公开(公告)号：KR100336679B1

公开(公告)日：2002-05-13

申请号：KR1019997005640

申请日：1998-10-07

Applicant: 로레알

Inventor： 롱도크리스띤

IPC: A61K8/40 ,  A61K8/41 ,  A61Q5/10

CPC classification number: A61K8/49 ,  A61K8/418 ,  A61K8/492 ,  A61K8/4926 ,  A61K8/494 ,  A61K8/4946 ,  A61K8/496 ,  A61Q5/065 ,  A61Q5/10

Abstract: 본 발명은, 염색에 적합한 매질 중에, 적합하게 선택된 양이온성 직접 염료 하나 이상과 니트로벤젠 직접 염료 하나 이상을 포함하는, 케라틴 섬유, 특히 모발과 같은 인간 케라틴 섬유의 염색을 위한 바로 사용가능한 조성물, 뿐만 아니라 이 조성물을 사용한 염색 방법에 관한 것이다.

Abstract translation: 准备使用含有直接阳离子染料（I; II; III和/或III'）和直接硝化苯染料（优选式（IV））的角蛋白纤维，特别是人发的染色组合物。 阳离子染料具有下式：D = N或-CH; R 1和R 2 = H，任选被CN，OH，NH 2，4'-氨基苯基取代的1-4C烷基，或者其与苯环上的C原子连接，形成可含有额外的O或N的杂环， 被一个或多个1-4C烷基取代; R3和R'3 = H，卤素，CN，1-4C烷氧基或乙酰氧基; X =阴离子，优选Cl，甲基硫酸盐或乙酸盐; A = 19个给定的单环或双环含N +杂环中的任一个; R6 = H或1-4C烷基; R7 = H，任选地被CN，NH 2，4'-氨基苯基取代的烷基，或与R6一起形成可以含有另外的O或N并可被1-4C烷基取代的杂环; R8和R9 = H，卤素，1-4C烷基或烷氧基或CN; B = 6个给定的单环和双环含N +杂环的任何一个; R 13 = H，1-4C烷氧基，卤素或氨基; R 14 = H，1-4C烷基，或者其与苯环上的C原子连接，形成可以含有环氧并可被一个或多个1-4C烷基取代的杂环; R 15 = H或卤素; R16和R17 = H或1-4C烷基; D1和D2 = N或CH; m = 0或1，使得当R 13是未取代的氨基时，则D1和D2均为CH且m为零; E = 9个给定的含有N +的单环和双环杂环中的任何一个。 优选的直接硝化苯染料为式（IV）。 R18 =可以被1-4C烷基，1-4C单羟基烷基，2-4C多羟基烷基，氨基烷基，单烷基和二烷基氨基烷基，脲基烷基或芳基任选被一个或多个 更多的OH，COOH，氨基或二烷基氨基; R19 = H，NH2，OH，1-4C烷基或烷氧基，1-4C单羟基烷基或烷氧基，2-4C多羟基烷基或烷氧基，1-4C氨基烷氧基或氨基，被1-4C烷基单取代或二取代 1-4C单羟基烷基，2-4C多羟基烷基，1-4C氨基烷基，单和二1-4C烷基氨基1-4C烷基，1-4C脲基或任选被一个或多个OH，COOH取代的芳基， 氨基或二烷基氨基; R 2 O = H，卤素，1-4C烷基或硝基该组合物可进一步包含：（1）一种或多种氧化碱如对亚苯基二胺或对氨基苯酚，（2）一种或多种成色剂如 - 亚苯基二胺或间氨基苯酚，（3）氧化剂如过氧化氢或过氧化脲，（4）和酶如过氧化物酶和两种电子氧化还原酶。 阳离子染料优选包含0.001-10％，特别是0.05-5％的组合物，硝化苯染料占组合物的0.0005-15％，特别是0.005-10％。 还要求保护包含含有两种类型的染料和氧化碱和/或成色剂的第一部分和包含氧化剂的第二部分的两部分试剂盒。

公开(公告)号：KR1020010062853A

公开(公告)日：2001-07-07

申请号：KR1020000087154

申请日：2000-12-30

Applicant: 로레알

Inventor： 꼬따르프랑소와 ,  롱도크리스띤

IPC: A61K8/34 ,  A61Q5/10

CPC classification number: A61K8/342 ,  A61K8/817 ,  A61K8/87 ,  A61Q5/10

Abstract: PURPOSE: Provided are ready-to-use oxidation dyeing compositions that resist running and tend to remain well-confined to the site of application. Additionally, such compositions may favor more intense and more chromatic (radiant) shades, while exhibiting low selectivities and good fastness toward chemical agents (shampoo, permanent waving and the like) and/or natural agents (light, perspiration and the like), and while offering the hair good cosmetic properties. CONSTITUTION: The cosmetic composition for oxidation dyeing keratin fibers, comprising, in a dyeing medium (1) at least one oxidation dye, (2) at least one thickening polymer comprising at least one fatty chain, and (3) at least one fatty alcohol comprising more than twenty carbon atoms. Where, the keratin fibers are chosen from human keratin fibers chosen from human hair; and the at least one fatty alcohol comprising more than twenty carbon atoms is chosen from behenyl alcohol and erucyl alcohol and is a mixture of fatty alcohols comprising at least 30% by weight of at least one fatty alcohol comprising more than twenty carbon atoms.

Abstract translation: 目的：提供抵抗运行的易于使用的氧化染色组合物，并且倾向于保持良好地限制在施用部位。 此外，这种组合物可以有利于更强烈和更有色（辐射）色调，同时对化学试剂（洗发剂，永久挥发等）和/或天然剂（轻，汗水等）具有低选择性和良好的牢度，以及 同时提供头发好的化妆品性质。 构成：用于氧化染色角蛋白纤维的化妆品组合物，其包含在染色介质（1）中至少一种氧化染料，（2）至少一种包含至少一个脂肪链的增稠聚合物，和（3）至少一种脂肪醇 包含二十多个碳原子。 其中角蛋白纤维选自人类头发中的人角蛋白纤维; 并且包含二十多个碳原子的至少一种脂肪醇选自二十二烷醇和芥酸，并且是包含至少30重量％的至少一种包含多于20个碳原子的脂肪醇的脂肪醇的混合物。

公开(公告)号：KR1020010062852A

公开(公告)日：2001-07-07

申请号：KR1020000087148

申请日：2000-12-30

Applicant: 로레알

Inventor： 꼬따르프랑소와 ,  롱도크리스띤

IPC: A61K8/84 ,  A61K8/34 ,  A61Q5/10

CPC classification number: A61K8/8147 ,  A61K8/39 ,  A61K8/817 ,  A61Q5/10

Abstract: PURPOSE: Provided are compositions for oxidation dyeing of keratin fibers, in particular human keratin fibers such as hair, comprising, in a dyeing medium, at least one oxidation dye, at least one thickening polymer comprising at least one fatty chain and at least one fatty alcohol chosen from monoglycerolated and polyglycerolated fatty alcohols. CONSTITUTION: The cosmetic composition for oxidation dyeing keratin fibers, comprises, in a dyeing medium (1) at least one oxidation dye, (2) at least one thickening polymer comprising at least one fatty chain, and (3) at least one fatty alcohol chosen from monoglycerolated and polyglycerolated fatty alcohols. Where, the keratin fibers are chosen from human keratin fibers chosen from human hair; the at least one fatty alcohol chosen from monoglycerolated and polyglycerolated fatty alcohols is chosen from fatty alcohols of formula: RO-(-CH2-CH(CH2OH)-O-)n-H in which: R is chosen from linear and branched, saturated and unsaturated groups comprising from 8 to 40 carbon atoms; and n is a number ranging from 1 to 30.

Abstract translation: 目的：提供角蛋白纤维，特别是人角蛋白纤维如毛发的氧化染色的组合物，其在染色介质中包含至少一种氧化染料，至少一种包含至少一种脂肪链的增稠聚合物和至少一种脂肪酸 选自单甘油和聚甘油脂肪醇的醇。 构成：用于氧化染色角蛋白纤维的化妆品组合物在染色介质（1）中包含至少一种氧化染料，（2）至少一种包含至少一个脂肪链的增稠聚合物，和（3）至少一种脂肪醇 选自单甘油和聚甘油脂肪醇。 其中角蛋白纤维选自人类头发中的人角蛋白纤维; 选自单甘油和聚甘油脂肪醇的至少一种脂肪醇选自下式的脂肪醇：RO - （ - CH2-CH（CH2OH）-O-）nH，其中：R选自直链和支链，饱和和不饱和的 包含8至40个碳原子的基团; n为1〜30的数。

公开(公告)号：KR1020010031197A

公开(公告)日：2001-04-16

申请号：KR1020007004140

申请日：1999-07-28

Applicant: 로레알

Inventor： 롱도크리스띤

IPC: A61K8/44 ,  A61K8/49 ,  A61K8/41 ,  A61Q5/10

CPC classification number: A61K8/416 ,  A61K8/49 ,  A61K8/492 ,  A61K8/4926 ,  A61K8/494 ,  A61K8/4946 ,  A61K8/4953 ,  A61Q5/065

Abstract: 본 발명은 적합한 염색용 매질내에 특정 화학식의 양이온성 직접 염료 하나 이상을 함유하는, 케라틴 섬유, 특히 모발과 같은 인간의 케라틴 섬유 염색용 조성물에 관한 것으로, 이것은 하나 이상의 사차 암모늄염을 함유하는 것을 특징으로 한다. 본 발명은 또한 이를 사용한 방법 및 장치에 관한 것이다.

公开(公告)号：KR1020000011486A

公开(公告)日：2000-02-25

申请号：KR1019990026861

申请日：1999-07-05

Applicant: 로레알

Inventor： 롱도크리스띤

IPC: C09B44/00 ,  A61Q5/10 ,  A61K8/40

CPC classification number: A61Q5/065 ,  A61K8/49 ,  A61K8/4926 ,  A61K8/494 ,  A61K8/4946 ,  A61K8/4953

Abstract: PURPOSE: A keratin fiber coloring compound consisting of positive ionic direct dyeing compound and more than one of viscosity-increasing polymer(which containing more than one of sugar unit) in adequate medium for coloring is provided, which colors human hair keratin strongly and non-selectively. Also provided are coloring methods and equipment. CONSTITUTION: A keratin fiber coloring compound contains more than one of positive ionic direct dyeing compound(chemical formula 1, 2, 3, or 3a) and more than one of viscosity-increasing polymer(which containing more than one of sugar unit). Positive ionic direct dyeing compound is desirably 0.001-10wt%(more desirably 0.005-5wt%) and viscosity-increasing polymer is desirably 0.01-10wt%, especially 0.1-5wt% to total weight of coloring compound.

Abstract translation: 目的：提供由正离子直接染色化合物和多于一种增粘聚合物（含有多于一种糖单元）组成的角蛋白纤维着色化合物，在适当的着色介质中，其强烈和非 - 选择性。 还提供着色方法和设备。 构成：角蛋白纤维着色化合物含有多种阳离子直接染色化合物（化学式1，2，3或3a）和多于一种增粘聚合物（含有多于一种糖单元）。 正离子直接染色化合物优选为0.001-10重量％（更优选0.005-5重量％），增粘聚合物优选为着色化合物总重量的0.01-10重量％，特别是0.1-5重量％。

公开(公告)号：KR100843521B1

公开(公告)日：2008-07-03

申请号：KR1020047016022

申请日：2003-04-11

Applicant: 로레알

Inventor： 꼬따르프랑소와 ,  롱도크리스띤

IPC: A61K8/58 ,  A61K8/41 ,  A61Q5/10

CPC classification number: A61Q5/10 ,  A61K8/25

Abstract: 본 발명의 주제는 물을 기재로 한 화장품에 적합한 매질 및 염기성 pH 하에서, 1종 이상의 산화 염료, 소디움 메타실리케이트 및 암모니아수로 이루어진 알칼리화제를 함유하는, 인간 케라틴 섬유, 특히 모발의 산화 염색용 조성물 및 이 조성물을 사용한 염색 방법에 관한 것이다.

公开(公告)号：KR100355641B1

公开(公告)日：2002-10-09

申请号：KR1019990027052

申请日：1999-07-06

Applicant: 로레알

Inventor： 롱도크리스띤 ,  랑제라르 ,  꼬떼레쟝

IPC: C09B44/00 ,  A61K8/58

CPC classification number: A61Q5/065 ,  A61K8/49 ,  A61K8/4926 ,  A61K8/494 ,  A61K8/4946 ,  A61K8/4953

Abstract: A dye composition for keratinic fibers, especially hair, comprises at least one compound (I), (II), (III), (III') or (IV), and at least one polymeric thickener. A dye composition for keratinic fibers, especially hair, comprises at least one compound of formula (I), (II), (III), (III') or (IV), and at least one polymeric thickener. D, D1, D2 = N or -CH; R1, R2 = H, 1-4C alkyl, (optionally substituted), 4'-aminophenyl or forms with a carbon of the benzene a heterocycle (optionally containing O or N and optionally substituted); R3, R'3 = H, halo, cyano, 1-4C alkyl, 1-4C alkoxy or acetyloxy; X , X' = anion; A = a group of formula (A1); R4 = 1-4C alkyl (optionally substituted); R5 = 1-4C alkoxy; R6, R11, R12, R16, R17 = H or 1-4C alkyl; R7 = H, alkyl (optionally substituted) or 4'-aminophenyl; NR6R7 = heterocycle (optionally containing O or N, and optionally substituted); R8, R9 = H, halo, 1-4C alkyl, 1-4C alkoxy or cyano; B' = a group of formula (B'3); R, R', R10 = 1-4C alkyl; R13 = H, halo, 1-4C alkoxy or amino; R14 = H, 1-4C alkyl or forms with a carbon of the benzene a heterocycle (optionally containing O or N, and optionally substituted); R15 = H or halo; m, r = 0 or 1; E = a group of formula (E1); G = a group of formula (G1)-(G3); R18 = 1-4C alkyl, phenyl (optionally substituted by halo or 1-4C alkyl); R19, R21 = 1-4C alkyl or phenyl; R20, R31, R32 = H, 1-4C alkyl or phenyl; R20 + R21 = in (G1) a substituted benzene or in (G2) an optionally substituted benzene; Z = O, S or -NR19; M, K', P' = -CH, -CR or -NR22(X' )r; R22 = O-, 1-4C alkyl or 1-4C alkoxy; R23, R24 = H, halo, 1-4C alkyl, 1-4C alkoxy or nitro; J = a group of formula (J1) or 5- or 6-membered nitrogen and/or carbonyl containing heterocycle (optionally substituted), preferably a group of formula (J2); R25 = H, halo, 1-4C alkyl, 1-4C alkoxy, hydroxy, nitro, -NHR28, -NR29R30, -NHCO(1-4C alkyl); R26 = H, halo, 1-4C alkyl, 1-4C alkoxy; R27 = H, hydroxy, -NHR28 or -NR29R30; R28 = H, 1-4C alkyl, 1-4C monohydroxyalkyl, 2-4C polyhydroxyalkyl or phenyl; R25 + R26, R26 + R27, R26 + R28 = 5- or 6-membered heterocycle containing at least one N, S or O; R29, R30 = 1-4C alkyl, 1-4C monohydroxyalkyl or 2-4C polyhydroxyalkyl; Y' = -CO- or -C(CH3)=; U' = not defined; n = 0 or 1; and with provisos. The full definition is given in the Definition (Full Definition) Field. Independent claims are also included for: (1) a method of dyeing hair by applying the composition and optionally rinsing and washing; (2) a kit comprising two compartments to be mixed before application, one comprising a cationic direct colorant and optionally at least one oxidation base and the other comprising at least one oxidizing agent. One of the compartments comprises the polymeric thickener.

公开(公告)号：KR100329413B1

公开(公告)日：2002-03-20

申请号：KR1019990019063

申请日：1999-05-26

Applicant: 로레알

Inventor： 롱도크리스띤

IPC: C09B44/10 ,  C09B67/22

CPC classification number: A61Q5/065 ,  A61K8/49 ,  A61K8/4926 ,  A61K8/494 ,  A61K8/4946 ,  A61K8/496

Abstract: 본 발명은, 염색에 적당하고 산화효소 또는 산화환원효소가 없는 매질내에, 주어진 화학식의 하나 이상의 양이온성 직접 염료를 함유하는 케라틴 섬유용, 특히 모발과 같은 인간 케라틴 섬유용 직접 염료 조성물에 관한 것이고, 상기 조성물은 또한 하나 이상의 특정 폴리올 및/또는 폴리올 에테르를 함유하는 것을 특징으로 한다.
본 발명의 주제는 또한 상기 조성물을 이용한 염색 방법 및 장치이다.

公开(公告)号：KR1020010062854A

公开(公告)日：2001-07-07

申请号：KR1020000087155

申请日：2000-12-30

Applicant: 로레알

Inventor： 꼬따르프랑소와 ,  롱도크리스띤

IPC: A61K8/34 ,  A61K8/39 ,  A61Q5/10

CPC classification number: A61Q5/10 ,  A61K8/342 ,  A61K8/39

Abstract: PURPOSE: Provided are ready-to-use oxidation dyeing compositions that resist running and tend to remain well-confined to the site of application. Additionally, such compositions may favor more intense and more chromatic (radiant) shades, while exhibiting low selectivities and good fastness toward chemical agents (shampoo, permanent waving and the like) and/or natural agents (light, perspiration and the like), and while offering the hair good cosmetic properties. CONSTITUTION: The composition for oxidation dyeing keratin fibers, such as human keratin fibers like hair, comprises, in a dyeing medium, (1) at least one oxidation dye, (2) at least one fatty alcohol comprising more than twenty carbon atoms, (3) optionally at least one fatty alcohol having at most twenty carbon atoms, (4) at least one oxyalkylenated nonionic surfactant with an HLB greater than 5, and (5) optionally at least one oxyalkylenated surfactant with an HLB at most equal to 5, in a proportion such that the weight ratio £(4)|/£(2)+(3)+(5)| is less than or equal to 1:1.

Abstract translation: 目的：提供抵抗运行的易于使用的氧化染色组合物，并且倾向于保持良好地限制在施用部位。 此外，这种组合物可以有利于更强烈和更有色（辐射）色调，同时对化学试剂（洗发剂，永久挥发等）和/或天然剂（轻，汗水等）具有低选择性和良好的牢度，以及 同时提供头发好的化妆品性质。 构成：用于氧化染色角蛋白纤维如人头发角蛋白纤维的组合物在染色介质中包含（1）至少一种氧化染料，（2）至少一种包含多于20个碳原子的脂肪醇（ 3）任选的至少一种具有至多20个碳原子的脂肪醇，（4）至少一种HLB大于5的氧化亚烷基化非离子表面活性剂，和（5）任选至少一种HLB至多等于5的氧化烯化表面活性剂， 以使得重量比£（4）| /£（2）+（3）+（5）|的比例 小于或等于1：1。

公开(公告)号：KR1020010062850A

公开(公告)日：2001-07-07

申请号：KR1020000087119

申请日：2000-12-30

Applicant: 로레알

Inventor： 베보세실 ,  롱도크리스띤 ,  꼬따르프랑소와 ,  부디프랑소와

IPC: A61K8/49 ,  A61K8/41 ,  A61K8/84

CPC classification number: A61Q5/10 ,  A61K8/817 ,  A61K8/84 ,  A61K2800/5426

Abstract: PURPOSE: Provided are cosmetic compositions for oxidation dyeing keratin fibers, such as human keratin fibers like hair, comprising, in a dyeing medium, (1) at least one oxidation dye, and (2) a combination comprising at least one cyclo homopolymer of dialkyldiallylammonium and at least one other particular quaternary polyammonium. CONSTITUTION: The composition for oxidation dyeing keratin fibres comprises, in an appropriate dyeing medium, at least one oxidation dye, and additionally comprises at least one cyclo homopolymer of dialkyldiallylammonium comprising, as a constituent of the chain, at least one unit of structure (I): at least one quaternary polyammonium polymer chosen from: (i) polymers comprising repeating units of formula(II) and (ii) polyquaternary ammonium polymers comprising repeating units of formula(lIl). In the formula(I), k and t, which may be identical or different, are each chosen from 0 and 1, with the proviso that the sum of k+t is equal to 1; R12, which may be identical or different, are each chosen from hydrogen atoms and methyl groups; R10 and R11, which may be identical or different, are each chosen from alkyl groups comprising from 1 to 22 carbon atoms, hydroxyalkyl groups, and C1-C4 amidoalkyl groups; R10 and R11, together with the nitrogen atom to which they are commonly bonded, may additionally form at least one heterocyclic group; and Y is an anion. In the formula(II), R1, R2, R3 and R4, which may be identical or different, are each chosen from alkyl groups comprising from 1 to 4 carbon atoms and hydroxyalkyl groups comprising from 1 to 4 carbon atoms; n and p, which may be identical or different, are each chosen from integers ranging from 2 to 20; and X is an anion chosen from anions derived from inorganic acids and anions derived from organic acids. And in the formula(3), p is an integer ranging from 1 to 6, D is chosen from direct bonds and -(CH2)r-CO- groups, wherein r is a number equal to 4 or 7, and X is an anion chosen from anions derived from inorganic acids and anions derived from organic acids.

Abstract translation: 目的：提供用于氧化染色角蛋白纤维的化妆品组合物，例如人类角蛋白纤维如毛发，在染色介质中包含（1）至少一种氧化染料，和（2）包含至少一种二烷基二烯丙基铵的环均聚物 和至少一种其它特定的季铵多铵。 构成：用于氧化染色角蛋白纤维的组合物在合适的染色介质中包含至少一种氧化染料，并且另外包含至少一种二烷基二烯丙基铵的环均聚物，其包含作为链的组分的至少一个结构单元（I ）：至少一种季铵聚铵聚合物，其选自：（i）包含式（II）的重复单元的聚合物和（ii）包含式（III）的重复单元的聚季铵化聚合物。 在式（I）中，k和t可以相同或不同，各自选自0和1，条件是k + t的和等于1; R12可以相同或不同，各自选自氢原子和甲基; R10和R11可以相同或不同，各自选自含有1至22个碳原子的烷基，羟基烷基和C 1 -C 4酰氨基烷基; R10和R11与它们通常键合的氮原子一起可另外形成至少一个杂环基; Y为阴离子。 在式（II）中，可以相同或不同的R 1，R 2，R 3和R 4各自选自含有1至4个碳原子的烷基和包含1至4个碳原子的羟烷基; n和p可以相同或不同，各自选自2至20的整数; X是选自阴离子的阴离子，其衍生自无机酸和衍生自有机酸的阴离子。 在式（3）中，p是1至6的整数，D选自直接键和 - （CH 2）r -CO-基，其中r是等于4或7的数，X是 阴离子选自阴离子衍生自无机酸和阴离子衍生自有机酸。