公开(公告)号：KR1020090041242A

公开(公告)日：2009-04-28

申请号：KR1020070106843

申请日：2007-10-23

Applicant: 한국과학기술연구원

Inventor： 유복렬 ,  한준수 ,  임원철 ,  정동의

IPC: C07F7/08

CPC classification number: C07F7/0836 ,  C08G77/00

Abstract: A cycloalkenylsilanepolyol derivative which is an environment coupling agent dissolved in water or alcohol is provided to reform the surface of inorganic substance by simple heating without a catalyst and to produce water as by-product in condensation reaction. A cycloalkenylsilanepolyol derivative represented by the chemical formula 1 is prepared by hydrolyzing an organosilane compound represented by the chemical formula 2 with the acetic acid aqueous solution of 0.1-10 weight% at 0-40°C, wherein R is an isomer mixture of 2-cyclopentenyl, 3-cyclohexanyl, 3- or 4-methylcyclo hexa-3-enyl, 3,4-dimethylcyclohexa-3-enyl or bicyclo[2,2,2]octa-5-en-2-yl; and Y is a hydroxyl group, C1~6 alkyl group or ((2- cyclopentenyl) dihydroxy silyl) oxy.

Abstract translation: 提供溶解在水或醇中的环状偶联剂的环烯基硅烷多元醇衍生物，通过简单地加热而不用催化剂，在缩合反应中作为副产物生成水而使无机物质的表面改性。 由化学式1表示的环烯基硅烷多元醇衍生物通过在0-40℃下用0.1-10重量％的乙酸水溶液水解由化学式2表示的有机硅烷化合物来制备，其中R是2- 3-环己基，3-环己基，3-或4-甲基环己基-3-烯基，3,4-二甲基环己-3-烯基或双环[2,2,2]辛-5-烯-2-基; Y为羟基，C 1-6烷基或（（2-环戊烯基）二羟基甲硅烷基）氧基。