公开(公告)号：KR1020100028702A

公开(公告)日：2010-03-15

申请号：KR1020080087550

申请日：2008-09-05

Applicant: 서울대학교산학협력단

Inventor： 송인규 ,  정지철 ,  이호원 ,  김희수

IPC: B01J23/00 ,  B01J23/16 ,  B01J37/02 ,  B01J37/04

CPC classification number: B01J23/31 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  C07C11/167

Abstract: PURPOSE: A multicomponent bismuth-molybdate catalyst, a method of producing thereof, and a method of producing 1,3-butadiene using thereof are provided to obtain the 1,3-butadiene with high yield using a C4 distillate with a lot of impurities as a reactant directly. CONSTITUTION: A multicomponent bismuth-molybdate catalyst is used to produce 1,3-butadiene from a C4 distillate including normal-butane and normal-butene by an oxidative dehydration, which essentially contains bismuth and molybdenum component and a metallic component with divalent or trivalent cation. The metallic component with divalent or trivalent cation is selected from the group consisting of cobalt, nickel, zinc, magnesium, manganese, copper, iron, potassium, sodium, aluminum, vanadium, zirconium, tungsten and silicon.

Abstract translation: 目的：提供一种多组分钼酸铋催化剂及其制备方法，以及使用该方法制备1,3-丁二烯的方法，使用具有大量杂质的C 4馏出物以高产率获得1,3-丁二烯 直接反应。 构成：使用多组分钼酸铋催化剂通过氧化脱水从包含正丁烷和正丁烯的C4馏出物生产1,3-丁二烯，其基本上含有铋和钼组分以及具有二价或三价阳离子的金属组分 。 具有二价或三价阳离子的金属组分选自钴，镍，锌，镁，锰，铜，铁，钾，钠，铝，钒，锆，钨和硅。

公开(公告)号：KR1020090103424A

公开(公告)日：2009-10-01

申请号：KR1020080029032

申请日：2008-03-28

Applicant: 에스케이이노베이션 주식회사 ,  에스케이종합화학 주식회사 ,  서울대학교산학협력단

Inventor： 정영민 ,  권용탁 ,  김태진 ,  이성준 ,  김용승 ,  오승훈 ,  송인규 ,  김희수 ,  정지철 ,  이호원

IPC: C07C5/32 ,  C07C5/327 ,  C07C11/167

CPC classification number: C07C5/42 ,  C07C2523/80 ,  C07C2523/887 ,  C07C11/167

Abstract: PURPOSE: A method for producing 1,3-butadiene from n-butene using continuous-flow dual-bed reactor with excellent catalyst reproducibility is provided to obtain 1,3-butadiene at high yield by maximizing activity of oxidation-dehydrogenation of n-butene. CONSTITUTION: A method for producing 1,3-butadiene from n-butene using continuous-flow dual-bed reactor comprises the steps of: laminating and filling a bismuth molybdate-based first catalyst and a ferrite-based second catalyst, which are a catalyst-fixed layer on a reactor by a quartz layer so that a separated laminated layer is formed; performing oxidation-dehydrogenation while consecutively passing a C4 mixture including normal butane and a reactant containing air and steam through a catalyst layer of the reactor; and obtaining 1,3-butadiene.

Abstract translation: 目的：提供使用具有优异催化剂再现性的连续流动双床反应器从正丁烯生产1,3-丁二烯的方法，通过使正丁烯氧化脱氢的活性最大化，以高产率获得1,3-丁二烯 。 构成：使用连续流动双床反应器从正丁烯生产1,3-丁二烯的方法包括以下步骤：层压和填充钼酸铋基第一催化剂和作为催化剂的铁酸盐基第二催化剂 - 混合层，通过石英层在反应器上形成分离的层压层; 进行氧化脱氢，同时使含有正丁烷的C4混合物和含有空气和蒸汽的反应物通过反应器的催化剂层; 并得到1,3-丁二烯。