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    포스페이트기를 갖는 기질에 대한 선택적 형광 화학센서 및이를 이용한 분석방법
    11.
    发明公开
    포스페이트기를 갖는 기질에 대한 선택적 형광 화학센서 및이를 이용한 분석방법 无效
    用于含磷磷酸盐的选择性荧光化学传感器及其相同的磷酸盐测定

    公开(公告)号：KR1020090032453A

    公开(公告)日：2009-04-01

    申请号：KR1020070097713

    申请日：2007-09-28

    Applicant: 재단법인서울대학교산학협력재단 ,  삼성전자주식회사

    Inventor： 홍종인 ,  이현우

    IPC: G01N21/64 ,  G01N21/00 ,  C07G99/00 ,  G01N33/533

    Abstract: A selective fluorescent chemosensor for phospate-containing substrate and an analysis method using the same are provided to perform fluorescence probe, which is important for body control mechanism of cells, due to the high preference for phosphate. A selective fluorescent chemosensor for phospate-containing substrate contains fluorescence, a linker giving elasticity to the fluorescence, a phosphate combining portion of binuclear metal complex form, and a central supporting moiety for controlling the degree of freedom in the combination of phospate-containing substrate and the stacking of fluorescent.

    Abstract translation: 提供了含磷酸盐底物的选择性荧光化学传感器和使用其的分析方法，由于对磷酸盐的偏好，因此进行对细胞的体内机制控制重要的荧光探针。 用于含磷酸盐底物的选择性荧光化学传感器包含荧光，给荧光弹性的接头，双核金属络​​合物形式的磷酸盐结合部分和用于控制含磷酸盐底物和 荧光灯堆叠。

    유기 금속 화합물, 이를 이용한 유기 전계 발광 소자 및그의 제조방법
    14.
    发明公开
    유기 금속 화합물, 이를 이용한 유기 전계 발광 소자 및그의 제조방법 有权
    有机金属化合物，使用该化合物的有机电致发光显示器件及其制备方法

    公开(公告)号：KR1020070075042A

    公开(公告)日：2007-07-18

    申请号：KR1020060003311

    申请日：2006-01-11

    Applicant: 삼성에스디아이 주식회사 ,  재단법인서울대학교산학협력재단

    Inventor： 박수진 ,  신대엽 ,  양남철 ,  권태혁 ,  김명기 ,  홍종인

    IPC: C07F15/00 ,  C09K11/06 ,  H05B33/00

    CPC classification number: H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/185 ,  H01L51/5024

    Abstract: Organic metal compounds, organic electroluminescence display devices by using the same compounds and a preparation method thereof are provided to improve luminescence property and solubility by increasing their molecular weight through connection of a host compound and a dopant compound, so that luminescence efficiency, brilliance, color purity and life-time properties of the organic electroluminescence display device are improved. The organic metal compounds wherein the host compound and dopant compound are connected, represented by the formula(1) are provided, wherein X is X1, X2 or X3; R1 to R9 are each independently a mono-substituted or multi-substituted function group, and hydrogen, cyano group, hydroxyl group, thiol group, halogen atom, optionally substituted C1-C30 alkyl group, optionally substituted C1-C30 alkoxy group, optionally substituted C2-C30 alkenyl group, optionally substituted C6-C30 aryl group, optionally substituted C6-C30 arylalkyl group, optionally substituted C6-C30 aryloxy group, optionally substituted C2-C30 heteroaryl group, optionally substituted C2-C30 heteroarylalkyl group, optionally substituted C2-C30 heteroaryloxy group, optionally substituted C5-C30 cycloalkyl group, optionally substituted C2-C30 heterocycloalkyl group, optionally substituted C1-C30 alkylcarbonyl group, optionally substituted C7-C30 arylcarbonyl group, C1-C30 alkylthio group, -Si(R')(R")(R"') group or -N(R')(R") group; R', R" and R"' are each independently hydrogen or C1-C30 alkyl group; M is Ir, Os, Pt, Pb, Re or Ru; L is a bidentate ligand; and m is 3, n is 1 or 2, and a, b and c are each independently an integer from 1 to 3.

    Abstract translation: 提供有机金属化合物，通过使用相同化合物的有机电致发光显示装置及其制备方法，以通过连接主体化合物和掺杂剂化合物增加其分子量来提高发光性能和溶解度，从而使得发光效率，亮度，颜色 提高了有机电致发光显示装置的纯度和寿命特性。 提供其中由式（1）表示的连接有主体化合物和掺杂剂化合物的有机金属化合物，其中X为X 1，X 2或X 3; R 1至R 9各自独立地为单取代或多取代的官能团，氢，氰基，羟基，硫醇基，卤素原子，任选取代的C 1 -C 30烷基，任选取代的C 1 -C 30烷氧基， 任选取代的C 6 -C 30芳烷基，任选取代的C 6 -C 30芳氧基，任选取代的C 2 -C 30杂芳基，任选取代的C 2 -C 30杂芳基烷基，任选取代的C 2 -C 30芳基， C30杂芳氧基，任选取代的C 5 -C 30环烷基，任选取代的C 2 -C 30杂环烷基，任选取代的C 1 -C 30烷基羰基，任选取代的C 7 -C 30芳基羰基，C 1 -C 30烷硫基，-Si（R'）（R “）（R”'）基团或-N（R'）（R“）基团; R'，R”和R“'各自独立地为氢或C 1 -C 30烷基; M为Ir，Os，Pt，Pb ，Re或Ru; L是双齿配体; m是3，n是1或2，a d a，b和c各自独立地为1〜3的整数。

    유기 금속 화합물, 이를 이용한 유기 전계 발광 소자 및그의 제조방법
    15.
    发明授权
    유기 금속 화합물, 이를 이용한 유기 전계 발광 소자 및그의 제조방법 有权
    유기금속화합물，이를이용한유기전계발광소자및그의제조방

    公开(公告)号：KR100732821B1

    公开(公告)日：2007-06-27

    申请号：KR1020060003313

    申请日：2006-01-11

    Applicant: 삼성에스디아이 주식회사 ,  재단법인서울대학교산학협력재단

    Inventor： 박수진 ,  신대엽 ,  양남철 ,  권태혁 ,  김명기 ,  홍종인

    IPC: C07F15/00 ,  C09K11/06 ,  H05B33/00

    Abstract: Organic metal compounds, organic electroluminescence devices by using the same compounds and a preparation method of the same devices are provided to induce improvement of luminescence properties and increase of solubility in the metal compounds by connecting host compounds to dopant compounds, so that the organic electroluminescence device having improved luminescence efficiency, brilliance, color purity and life is produced if the organic metal compounds are applied to the organic electroluminescence devices. The organic metal compounds represented by the formula(1) in which the host compounds are connected to the dopant compounds are provided, wherein X is the formula(X1), formula(X2) or formula(X3) groups; R1 to R10 are each independently hydrogen, cyano group, hydroxy group, thiol group, halogen atom, substituted or unsubstituted C1-C30 alkyl group, substituted or unsubstituted C1-C30 alkoxy group, substituted or unsubstituted C2-C30 alkenyl group, substituted or unsubstituted C6-C30 aryl group, substituted or unsubstituted C6-C30 arylalkyl group, substituted or unsubstituted C6-C30 aryloxy group, substituted or unsubstituted C2-C30 heteroaryl group, substituted or unsubstituted C2-C30 heteroarylalkyl group, substituted or unsubstituted C2-C30 heteroaryloxy group, substituted or unsubstituted C5-C30 cycloalkyl group, substituted or unsubstituted C2-C30 heterocycloalkyl group, substituted or unsubstituted C1-C30 alkylcarbonyl group, substituted or unsubstituted C7-C30 arylcarbonyl group, substituted or unsubstituted C1-C30 alkylthio group, -Si(R')(R'')(R''') group or -N(R')(R'') group; M is Ir, Os, Pt, Pb, Re or Ru; and m is 3, n is 1 or 2, and a, b and c are each independently an integer from 1 to 3. The organic electroluminescence display device contains the organic metal compound represented by the formula(1) between a pair of electrodes.

    Abstract translation: 提供了有机金属化合物，使用相同化合物的有机电致发光器件及其制备方法，以通过将主体化合物连接至掺杂剂化合物来引起发光性能的提高和金属化合物中溶解度的增加，使得有机电致发光器件 如果将有机金属化合物应用于有机电致发光器件，则具有提高的发光效率，亮度，色纯度和寿命。 提供其中主体化合物与掺杂剂化合物连接的式（1）表示的有机金属化合物，其中X是式（X1），式（X2）或式（X3）基团; R1至R10各自独立地为氢，氰基，羟基，巯基，卤原子，取代或未取代的C1-C30烷基，取代或未取代的C1-C30烷氧基，取代或未取代的C2-C30烯基，取代或未取代的 取代或未取代的C 6 -C 30芳基，取代或未取代的C 6 -C 30芳氧基，取代或未取代的C 2 -C 30杂芳基，取代或未取代的C 2 -C 30杂芳基烷基，取代或未取代的C 2 -C 30杂芳氧基 取代或未取代的C 5 -C 30环烷基，取代或未取代的C 2 -C 30杂环烷基，取代或未取代的C 1 -C 30烷基羰基，取代或未取代的C 7 -C 30芳基羰基，取代或未取代的C 1 -C 30烷硫基， '）（R“）（R''）基团或-N（R'）（R”）基团; M是Ir，Os，Pt，Pb，Re或Ru; m为3，n为1或2，并且a，b和c各自独立地为1至3的整数。有机电致发光显示装置在一对电极之间包含由式（1）表示的有机金属化合物。

    유기 금속 화합물, 이를 이용한 유기 전계 발광 소자 및그의 제조방법
    16.
    发明授权
    유기 금속 화합물, 이를 이용한 유기 전계 발광 소자 및그의 제조방법 有权
    유기금속화합물，이를이용한유기전계발광소자및그의제조방

    公开(公告)号：KR100732820B1

    公开(公告)日：2007-06-27

    申请号：KR1020060003312

    申请日：2006-01-11

    Applicant: 삼성에스디아이 주식회사 ,  재단법인서울대학교산학협력재단

    Inventor： 박수진 ,  신대엽 ,  양남철 ,  권태혁 ,  김명기 ,  홍종인

    IPC: C07F15/00 ,  C09K11/06 ,  H05B33/00

    Abstract: Organic metal compounds, organic electroluminescence devices by using the same compounds and a preparation method of the same devices are provided to improve luminescence properties and solubility of the metal compounds by increasing molecular weight through connection of host compounds to dopant compounds, so that luminescence efficiency, brilliance, color purity and half-life of the organic electroluminescence device are improved. The organic metal compounds represented by the formula(1), in which the host compounds are connected to the dopant compounds, wherein X is X1, X2 or X3; R1 to R19 are each independently hydrogen, cyano group, hydroxy group, thiol group, halogen atom, substituted or unsubstituted C1-C30 alkyl group, substituted or unsubstituted C1-C30 alkoxy group, substituted or unsubstituted C2-C30 alkenyl group, substituted or unsubstituted C6-C30 aryl group, substituted or unsubstituted C6-C30 arylalkyl group, substituted or unsubstituted C6-C30 aryloxy group, substituted or unsubstituted C2-C30 heteroaryl group, substituted or unsubstituted C2-C30 heteroarylalkyl group, substituted or unsubstituted C2-C30 heteroaryloxy group, substituted or unsubstituted C5-C30 cycloalkyl group, substituted or unsubstituted C2-C30 heterocycloalkyl group, -Si(R')(R'')(R''') group or -N(R')(R'') group; M is Ir, Os, Pt, Pb, Re or Ru; and m is 3, n is 1 or 2, a, b and c are each independently an integer from 1 to 3, and L is acetylacetonate or picolinate. The organic electroluminescence device contains the organic metal compound represented by the formula(1) between a pair of electrodes.

    Abstract translation: 提供了有机金属化合物，使用相同化合物的有机电致发光器件及其制备方法，以通过将主体化合物与掺杂剂化合物连接而增加分子量来提高金属化合物的发光性质和溶解性，从而使发光效率， 提高了有机电致发光器件的亮度，色纯度和半衰期。 由式（1）表示的有机金属化合物，其中主体化合物与掺杂化合物连接，其中X是X 1，X 2或X 3; R 1至R 19各自独立地为氢，氰基，羟基，巯基，卤素原子，取代或未取代的C 1 -C 30烷基，取代或未取代的C 1 -C 30烷氧基，取代或未取代的C 2 -C 30烯基，取代或未取代的 取代或未取代的C 6 -C 30芳基，取代或未取代的C 6 -C 30芳氧基，取代或未取代的C 2 -C 30杂芳基，取代或未取代的C 2 -C 30杂芳基烷基，取代或未取代的C 2 -C 30杂芳氧基 ，取代或未取代的C 5 -C 30环烷基，取代或未取代的C 2 -C 30杂环烷基，-Si（R'）（R“）（R''）基团或-N（R'）（R”）基团 ; M是Ir，Os，Pt，Pb，Re或Ru; m为3，n为1或2，a，b和c各自独立地为1至3的整数，并且L为乙酰丙酮化物或吡啶甲酸盐。 有机电致发光器件在一对电极之间包含由式（1）表示的有机金属化合物。

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