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    PIGMENT STABILISATION
    13.
    发明申请
    PIGMENT STABILISATION 审中-公开
    镇定颜料

    公开(公告)号：WO1997007160A1

    公开(公告)日：1997-02-27

    申请号：PCT/EP1996003623

    申请日：1996-08-16

    Applicant: CLARIANT FINANCE (BVI) LIMITED ,  SANDOZ-PATENT-GMBH ,  LIGNER, Gilbert ,  STOLL, Klaus ,  THUERMER, Andreas ,  WEBSTER, Joseph, Reni

    Inventor： CLARIANT FINANCE (BVI) LIMITED ,  SANDOZ-PATENT-GMBH

    IPC: C08K05/3435

    CPC classification number: C08K5/3435 ,  C08K5/0041

    Abstract: Certain piperidine compounds having the formula (I) are used to protect natural or synthetic, organic or inorganic pigments or pigment mixtures in natural or synthetic polymer or prepolymer substrates against the negative effects of heat and/or light on light-fastness or colour stability, in particular against colour changes or light-induced discoloration. In the formula (I), R1 stands for hydrogen, hydroxyl, low-molecular alkyl, low-molecular alkoxy or acyl; R2 stands for a rest of aromatic character with one or two cores and optional substituents; R3 stands for oxygen, -NH- or -N(C1-4-alkyl)-; and all R8 independently represent hydrogen or methyl. Also disclosed is a master batch composition with at least one piperidine compound of formula (I), optionally at least one inorganic or organic pigment and a natural or synthetic material that is identical to or compatible with the natural or synthetic polymer or prepolymer substrate that is to be pigmented. In a process for protecting organic or inorganic pigments or pigment mixtures in synthetic polymer or prepolymer substrates against the negative effects of heat and/or light on light-fastness or colour stability, in particular against changes of colour or light-induced discoloration, an amount of at least one piperidine compound of formula (I) sufficient for stabilisation purposes is added as such or in the form of a master batch composition to the pigment or pigment mixture to be stabilised, or to the natural or synthetic polymer or prepolymer substrate that contains the pigment or pigment mixture.

    Abstract translation: 本发明涉及（I），式I的某些哌啶化合物，其中R1是氢，羟基，低级烷基，低级烷氧基或酰基，R 2是任选取代基承载的单 - 或双环基团，芳族特性的，R 3是氧，-NH-或 - N（C 1-4烷基） - 和所有R8独立地是氢或甲基，在用于稳定在天然或合成聚合物或预聚物的基板天然或合成的有机或无机颜料或颜料的混合物对热和/或光的不利影响 耐光性和颜色稳定性，尤其是针对光诱导衰落或色调偏移。 本发明还涉及一种母料组合物，其包括根据上述式（I）至少一种哌啶化合物，任选的至少一种无机或有机颜料，并与天然或合成材料，天然或合成聚合物或预聚物的基体是相同的或相容的着色 ， 本发明还通过增加一个到稳定提供了一种用于在合成聚合物或反对的热和/或光的耐光性和颜色稳定性的不利影响预聚合基板的有机或无机颜料或颜料的混合物的稳定化的方法，特别是针对在色调或光诱导褪色移 原样或以母料组合物的形式的式（I）的至少一种哌啶化合物的足够量的稳定化的颜料或颜料混合物或到含有天然或合成的聚合物或预聚物的衬底中的颜料或颜料混合物。

    RECIPROCATING PISTON, IN PARTICULAR MADE OF LIGHT METAL, FOR INTERNAL COMBUSTION ENGINES
    14.
    发明申请
    RECIPROCATING PISTON, IN PARTICULAR MADE OF LIGHT METAL, FOR INTERNAL COMBUSTION ENGINES 审中-公开
    往复式由包括合金用于内燃机

    公开(公告)号：WO1995015433A1

    公开(公告)日：1995-06-08

    申请号：PCT/DE1994001375

    申请日：1994-11-17

    Applicant: MAHLE GMBH ,  KLING, Jürgen ,  STOLL, Klaus

    Inventor： MAHLE GMBH

    IPC: F02F03/22

    CPC classification number: F16J1/08 ,  F01P3/08 ,  F02F3/00 ,  F02F3/22

    Abstract: In reciprocating pistons, in particular made of light metal, for internal combustion engines, and having in the piston head a closed cooling oil ring-shaped channel with an inlet and at least one outlet, the cooling oil is sprayed from the crankcase into the inlet of the cooling oil ring-shaped channel as a slanted free oil stream in relation to the piston axis. The inlet and outlet are positioned and sized for high stresses. A piston of this type has the following characteristics: (a) the length of the inlet (3) in the circumferential direction of the cooling oil ring-shaped channel (2) is slightly shorter than it would be required to directly collect the oil stream in all positions of the piston along its travel; (b) the inlet (3) is directly adjacent to one of two opposite hubs of the piston that receive a piston pin; (c) the total length of the inlet (3) equals maximum two thirds of the distance between the hubs of the piston in the circumferential direction; (d) the outlet (4) is round and has a diameter that corresponds to the radial width of the cooling oil ring-shaped channel.

    Abstract translation: 在往复运动由活塞，特别是轻金属有产用于内燃发动机具有在活塞的关闭头的供给和至少一个排放开口的冷却油环形管道，冷却油从曲轴箱斜向喷射到活塞轴为游离油喷射到冷却油环形管道的入口开口。 供应和排放口的位置和尺寸的设计必须高负荷。 这种活塞具有以下特征：（a）该供给开口（3）的冷却油环形通道的圆周方向（2）的长度略短于有必要在活塞（b）中的进料口的所有行程位置的喷油嘴的直接收集（ 3）直接邻接对置的活塞销接收在（c）中的进料口（3的总长度）是在活塞（d）中的轮毂之间的周边间距最多三分之二的出口开口（4）圆形，并具有与活塞的凸起的两个一 直径对应于冷却油环形通道的径向宽度。

    MICROPOROUS FILMS
    16.
    发明申请
    MICROPOROUS FILMS 审中-公开
    微孔膜

    公开(公告)号：WO2007039521A1

    公开(公告)日：2007-04-12

    申请号：PCT/EP2006/066753

    申请日：2006-09-26

    Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  KRISTIANSEN, Per Magnus ,  RÖMLING, Hartmut ,  STOLL, Klaus ,  KOLB, Markus

    Inventor： KRISTIANSEN, Per Magnus ,  RÖMLING, Hartmut ,  STOLL, Klaus ,  KOLB, Markus

    IPC: C08J5/18 ,  C08K5/20

    CPC classification number: C08J5/18 ,  C08J2323/12 ,  C08K5/20 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/12 ,  Y10T442/678 ,  C08L2666/06

    Abstract: A microporous film made of a composition containing A) 100 to 60 parts by weight of a polypropylene homopolymer, B) 0 to 40 parts by weight of a low density polyethylene or a polyethylene copolymer with butene, hexene or octene, and C) 0.005 to 0.5 % by weight, relative to the weight of component A), of at least one beta- nucleating agent selected from the class consisting of organic compounds containing trisamide moieties; the film having a water vapor-permeability of ≥ 200 g / m2 d at 23°C / 50 % r.h. or ≥ 800 g /m2 d at 23°C / 85 % r.h..

    Abstract translation: 一种由含有A）100〜60重量份的聚丙烯均聚物组成的微孔膜，B）0〜40重量份的低密度聚乙烯或具有丁烯，己烯或辛烯的聚乙烯共聚物，以及C）0.005〜 至少一种β-成核剂，相对于组分A）的重量为0.5重量％，其选自含有三酰胺部分的有机化合物; 该膜在23℃/ 50％r.h下具有= 200g / m 2的水蒸汽透过度。 或= 23℃时= 800g / m 2/85％r.h ..

    ADDITIVE MIXTURES
    17.
    发明申请
    ADDITIVE MIXTURES 审中-公开
    添加剂混合物

    公开(公告)号：WO2005030855A2

    公开(公告)日：2005-04-07

    申请号：PCT/EP2004/052263

    申请日：2004-09-22

    Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  STOLL, Klaus ,  HIRT, Urs ,  VAN DE LANGKRUIS, Judy

    Inventor： STOLL, Klaus ,  HIRT, Urs ,  VAN DE LANGKRUIS, Judy

    IPC: C08K5/15

    CPC classification number: C08K5/1575 ,  C08K5/1345 ,  C08K5/25 ,  C08L23/10

    Abstract: An additive mixture containing the components (A), (B) and optionally (C), wherein component (A) is at least one compound of the formula (I) wherein p is zero or 1; m and n are independently of one another an integer from zero to 3; and the radicals R are independently of one another C 1 -C 8 alkyl, C 1 -C 8 alkoxy, hydroxy, halogen, C 1 -C 8 alkylthio, C 1 -C 8 alkylsulfoxy or 2 radicals R form together with 2 adjacent carbon atoms of the unsaturated parent ring a 5- to 7-membered carbocyclic or heterocyclic ring; component (B) is at least one compound of the formula (II) wherein x and y are independently of one; another an integer from 2 to 10; the radicals A 1 , A 2 and A 3 are independently of one another C 1 -C 10 alkyl, C 5 -C 12 cycloalkyl unsubstituted or substituted by 1 to 3 C 1 -C 10 alkyl; phenyl unsubstituted or substituted by 1 to 3 C 1 -C 10 alkyl; or C 7 -C 12 phenylalkyl, and the radicals A 2 and A 3 are additionally hydrogen; with the proviso that at least one of the radicals A 1 and A 2 is branched C 3 -C 10 alkyl, C 5 -C 12 cycloalkyl unsubstituted or substituted by 1 to 3 C 1 -C 10 alkyl; phenyl unsubstituted or substituted by 1 to 3 C 1 -C 10 oalkyl; or C 7 ­-C 12 phenylalkyl; and component (C) is a lubricant or a mixture of lubricants.

    Abstract translation: 包含组分（A），（B）和任选的（C）的添加剂混合物，其中组分（A）是至少一种式（I）的化合物，其中p为0或1; m和n彼此独立地为0至3的整数; 并且基团R彼此独立地为C 1 -C 8烷基，C 1 -C 8烷氧基，羟基，卤素，C 1 -C 8烷硫基，C 1 -C 8烷基亚磺酰基或2个基团R与不饱和亲环的2个相邻碳原子一起形成5- 元环碳环或杂环; 组分（B）是至少一种式（II）的化合物，其中x和y独立地为一个; 另一个从2到10的整数; 基团A1，A2和A3彼此独立地为C1-C10烷基，未被取代或被1至3个C1-C10烷基取代的C5-C12环烷基; 未取代或被1至3个C 1 -C 10烷基取代的苯基; 或C7-C12苯基烷基，基团A2和A3另外是氢; 条件是基团A1和A2中的至少一个是支链C 3 -C 10烷基，未被取代或被1至3个C 1 -C 10烷基取代的C 5 -C 12环烷基; 未取代或被1至3个C 1 -C 10烷基取代的苯基; 或C7-C12苯基烷基; 组分（C）是润滑剂或润滑剂的混合物。

    STABILIZER COMPOSITIONS
    18.
    发明申请
    STABILIZER COMPOSITIONS 审中-公开
    稳定剂组合物

    公开(公告)号：WO1997049758A1

    公开(公告)日：1997-12-31

    申请号：PCT/IB1997000770

    申请日：1997-06-24

    Applicant: CLARIANT INTERNATIONAL LIMITED ,  CLARIANT FINANCE (BVI) LIMITED ,  MALIK, Jan ,  STOLL, Klaus ,  THUERMER, Andreas

    Inventor： CLARIANT INTERNATIONAL LIMITED ,  CLARIANT FINANCE (BVI) LIMITED

    IPC: C08K05/13

    CPC classification number: C08K5/13 ,  C08K5/49 ,  C08L23/04

    Abstract: The present invention relates to a stabilizer composition comprising a) at least one sterically hindered phenol, b) at least one phosphorus-containing secondary antioxidant, and c) at least one tocopherol compound wherein the weight ratio of component (a) to component (b) is from 2:1 to 1:4 and the weight ratio of component (a) to component (c) is from 2:1 to 10:1 for the stabilization of polyethylene-based thermoplastic polymers against degradation, cross-linking and/or discoloration due to the exposure to heat or light, especially in the presence of oxygen. A further aspect of the present invention is a masterbatch composition comprising the aforesaid stabilizer composition. A process for producing the stabilizer composition is similarly an object of the invention. The present invention also provides a method for enhancing the processing stability of polyethylene-based thermoplastic polymers comprising incorporating therein at any convenient stage of the processing a stabilizing quantity of the aforementioned stabilizer composition. The invention further embraces a stabilized polyethylene-based thermoplastic polymer and any article manufactured therefrom.

    Abstract translation: 本发明涉及稳定剂组合物，其包含a）至少一种空间位阻酚，b）至少一种含磷次级抗氧化剂，和c）至少一种生育酚化合物，其中组分（a）与组分（b ）为2:1至1:4，并且组分（a）与组分（c）的重量比为2:1至10:1，用于稳定聚乙烯基热塑性聚合物以降解，交联和/ 或由于暴露于热或光而变色，特别是在存在氧的情况下。 本发明的另一方面是包含上述稳定剂组合物的母料组合物。 制备稳定剂组合物的方法同样是本发明的目的。 本发明还提供一种提高聚乙烯类热塑性聚合物的加工稳定性的方法，其包括在任何方便的加工阶段将稳定剂量的上述稳定剂组合物并入其中。 本发明还包括稳定的聚乙烯基热塑性聚合物和由其制造的任何制品。

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