公开(公告)号：US20230183464A1

公开(公告)日：2023-06-15

申请号：US17997600

申请日：2021-05-03

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER

IPC: C08L25/06 ,  C08L25/10 ,  C08K5/00

CPC classification number: C08L25/06 ,  C08L25/10 ,  C08K5/005 ,  C08L2205/02

Abstract: A thermoplastic polymer composition (A) leads to reduced migration of stabilisers or other ingredients (I), if it contains e.g. 50 to 90 wt. %, relative to the polymer composition (A), of a thermoplastic polymer (P), which has migration barrier properties, as well as at least one stabiliser component (S) and/or a further ingredient (I), wherein the following is true for the polymer composition (A): a) the glass transition temperature Tg of the thermoplastic polymer (P) is greater than the use temperature; and b) the polymer-specific constant for polymers (Ap) of the thermoplastic polymer (P) is less than I; and c) the derived diffusion coefficient (Dp) of the thermoplastic polymer (P) for mineral oil is less than 10−12 cm2/s at 20° C.; and d) the morphology of the thermoplastic polymer (P) is either single-phase homogeneous, or two-phase heterogeneous.

公开(公告)号：US11591462B2

公开(公告)日：2023-02-28

申请号：US16495133

申请日：2018-03-14

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz

IPC: C08L25/14 ,  B29C45/00 ,  C08L25/12 ,  B29K25/00 ,  B29L31/30

Abstract: The invention relates to polymer blends of a styrene copolymer A selected from the group consisting of styrene acrylonitrile copolymers (SAN), styrene acrylonitrile maleic anhydride terpolymers (SMA), styrene acrylic copolymers, acrylonitrile butadiene styrene terpolymers (ABS), acrylonitrile butadiene styrene terpolymers with polyamide (ABS/PA), and acrylonitrile styrene acrylate terpolymers (ASA); and at least one copolymer B selected from the group consisting of styrene-butadiene block copolymers (SBC) and styrene-isoprene block copolymers (SIS); wherein the mold shrinkage of the polymer blend is reduced by at least 5% compared to the mold shrinkage of the pure styrene copolymer A.A process for the preparation of the polymer blends and the uses of the polymer blends in an injection molding process are described.

公开(公告)号：US11525052B2

公开(公告)日：2022-12-13

申请号：US16627448

申请日：2018-07-03

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Felix Rattay

IPC: C08L25/12 ,  C08L51/00 ,  C08F220/18 ,  C08K3/22 ,  C08K5/3432

Abstract: Thermoplastic styrene copolymer resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one transition metal oxide pigment B, (cl) at least one hindered amine UV light stabilizer C1, (c2) optionally at least one UV absorber C2 different from Cl, (d) optionally further polymer additives D, other than components B, C1, C2, and E, and (e) optionally one metal scavenger component E, wherein at least 99.0 wt.-% of the transition metal oxide pigment B consist of transition metal atoms and oxygen atoms.

公开(公告)号：US11512149B2

公开(公告)日：2022-11-29

申请号：US16338848

申请日：2017-10-02

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Wolfgang Fischer ,  Peter Ittemann ,  Florian Patcas ,  Michael Ruf

IPC: C08F2/01 ,  C08F2/06 ,  C08F2/34 ,  C08F212/10 ,  C08F220/14 ,  C08F220/44 ,  B01J19/18

Abstract: A method for producing a polymer from a first component and a second component using a reactor (50) offers technical advantages, wherein reaction heat produced in the reactor (50) is discharged via a boiling cooler (40) by supplying gaseous vapors produced in the reactor (50) to the boiling cooler (40). A product flow containing condensed vapors is returned to the reactor (50) from the boiling cooler (40) via a separation vessel (60), and an aqueous phase is separated from the product flow in the separation vessel (60). A system is provided for producing a polymer from a first component and a second component, comprising a reactor (50) and a boiling cooler (40) for discharging reaction heat produced in the reactor (50). A separation vessel (60) is arranged between the boiling cooler (40) and the reactor (50) such that a product flow containing condensed vapors is returned to the reactor (50) from the boiling cooler (40) via the separation vessel (60).

公开(公告)号：US11505688B2

公开(公告)日：2022-11-22

申请号：US16633284

申请日：2018-07-25

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Norbert Niessner ,  Eike Jahnke ,  Hans-Werner Schmidt ,  Tristan Kolb

IPC: C08L25/12 ,  C08L25/14 ,  C08J3/20

Abstract: A scratch-resistant thermoplastic polymer composition (P) comprising 88 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 5 wt.-% of at least one modified organopolysiloxane compound, and optionally at least one colorant, dye or pigment, and/or at least one further additive, provides with improved properties.

公开(公告)号：US20220363889A1

公开(公告)日：2022-11-17

申请号：US17767299

申请日：2020-10-12

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Oliver CARSTENSEN ,  Norbert NIESSNER ,  Eike JAHNKE ,  Yvonne van VEEN

IPC: C08L55/02 ,  C08L25/12 ,  C08L53/02

Abstract: The invention is directed to a thermoplastic recycling molding composition comprising recycled acrylonitrile-butadiene-styrene copolymer (r-ABS) as component A and virgin material as component B, wherein the component B is a mixture of at least two components selected from virgin thermoplastic polymers B1 and virgin lubricants B2, or wherein the component B is one or more polymer selected from polymers which are not homogenously miscible with rABS. Further, the present invention is directed to a process for the preparation of the thermoplastic recycling molding composition.

公开(公告)号：US11352487B2

公开(公告)日：2022-06-07

申请号：US15573658

申请日：2016-05-12

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Gisbert Michels

IPC: C08L25/12 ,  C08F279/04 ,  C08J3/00 ,  C08J3/14

Abstract: The present invention relates to thermoplastic molding compounds F containing at least two graft rubbers P-I and P-II which are processed by the co-precipitation of a mixture of the respective emulsions containing P-I and P-II. The present invention further relates to a method for producing such thermoplastic molding compounds F and to molded bodies obtained from a thermoplastic molding compound F according to the invention.

公开(公告)号：US20210277232A1

公开(公告)日：2021-09-09

申请号：US16330581

申请日：2017-09-07

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Bianca WILHELMUS ,  Norbert NIESSNER ,  Viktor WIEBE ,  Frank EISENTRAEGER

IPC: C08L77/02 ,  C08L55/02 ,  B33Y10/00 ,  B33Y70/00 ,  B33Y40/10 ,  B29C64/153 ,  B29C64/314

Abstract: The present invention relates to a thermoplastic polymer powder and to the use thereof as material for selective laser sintering (SLS). The polymer powder contains a partially crystalline polymer, an amorphous polymer and a compatibilizing agent, and optionally additional additives and/or auxiliary substances, wherein the partially crystalline polymer, the amorphous polymer and the compatibilizing agent are in the form of a polymer blend. The invention also relates to a method for producing the thermoplastic polymer powder and to a method of selective laser sintering (SLS).

公开(公告)号：US20210277202A1

公开(公告)日：2021-09-09

申请号：US16614162

申请日：2018-06-05

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Bianca WILHELMUS ,  Norbert NIESSNER ,  Hannes KERSCHBAUMER ,  Mohammed ABBOUD

IPC: C08J11/12 ,  C08L25/06 ,  C07C4/22 ,  C10G1/10 ,  C10B53/07

Abstract: The invention relates to a method for economically using styrene-containing plastic waste as raw material for new high-quality plastic products as part of a raw material recycling process, optionally having the steps of pre-treating a styrene-containing starting material, decomposing the styrene-containing starting material in a suitable reactor, discharging and collecting the resulting gases and condensing the low-molecular products in a suitable separator, separating the collected low-molecular components of the previous step by means of a fractioning distillation process, and optionally additionally decomposing the styrene oligomers in a steam cracker.

公开(公告)号：US20210163653A1

公开(公告)日：2021-06-03

申请号：US17267906

申请日：2019-08-27

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Wolfgang FISCHER ,  Ulrich JANSEN ,  Gisbert MICHELS

IPC: C08F285/00 ,  C08F6/00 ,  C08L51/00 ,  C08L55/02 ,  C08F212/08 ,  C08F220/44 ,  C08F2/22

Abstract: The present invention is directed to a process for the production of graft copolymer compositions which are based on acrylonitrile-styrene-acrylate (ASA) or acrylonitrile- butadiene-styrene (ABS) graft copolymers. The graft copolymers compositions are obtained by emulsion polymerization and afterwards precipitation, dewatering, drying and optionally cooling of the dried graft copolymer powder, wherein the graft copolymer B powder obtained is mixed with an aeration gas, preferably air and/or nitrogen, wherein the bulk density of the graft copolymer B powder is equal or less than 98.5% of the bulk density of the non-aerated graft copolymer B, during the whole aeration step. The graft copolymer powders show higher powder flowability and less tendency of caking during storage, for example in a silo.