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    SELECTIVE NANOPARTICLE BASED ION BINDING NANOMATERIALS
    14.
    发明申请
    SELECTIVE NANOPARTICLE BASED ION BINDING NANOMATERIALS 审中-公开
    基于选择性纳米颗粒的离子结合纳米颗粒

    公开(公告)号：WO2012092304A1

    公开(公告)日：2012-07-05

    申请号：PCT/US2011/067443

    申请日：2011-12-27

    Applicant: MASSACHUSETTS INSTITUTE OF TECHNOLOGY ,  ENI SPA ,  CHO, Eun, Seon ,  STELLACCI, Francesco ,  CESTI, Pietro ,  BORRELLI, Raffaella

    Inventor： CHO, Eun, Seon ,  STELLACCI, Francesco ,  CESTI, Pietro ,  BORRELLI, Raffaella

    IPC: B82Y15/00 ,  G01N27/12

    CPC classification number: B82Y15/00 ,  G01N27/127

    Abstract: Nanoparticles with a patterned ligand coat can bind ions selectively. The ligand patterning can arise via self-assembly when two chemically dissimilar (e.g., in size and/or hydrophilicity) ligands are used together. One of the ligands can include one or more moieties capable of interacting with an ion, such as ether oxygens, hydroxyl groups, amine nitrogens, or other groups having a lone pair of electrons. Ion binding can be both selective and reversible.

    Abstract translation: 具有图案化配体涂层的纳米颗粒可以选择性地结合离子。 当两个化学不相似（例如，尺寸和/或亲水性）配体一起使用时，配体图案可以通过自组装产生。 配体之一可以包括能够与离子相互作用的一个或多个部分，例如醚氧基，羟基，胺氮或具有一对电子的其它基团。 离子结合可以是选择性的和可逆的。

    MONOLAYER-COATED SURFACES AS CATALYTIC PLATFORMS FOR ORGANIC REACTIONS
    15.
    发明申请
    MONOLAYER-COATED SURFACES AS CATALYTIC PLATFORMS FOR ORGANIC REACTIONS 审中-公开
    单层涂层表面作为有机反应的催化平台

    公开(公告)号：WO2009143406A3

    公开(公告)日：2010-01-14

    申请号：PCT/US2009044942

    申请日：2009-05-22

    Applicant: MASSACHUSETTS INST TECHNOLOGY ,  STELLACCI FRANCESCO ,  WUNSCH BENJAMIN

    Inventor： STELLACCI FRANCESCO ,  WUNSCH BENJAMIN

    IPC: B01J23/10

    CPC classification number: B01J31/226 ,  B01J2531/18

    Abstract: This invention provides a method for increasing the activity of catalysts. The method requires the introduction of the catalyst into nano- structured surfaces. The catalysts are introduced as functional groups in molecules forming a monolayer on a surface. A mixed monolayer of catalyst and inert molecules generates ordered domains of molecules on the surface. The catalyst is confined in regions of 0.5 nm to 3 nm in size and is surrounded by an inert material. The presence of such ordered domains that commensurate in size with the reactants, enhance the performance of the catalyst and increase the rate of the reaction.

    Abstract translation: 本发明提供了增加催化剂活性的方法。 该方法需要将催化剂引入纳米结构表面。 催化剂作为在表面上形成单层的分子中的官能团引入。 催化剂和惰性分子的混合单层在表面上产生分子的有序域。 催化剂被限制在大小为0.5nm至3nm的区域中并被惰性材料包围。 存在与反应物大小相当的有序域，增强了催化剂的性能并提高了反应速率。

    MONOLAYER-COATED SURFACES AS CATALYTIC PLATFORMS FOR ORGANIC REACTIONS
    16.
    发明申请
    MONOLAYER-COATED SURFACES AS CATALYTIC PLATFORMS FOR ORGANIC REACTIONS 审中-公开
    单层涂层表面作为有机反应的催化平台

    公开(公告)号：WO2009143406A2

    公开(公告)日：2009-11-26

    申请号：PCT/US2009/044942

    申请日：2009-05-22

    Applicant: MASSACHUSETTS INSTITUTE OF TECHNOLOGY ,  STELLACCI, Francesco ,  WUNSCH, Benjamin

    Inventor： STELLACCI, Francesco ,  WUNSCH, Benjamin

    IPC: B01J31/02

    CPC classification number: B01J31/226 ,  B01J2531/18

    Abstract: This invention provides a method for increasing the activity of catalysts. The method requires the introduction of the catalyst into nano- structured surfaces. The catalysts are introduced as functional groups in molecules forming a monolayer on a surface. A mixed monolayer of catalyst and inert molecules generates ordered domains of molecules on the surface. The catalyst is confined in regions of 0.5 nm to 3 nm in size and is surrounded by an inert material. The presence of such ordered domains that commensurate in size with the reactants, enhance the performance of the catalyst and increase the rate of the reaction.

    Abstract translation: 本发明提供了增加催化剂活性的方法。 该方法需要将催化剂引入纳米结构表面。 催化剂作为在表面上形成单层的分子中的官能团引入。 催化剂和惰性分子的混合单层在表面上产生分子的有序域。 催化剂被限制在大小为0.5nm至3nm的区域中并被惰性材料包围。 存在与反应物大小相当的有序域，增强了催化剂的性能并提高了反应速率。

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