公开(公告)号：CA2835150C

公开(公告)日：2021-08-31

申请号：CA2835150

申请日：2012-05-07

Applicant: STAMICARBON B V ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： MOLINARI LUCIO ,  ANGELINI FABIO ,  BARBATO LUCIA

IPC: C01B3/02 ,  C01B3/04 ,  C01B17/04

Abstract: Disclosed is a process for the concurrent production of hydrogen and sulphur from a H2S-containing gas stream, with zero emissions. The method comprises the thermal oxidative cracking of H2S so as to form H2 and S2. Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The ratio H2S/O2 in the feedstock is higher than 2:1, preferably in the range of 3:1-5: 1.

公开(公告)号：CA2835470C

公开(公告)日：2020-06-23

申请号：CA2835470

申请日：2012-06-15

Applicant: STAMICARBON B V ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： IAQUANIELLO GAETANO ,  CUCCHIELLA BARBARA ,  ANTONETTI ELENA

IPC: C01B3/38 ,  C01B3/16 ,  C01B3/48 ,  C01B3/50

Abstract: The present invention relates to a method for hydrogen production and to a method of hydrogen and/or carbon dioxide production from syngas. The method comprises the steps of: (i) providing a gas stream comprising hydrogen and carbon monoxide, (ii) separating at least part of hydrogen from the stream yielding a hydrogen-depleted stream, (iii) subjecting the hydrogen- depleted stream to a water-gas shift reaction, and (iv) separating hydrogen from the stream resulting from step (iii). The method according to the invention improves the conversion of carbon monoxide in the water gas shift reaction and allows to increase the hydrogen production by 10-15% and to increase the overall energy efficiency of the system by 5-7%. The invention further relates to a plant for hydrogen and/or carbon dioxide production suitable for the method of the invention.

公开(公告)号：DK2969131T3

公开(公告)日：2020-03-23

申请号：DK14714415

申请日：2014-03-14

Applicant: STAMICARBON B V ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： COLOZZI MICHELE ,  PALO EMMA ,  CONTALDO PALMA ,  PEPE MARIA ROSARIA ,  PALMA VINCENZO ,  VAIANO VINCENZO

IPC: B01D53/14 ,  B01D53/48 ,  C10L3/10

公开(公告)号：EA033713B1

公开(公告)日：2019-11-19

申请号：EA201792339

申请日：2012-07-26

Applicant: STAMICARBON B V ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： IAQUANIELLO GAETANO ,  PALO EMMA ,  CONTALDO PALMA

IPC: C01B3/38 ,  C01B3/48 ,  C01B3/50 ,  C01B3/56

Abstract: Изобретениеотноситсяк способупроизводстваводородсодержащейгазовойсмеси, включающемуследующиестадии: (i) получениепредварительнонагретойсмеси, включающейископаемоетопливо, предпочтительнометан, ипар, (ii) проведениеадиабатическойреакциимеждуископаемымтопливоми паромв присутствиикатализатора, гдеобразуетсясмесьпродуктовпервойреакции, включающаяметан, водороди диоксидводорода, и (iii) проведениереакциириформингас участиемкислородав присутствиикатализаторамеждууказаннойсмесьюпродуктовпервойреакциии кислородсодержащимпотоком, гдекислородсодержащийпотоксодержитпоменьшеймере 40 об.% кислорода, врезультатечегообразуетсясмесьпродуктоввторойреакции, включающаяводороди моноксидуглерода. Изобретениетакжеотноситсяк системе, пригоднойдляпроизводстваводородаизподаваемогоуглеводородав соответствиис изобретением.

公开(公告)号：DK2736840T3

公开(公告)日：2019-06-11

申请号：DK12748570

申请日：2012-07-26

Applicant: STAMICARBON B V ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： IAQUANIELLO GAETANO ,  PALO EMMA ,  CONTALDO PALMA

IPC: C01B3/38 ,  C01B3/48 ,  C01B3/50 ,  C01B3/56

公开(公告)号：EA032087B1

公开(公告)日：2019-04-30

申请号：EA201391596

申请日：2012-05-07

Applicant: STAMICARBON B V ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： MOLINARI LUCIO ,  ANGELINI FABIO ,  BARBATO LUCIA

IPC: C01B3/02 ,  C01B3/04 ,  C01B17/04

Abstract: Описываетсяспосободновременногополученияводородаи серыиз HS-содержащегогазовогопотокас нулевымивыбросами. Способвключаеттермическийокислительныйкрекинг HS, чтобыполучить Hи S. Предпочтительноокислениепроводят, используяобогащенныйкислородомвоздух, предпочтительночистыйкислород. Отношение HS/Oвисходномсырьесоставляетболеечем 2:1, предпочтительнов диапазоне 3:1-5:1.

公开(公告)号：CA2837773C

公开(公告)日：2018-10-16

申请号：CA2837773

申请日：2012-06-25

Applicant: STAMICARBON B V ACTING UNDER THE NAME OF MT INNOVATION CENTER

Inventor： IAQUANIELLO GAETANO ,  CUCCHIELLA BARBARA ,  ANTONETTI ELENA

IPC: C01B3/38 ,  C01B3/48 ,  C07C273/04

Abstract: Disclosed is a process for the production of a syngas mixture by catalytic partial oxidation. The syngas mixture is suitable as an intermediate in the production of hydrogen. According to the invention, the syngas is cooled, prior to a water gas shift reaction, with liquid water. This has the advantage of avoiding the problem of metal dusting, and it presents a gas mixture comprising water vapor that is particularly suitable for a water gas shift reaction in the production of hydrogen.

公开(公告)号：IN162564B

公开(公告)日：1988-06-11

申请号：IN868MA1984

申请日：1984-11-14

Applicant: STAMICARBON B V NETHERLANDS

Inventor： KLEINT JENS LUDOVICUS ANNA LEO

IPC: C08C3/02

公开(公告)号：BR8404125A

公开(公告)日：1985-07-16

申请号：BR8404125

申请日：1984-08-17

Applicant: STAMICARBON B V SUBSIDIARIA LI

Inventor： GEENEN ALBERT ARNOLD VAN ,  BONGERS JOZEF JOHANNES MARIA ,  LOOS JOZEF LAMBERTUS MARIA VAN ,  VRINSSEN CORNELIS HENDRIKUS

IPC: C08G69/14 ,  C08G18/80 ,  C08G65/32 ,  C08G65/333 ,  C08G69/00 ,  C08G69/18 ,  C08G69/20 ,  C08G69/40 ,  C07D223/06 ,  C08G81/00

Abstract: The invention concerns an N-substituted carbamoyl-lactam compound characterized by the formula:where in the formula:- R is a polyol radical from a polyol having the formula R-(OH) xi , where xi is an integer ≥ 2- R' is an alkyl, whether or not cyclic aralkyl, alkaryl or aryl group, xi is an integer > 0,- (-L) is an unopened lactam ring and- (-L-) is an opened lactam block. The compounds are highly suited for use as activators in preparing nylon block copolymers.

公开(公告)号：IT7849052D0

公开(公告)日：1978-04-24

申请号：IT4905278

申请日：1978-04-24

Applicant: STAMICARBON B V NITTETU CHEMIC

IPC: C01B17/50 ,  C01B17/58 ,  C01C1/02 ,  C01C1/12 ,  C01C1/24 ,  C01C

Abstract: An improved process for the recovery of ammonia and sulphur dioxide from a by-product mixture containing an ammonium salt of sulphuric acid obtained as a by-product in the preparation of epsilon -caprolactam or cyclohexanone oxime. The by-product mixture is reacted, in finely divided form and at a temperature of from 700 DEG to 950 DEG C., with gases obtained from the combustion of a fuel in a controlled amount of oxygen, and ammonia and sulphur dioxide are thereafter separated from the resulting reaction mixture. The amount of oxygen is controlled to be less than the theoretical additional amount that would be required to convert the nitrogen, sulphur, hydrogen and carbon contained in the by-product mixture and fuel into, respectively, N2, SO2, H2O and CO2.