CHLORINE ATOMS INDUCED MOLECULAR INTERLOCKED NETWORK IN A NON-FULLERENE ACCEPTOR

    公开(公告)号:WO2020062254A1

    公开(公告)日:2020-04-02

    申请号:PCT/CN2018/109119

    申请日:2018-09-30

    Abstract: An acceptor-donor-acceptor (A-D-A) type non-fullerene acceptor IDIC-4Cl with indacenodithiophene (IDT) as core, and chlorinated 1, 1-dicyanomethylene-3-indanone (IC) as end groups, was designed and synthesized. The introduction of chlorine atoms can effectively decrease the LUMO and HOMO energy levels due to its ability to accommodate more electron density. From the single crystal structures of IDIC-4Cl, the Cl-substitution's intervention into the molecular configuration and packing mainly lies in three aspects: single molecule configuration, one direction of the intermolecular arrangement and 3D molecular packing. Firstly, the introduction of the chlorine atom in IDIC-4Cl leads to a more planar molecular configuration than the H or F substituted analogs due to the formation of molecular interlocked network induced by the strong Cl···S intermolecular interactions. Secondly, IDIC-4Cl shows the close π-π stacking distance and the smallest dihedral angle (0 degree) between adjacent molecules to form ideal J-aggregation, which should be beneficial for charge transportation between different connected molecules in this direction. Finally, the interlocked interactions between Cl and S atoms lead to a highly ordered 3D molecular packing, in which the end groups will form an ideal overlapped packing among different molecules, while the other two analogs with H or F show less ordered packing of their IC ending groups. OSCs based on IDIC-4Cl shows the highest power conversion efficiency (PCE) of 9.24%, with an open-circuit voltage of 0.83 V, a high short-circuit current density of 16.21 mA cm -2 , and a fill factor of 68.69%. These results demonstrate that chlorination is a very powerful strategy to prepare high performance small molecule acceptors because of its interlocked network molecular packing identity either in pristine acceptor or blend films. Meanwhile, chlorinated compounds are easily synthesized with lower price, which will be definitely beneficial for the large-scale production in next commercialization.

    METHODS FOR GENERATING AND CONTROLLING TERAHERTZ RADIATION

    公开(公告)号:WO2021229586A1

    公开(公告)日:2021-11-18

    申请号:PCT/IL2021/050564

    申请日:2021-05-14

    Abstract: Apparatus for generating THz (terahertz) radiation, the apparatus comprising: a substrate; a planar array of subwavelength antennas formed on the substrate having rotational symmetry, Cn, of order "n" greater than or equal to 3 and rotational symmetry cycle 2π/η, which are excitable by near infrared (NIR)_pump radiation to radiate THz radiation having wavelengths that are substantially larger than characteristic dimensions of the subwavelength antenna; wherein the array comprises a plurality of sections each comprising a plurality of subwavelength antennas exhibiting a spatial pattern different from that of an adjacent section of the plurality of sections.

    SENSOR DIELECTRIC LAYER AND PREPARATION METHOD AND USE THEREOF

    公开(公告)号:WO2020191947A1

    公开(公告)日:2020-10-01

    申请号:PCT/CN2019/094686

    申请日:2019-07-04

    Abstract: A sensor dielectric layer and a preparation method and a use thereof. The sensor dielectric layer comprises a porous material (1) and an ionic conductor liquid (2) filled in the pores of the porous material (1), and the porous material (1) is a non-transparent or semi-transparent material. The preparation method comprises: mixing the ionic conductor liquid (2) with the porous material (1), allowing them to stand to obtain the sensor dielectric layer. By filling the ionic conductor liquid, the sensor dielectric layer achieves the purpose of converting a non-transparent material into a transparent material, improves the sensing performance of the sensor, and can be applied to the fabrication of a highly transparent sensor device or the like.

    FLEXIBLE ELECTROMYOGRAPHIC ELECTRODE ARRAY, AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF

    公开(公告)号:US20250064371A1

    公开(公告)日:2025-02-27

    申请号:US18717530

    申请日:2022-04-24

    Abstract: A flexible electromyographic electrode array and a preparation method therefor, and an electromyographic signal collection apparatus and an electrophysiological signal collection method. The flexible electromyographic electrode array includes: a flexible substrate (100); several liquid metal electrodes, wherein the liquid metal electrodes are arranged on the flexible substrate (100), and the liquid metal electrodes each include a wire and a circuit board connection pattern (110) which is located at one end of a wire (120); and several electrode contacts (130), wherein each of the electrode contacts (130) is connected to the other end of the wire (120), and the electrode contacts (130) are made of a contact solution which contains a hydrophilic polymer and a poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate.

    A MULTIVIEW 3D IMAGE ENCODING METHOD, APPARATUS, SYSTEM AND STORAGE MEDIUM

    公开(公告)号:US20240406441A1

    公开(公告)日:2024-12-05

    申请号:US18691407

    申请日:2022-03-30

    Abstract: A multiview 3D image encoding method, apparatus, system and storage medium are provided. The encoding method may include the steps of acquiring image data, and obtaining depth information containing a depth value of each pixel in an image based on the image data; grouping the image data into blocks, and calculating a perceived angular resolution of each object in blocks based on the depth information of each object in blocks respectively, wherein the perceived angular resolution of an object in blocks is a required maximum angular resolution that enables identification of the object in blocks; and configuring a respective encoding parameter for each object in blocks based on the perceived angular resolution of a respective one object in blocks, where the encoding parameter is configured such that a requirement of respective encoding parameter for a respective object in blocks with a respective perceived angular resolution is met.

    SYSTEM AND METHOD FOR TREATING NITRATE NITROGEN SEWAGE BY CONSTRUCTED WETLAND

    公开(公告)号:US20240279097A1

    公开(公告)日:2024-08-22

    申请号:US18435022

    申请日:2024-02-07

    Abstract: A system for treating nitrate nitrogen sewage by autotrophic denitrification subsurface flow constructed wetland and a method thereof. The system includes a wetland pool body, a wetland substrate, a water distribution device, a water outlet device, and plants. The wetland substrate is filled in the wetland pool body. The wetland substrate includes pyrite, volcanic rock, and biochar. The water distribution device is located at the top of the wetland pool body to distribute water into the wetland pool body, and the water outlet device is located at the bottom of the wetland pool body to collect treated sewage. The plant is planted in the wetland substrate. The dissolved oxygen concentration of the system for treating nitrate nitrogen sewage by autotrophic denitrification subsurface flow constructed wetland is maintained at 1.2˜2.8 mg/L.

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