O-COORDINATED METAL CHELATES AND THEIR USE IN OPTICAL RECORDING MEDIA HAVING HIGH STORAGE CAPACITY
    16.
    发明申请
    O-COORDINATED METAL CHELATES AND THEIR USE IN OPTICAL RECORDING MEDIA HAVING HIGH STORAGE CAPACITY 审中-公开
    O协调金属制品及其在具有高储存能力的光记录介质中的使用

    公开(公告)号:WO2005012228A1

    公开(公告)日:2005-02-10

    申请号:PCT/EP2004/051447

    申请日:2004-07-12

    Abstract: The invention relates to novel o ptical recording materials that comprise specific and in some cases novel diketone enamines or metal chelates thereof and that have excellent recording and playback quality especially ata wavelength of 350-500 nm. The invention accordingly relates to an optical recording medium comprising a substrate, a recording layer and optionally a reflecting layer, wherein the recording layer comprises a compound of formula (I), wherein M is hydrogen, aluminium or, preferably, a transition metal, which may in addition be coordinated with one or more further ligands and/or, for balancing out an excess charge, where applicable, may have an electrostatic interaction with one or more further ions inside or outside the coordination sphere, but M in formulae (Ib) and (Ic) is not hydrogen, Q is C-H, N or C-R 6 , it being possible for the stereochernistry of the C=Q double bond to be either E or Z. For the exact definitions of R 1 to R 6 reference should be made to the description. Also claimed are the novel compounds, especially tetracoordinated chelates, and a process for the preparation thereof.

    Abstract translation: 本发明涉及新颖的记录材料,其特别包括新颖的二酮烯胺或其金属螯合物,并且具有优异的记录和回放质量,特别是在350-500nm的波长。 因此,本发明涉及一种包括基底,记录层和任选地反射层的光学记录介质,其中记录层包含式(I)化合物,其中M是氢,铝或优选的过渡金属,其中 可以另外与一个或多个其它配位体配位和/或用于平衡过量电荷(如果适用的话)可以与配位球内部或外部的一个或多个另外的离子具有静电相互作用,而式(Ib) 和(Ic)不是氢,Q是CH,N或C-R6,C = Q双键的立体选择可能是E或Z。对于R1至R6的确切定义,应该进行参考 的描述。 还要求的是新化合物,特别是四配位螯合物,以及其制备方法。

    SUBSTITUTED PHTHALOCYANINES AND THEIR USE
    17.
    发明申请
    SUBSTITUTED PHTHALOCYANINES AND THEIR USE 审中-公开
    取代的邻苯二酚及其用途

    公开(公告)号:WO1998014520A1

    公开(公告)日:1998-04-09

    申请号:PCT/EP1997005223

    申请日:1997-09-24

    Abstract: This invention relates to a phthalocyanine or its metal complex of a divalent metal, oxometal, halogenometal or hydroxymetal, which comprises at least one unsubstituted or substituted formyl, carbonyl, hydroxymethyl or carboxyl group which is attached at the peripheral carbon skeleton. These phthalocyanines or their derivatives are used in recording layers of optical recording media. There is also claimed a novel process for the preparation of some of these compounds corresponding to formula (III),wherein M is div alent metal, oxometal, halogenometal or hydroxymetal, or 2 hydrogen atoms, X is halogen, or 2 X in vicinal position on a phenyl ring form together a -C=C-C=C- bridge so that an additional phenyl ring is obtained, Y is -OR1, -OOC-R2, -NHR1, -N(R1)R2 or -SR1, x is 0 or a number from 1 to 8, y depending on z is a number from z to 4, and z is a number from 1 to 4, by reacting a compound of formula (IV), wherein M, X, Y, x and y are as defined in formula (III), with z mol each of dimethylformamide and phosphoryl chloride.

    Abstract translation: 本发明涉及一种二价金属,氧化金属,卤素金属或羟基金属的酞菁或其金属络合物,其包含至少一个在外围碳骨架附着的未取代或取代的甲酰基,羰基,羟甲基或羧基。 这些酞菁或其衍生物用于光记录介质的记录层。 还要求一种用于制备对应于式(III)的一些这些化合物的新方法,其中M是疏水金属,氧化金属,卤素金属或羟基金属,或2个氢原子,X是卤素,或2位在相邻位置 在苯环上形成一个-C = C C = C-桥,使得得到另外的苯环,Y是-OR1,-OOC-R2,-NHR1,-N(R1)R2或-SR1,x为0 或数字1至8,y取决于z是z至4的数,z为1至4的数,通过使式(IV)化合物(其中M,X,Y,x和y) 如式(III)中所定义,zmol为二甲基甲酰胺和磷酰氯。

    ORGANIC LIGHT EMITTING SYSTEMS
    20.
    发明申请
    ORGANIC LIGHT EMITTING SYSTEMS 审中-公开
    有机发光系统

    公开(公告)号:WO2009092671A3

    公开(公告)日:2009-10-08

    申请号:PCT/EP2009050494

    申请日:2009-01-16

    CPC classification number: C09K11/06 C07F15/0033 H05B33/14 H05B33/28

    Abstract: Novel electrophosphorescent copolymers of the composition [A1]x1, [A2]x2, [A3]x3, [A4]x4, [A5]x5 wherein the structural units A1, A2, A3, A4 and/or A5 are in blocks or at random, and the copolymer is linear or crosslinked, and A1 is an organic radical of a phosphorescent light emitting moiety; A2 is an organic radical providing host functionality; A3 is an organic radical providing electron transport functionality; A4 is an organic radical providing hole transport functionality; A5 is a radical derived from aliphatic or aromatic organic monomers; x1 is a number from 1 to about 1000; x2, x3, x4 and x5 independently are numbers from 0 to about 100 000, with the proviso that the sum (x1 + x2 + x3 + x4 + x5) is at least 5, especially greater than 9; are characterized in that A1 contains a metal benzotriazole complex moiety or A2 is selected from repeating unit(s) of the formulae (III), (IV), where the symbols are as defined in claim 1. The novel copolymers are useful as active materials e.g. in electroluminescent devices.

    Abstract translation: 组合物[A1] x1,[A2] x2,[A3] x3,[A4] x4,[A5] x5的新型电致磷光共聚物,其中结构单元A1,A2,A3,A4和/或A5是块或在 无规,共聚物是直链或交联的,A1是磷光发光部分的有机基团; A2是提供主体功能的有机基团; A3是提供电子传递功能的有机基团; A4是提供空穴传输功能的有机基团; A5是衍生自脂族或芳族有机单体的基团; x1是从1到约1000的数字; x2,x3,x4和x5独立地为0至约100000的数字,条件是(x1 + x2 + x3 + x4 + x5)之和至少为5,特别大于9; 其特征在于A1含有金属苯并三唑配合物部分或A2选自式(III),(IV)的重复单元,其中符号如权利要求1中所定义。新型共聚物可用作活性材料 例如 在电致发光器件中。

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