Abstract:
PURPOSE: An analyzed material detection method at the liquid-liquid interface capable of using a surface-enhanced Raman scattering activated particle is provided to directly collect a SERS signal in the liquid without the necessity of the surface-enhanced Raman scattering activated substrate before the improvement of reproducibility and the SERS signal detection, and is provided to directly collect the SERS signal without an additional step such as an after treatment of the nano particle. CONSTITUTION: An analyzed material detection method at the liquid-liquid interface capable of using a surface-enhanced Raman scattering activated particle is comprised of the following steps. The hydrophilicity or the lipophilic property SERS activation nano particle distribution liquid is provided. A sample including the analyzed material is provided to the distribution liquid. The metal nano load is added to the sample. The lipophilic property or the hydrophilic material is added to the mixture of the analyzed material and the distribution liquid of the SERS activated particle. If the distribution liquid has the lipophilic property the hydrophilic material is added and if the distribution liquid has the hydrophilicity the lipophilic material is added. The laser is irradiated on the liquid-liquid interface and horizontally to the interface in the wavelength necessary for the conduction of the SERS activation. The SERS signal is detected and the concentration or presence of the analyzed material is determined.
Abstract:
플라즈모닉탐침체인금속나노입자를그래핀산화물로기능화시켜국부적표면플라즈몬공명(LSPR) 센서를제조하고, 이를방향족휘발성유기화합물의검출에이용한다. 이에따라, 친화도가낮은방향족휘발성유기화합물과금속나노입자탐침체간파이-파이상호작용(pi-pi stacking)을통해결합력을높일수 있다. 또한, 암시야현미경을이용하여단일플라즈모닉탐침체의 LSPR 특성변화를관찰함으로써방향족휘발성유기화합물을높은재현성과민감도로감지할수 있다. 또한, 종래와달리기판제작단계를간소화할 수있고, 단위입자수준에서의분석을통해분석에사용되는샘플의부피를현저히감소시킴으로써, 소량의실제시료를간단하게분석할수 있다.
Abstract:
PURPOSE: A device for detecting an analyte using surface-enhanced Raman scattering (SERS) active particles on the liquid-liquid interface is provided to improve the sensitivity of SERS by the orientation of active particles such as metal nano particles on the liquid-liquid interface. CONSTITUTION: A device for detecting an analyte using SERS active particles on the liquid-liquid interface includes a cylindrical tube. The cylindrical tube is utilized for detecting the existence or the concentration of the analyte using the arrangement of the SERS active nano particles on the hydrophilic liquid-lipophilic liquid interface. The width of the central portion of a body made of a transparent material is shorter than the length of the widest width on the upper or lower part of the central unit of the body. A ratio of the width of the central unit with respect to the length of the widest width is about 5:1 to 10:1.