公告)日:2016-12-01

    申请号:US14733265

    申请日:2015-06-08

    Applicant: PROSERNAT

    Abstract: In a column provided with internals for liquid/gas contacting, the sour water feedstock is stripped using steam, then cooled by a cold liquid and washed using cold water injection. This method allows to separate an ammonia-poor (5-5000 ppm) H2S gaseous effluent and an H2S-lean (100-1000 ppm for example) purified water. The method is yet improved by adding a second column that receives the purified water from the first column and separates the hydrogen sulfide and the ammonia according to the method operated in the first column. The purified water from the second column is preferably partially injected into the first and/or the second column as wash water. A facility for implementing the method according to the invention.

    Abstract translation: 在具有液体/气体接触的内部的柱中,使用蒸汽汽提酸水原料,然后用冷的液体冷却并用冷水注入进行洗涤。 该方法允许分离贫氨(5-5000ppm)H 2 S气态流出物和贫H2S(100-1000ppm)净化水。 通过添加从第一塔接收净化水的第二塔,根据第一塔中操作的方法分离硫化氢和氨,该方法得到改善。 来自第二塔的净化水优选以洗涤水部分地注入第一和/或第二塔。 一种用于实现根据本发明的方法的设备。

    REMOVAL OF AROMATIC HYDROCARBONS FROM LEAN ACID GAS FEED FOR SULFUR RECOVERY
    15.
    发明申请
    REMOVAL OF AROMATIC HYDROCARBONS FROM LEAN ACID GAS FEED FOR SULFUR RECOVERY 审中-公开
    从用于恢复硫酸的酸性气体中去除芳香烃

    公开(公告)号:WO2016174120A1

    公开(公告)日:2016-11-03

    申请号:PCT/EP2016/059461

    申请日:2016-04-28

    Applicant: PROSERNAT

    Abstract: The present invention is directed to a process for the removal of aromatic hydrocarbons from a lean acid gas containing less than 20 mol.% of H2S, comprising : a) contacting the lean acid gas stream (1) with a H 2 S-selective liquid absorbent solution (29) in a first absorption zone (2) to produce a gas stream depleted in H 2 S (3) and an absorbent solution enriched in H 2 S (4), b) introducing the absorbent solution (4) into a non-thermic stripping zone (8) where it is contacted with a stripping gas stream (7) to obtain an absorbent solution depleted in C 4 + aliphatic and aromatic hydrocarbons (9) and a stripping gas stream enriched in aromatic and C 4 + aliphatic hydrocarbons (10), c) contacting the stripping gas stream (10)obtained in step b) with a H 2 S-selective liquid absorbent solution (28) in a second absorption zone (12) to obtain a stripping gas stream depleted in H2S (13), and an absorbent solution enriched in H 2 S (14) d) introducing the absorbent solution (9) obtained in step b) into a desorption zone (16) wherein the H 2 S-selective liquid absorbent solution (17) is recovered and a lean acid gas is produced.

    Abstract translation: 本发明涉及从含有少于20mol%的H 2 S的贫酸性气体中除去芳族烃的方法,其包括:a)使贫酸性气流(1)与H 2 S选择性液体吸收剂溶液 (4)的吸收剂溶液中,b)将吸收剂溶液(4)引入非热剥离区(4)中, 8)在其中与汽提气流(7)接触以获得耗尽C4 +脂族和芳族烃(9)的吸收剂溶液和富含芳族和C 4 +脂族烃(10)的汽提气流,c)接触 步骤b)中获得的汽提气流(10)中的H2S选择性液体吸收剂溶液(28)在第二吸收区(12)中,以获得贫H2S(13)中的汽提气流,以及富含 H2S(14)d)引入步骤b)中获得的吸收剂溶液(9) 到解吸区(16),其中回收H 2 S选择性液体吸收剂溶液(17)并产生贫酸气体。

    EXTERNAL GAS MIXING PIPE FOR LIQUID-GAS CONTACTING UNIT
    17.
    发明申请
    EXTERNAL GAS MIXING PIPE FOR LIQUID-GAS CONTACTING UNIT 审中-公开
    用于液体 - 气体接触单元的外部气体混合管

    公开(公告)号:WO2017191482A1

    公开(公告)日:2017-11-09

    申请号:PCT/IB2016/000765

    申请日:2016-05-03

    Abstract: The present invention relates to a liquid-gas contacting unit (1) comprising a column (100), at least a lower packed bed (110) and a higher packed bed (120) positioned higher than the lower packed bed (110) inside the column (100), a gas-tight liquid collecting and redistributing device (130) disposed between the lower and the higher packed bed (110; 120) inside the column (100) and an external pipe (140) outside the column (100), the external pipe (140) comprising an inlet end (141), an outlet end (142) and a peripheral wall (143) between the inlet end (141) and the outlet end (142); the inlet end (141) being positioned between the lower packed bed (110) and the gas-tight liquid collecting and redistributing device (130) and the outlet end (142) being positioned between the higher packed bed (120) and the gas-tight liquid collecting and redistributing device (130). The present invention also relates to a method for improving the efficiency of a liquid-gas contacting unit by directing the gas from the lower packed bed to the higher packed bed through the external pipe.

    Abstract translation: 本发明涉及一种液 - 气接触单元(1),该单元包括塔(100),至少一个下部填充床(110)和一个位于其上方的高级填充床(120) 所述塔(100)内的下部填充床(110),设置在所述塔(100)内的所述下部填充床和所述较高填充床(110; 120)之间的气密液体收集和重新分配装置(130) (141)和出口端(142)之间的外部管(140),所述外部管(140)包括入口端(141),出口端(142)和外围壁(143) ; 所述入口端(141)位于所述下填充床(110)和所述气密液体收集和重新分配装置(130)之间,并且所述出口端(142)位于所述高填充床(120)和所述气体 - 致密液体收集和重新分配装置(130)。 本发明还涉及一种通过将来自下部填充床的气体引导通过外部管道到达较高填充床的方法来提高液体 - 气体接触单元的效率的方法。

    GAS REDIRECTING DEVICE FOR LIQUID-GAS CONTACTING COLUMN
    18.
    发明申请
    GAS REDIRECTING DEVICE FOR LIQUID-GAS CONTACTING COLUMN 审中-公开
    用于液体气体接触柱的气体更新装置

    公开(公告)号:WO2017072547A1

    公开(公告)日:2017-05-04

    申请号:PCT/IB2015/002178

    申请日:2015-10-30

    Abstract: The present invention relates to a gas-redirecting device (100) presenting an upper plane and a plurality of gas-redirecting tubes (3) comprising an inlet end and an outlet end. For each gas-redirecting tube, the orthogonal projections of the inlet end and the outlet end onto the upper plane have an over-lapping area of at most 50 % of the total area of the upper plane covered by the orthogonal projections. The present invention also relates to a liquid-gas contacting column (201) comprising such a gas-redirecting device (100), a floating support comprising such a liquid-gas contacting column, at least two packed beds (210, 220) and a method for improving the efficiency of a liquid-gas contacting column which is based on redirecting the gas from a wetted zone of a lower packed bed to a wetted zone of the higher packed bed, the liquid load through the wetted zone of the lower packed bed is different from the liquid load through the wetted zone of the higher packed bed.

    Abstract translation: 本发明涉及一种呈现上平面的气体改向装置(100)以及包括入口端和出口端的多个气体改向管(3)。 对于每个气体改向管,入口端和出口端在上平面上的正交投影具有重叠面积,该重叠面积至多为由正交投影覆盖的上平面的总面积的50%。 本发明还涉及一种包括这种气体改向装置(100)的液体 - 气体接触塔(201),包括这种液体 - 气体接触塔的漂浮支撑,至少两个填充床(210,220)和 提高液 - 气接触塔的效率的方法,该方法基于将气体从较低填充床的湿润区改向到较高填充床的湿润区,液体填料通过较低填充床的湿润区 与通过较高填充床的湿润区的液体负载不同。

    Removal of hydrogen sulfide and sulfur recovery from a gas stream by catalytic direct oxidation and claus reaction

    公开(公告)号:US10195565B2

    公开(公告)日:2019-02-05

    申请号:US15539257

    申请日:2015-12-23

    Applicant: PROSERNAT

    Abstract: A process for the removal of hydrogen sulfide and sulfur recovery from a H2S-containing gas stream by catalytic direct oxidation and Claus reaction through two or more serially connected catalytic reactors, wherein a specific control of the oxygen supplement is operated. The control and improvement of the process is obtained by complementing, in each major step of the process, the H2S-containing gas stream by a suitable flow of oxygen, namely before the H2S-containing gas stream enters the Claus furnace, in the first reactor of the process and in the last reactor of the process. Especially in application in a SubDewPoint sulfur recovery process the H2S/SO2 ratio is kept constant also during switch-over of the reactors R1 and R by adding the last auxiliary oxygen containing gas directly upstream the last reactor R so that the H2S/SO2 ratio can follow the signal of the ADA within a few seconds.

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