公开(公告)号：KR101253985B1

公开(公告)日：2013-04-15

申请号：KR1020130004170

申请日：2013-01-14

Applicant: 한국화학연구원

Inventor： 장종산 ,  황영규 ,  황동원 ,  이우황 ,  서유경 ,  윤지웅 ,  이종민 ,  이지선 ,  장인태

IPC: B01J20/32 ,  B01D53/02 ,  F24F3/14 ,  H01L51/50

Abstract: 본 발명은 다공성 유무기 혼성체, 그의 제조 방법, 그를 포함하는 흡착제 및 그의 응용에 관한 것이다.

公开(公告)号：KR101154029B1

公开(公告)日：2012-06-07

申请号：KR1020090043985

申请日：2009-05-20

Applicant: 한국화학연구원

Inventor： 장종산 ,  황영규 ,  이정호 ,  이종민 ,  정민희

IPC: C07D319/12 ,  C07D319/10

CPC classification number: C07D319/12

Abstract: 본발명은젖산에스테르로부터폴리락타이드의모노머로사용되는환형에스테르인락타이드를직접제조하는촉매및 이를이용한락타이드의제조방법에관한것으로, 더욱상세하게는불활성분위기에서출발물질인젖산에스테르그 자체또는젖산과젖산올리고머를소량포함한젖산에스테르혼합물을티타늄계촉매또는티타늄계촉매를포함하는촉매혼합물하에서에스테르교환반응시켜락타이드를제조함과동시에부산물로생성되는알콜(ROH)을제거하는단계를포함하는락타이드의제조방법을제공한다. 본발명에따른락타이드제조방법은젖산에스테르로부터락타이드를직접제조할수 있기때문에기존의상업화된공정에비해에너지소모가작고, 단순한공정으로락타이드를제조할수 있는새로운방법으로서광학특성(D-형또는 L-형광학이성체)을유지하면서도높은수율로락타이드를제조할수 있으므로공업적인활용성이매우높다.

公开(公告)号：KR1020120021899A

公开(公告)日：2012-03-09

申请号：KR1020100080977

申请日：2010-08-20

Applicant: 한국화학연구원

Inventor： 장종산 ,  황영규 ,  황동원 ,  이우황 ,  서유경 ,  윤지웅 ,  이종민 ,  이지선 ,  장인태

IPC: B01J20/32 ,  B01D53/02 ,  F24F3/14 ,  H01L51/50

CPC classification number: H01L51/5259 ,  H01L23/564 ,  H01L51/0077 ,  H01L51/5237

Abstract: PURPOSE: A porous organic-inorganic hybrid material, a method for manufacturing the same, an absorbent including the same, and the use of the same are provided to improve the initial absorbing speed of the hybrid material at high relative humidity and to improve the absorbing capability of the hybrid material at low relative humidity by carrying ionic compound or polar compound. CONSTITUTION: A method for manufacturing a porous organic-inorganic hybrid material includes the following: an ionic compound or a polar compound is carried in the hybrid material; a reaction mixture containing one or more inorganic metal precursor, one or more organic compounds functioning as ligand, and a solvent is prepared; porous organic-inorganic hybrid material is formed based on the reaction mixture. A moisture absorbent includes the hybrid material, a organic-inorganic hybrid material-inorganic complex, and the combination of the same.

Abstract translation: 目的：提供一种多孔有机 - 无机混合材料，其制造方法，包含该多孔有机 - 无机混合材料的吸收剂及其用途，以提高混合材料在高相对湿度下的初始吸收速度并改善吸收 通过携带离子化合物或极性化合物在低相对湿度下混合材料的能力。 构成：多孔有机 - 无机混合材料的制造方法包括：在混合材料中载带有离子性化合物或极性化合物; 制备含有一种或多种无机金属前体，一种或多种用作配体的有机化合物和溶剂的反应混合物; 基于反应混合物形成多孔有机 - 无机杂化材料。 吸湿剂包括混合材料，有机 - 无机杂化材料 - 无机复合物及其组合。

公开(公告)号：KR1020100124999A

公开(公告)日：2010-11-30

申请号：KR1020090043985

申请日：2009-05-20

Applicant: 한국화학연구원

Inventor： 장종산 ,  황영규 ,  이정호 ,  이종민 ,  정민희

IPC: C07D319/12 ,  C07D319/10

CPC classification number: C07D319/12

Abstract: PURPOSE: A method for preparing lactide using a catalyst which is able to directly produce from lactic acid ester is provided. CONSTITUTION: A lactide is prepared by ester exchange of lactic acid ester of chemical formula 1 under the presence of titanium catalyst or catalyst mixture containing the titanium catalyst. The lactic acid as an starter contains 20 weight% of lactic acid, lactic acid oligomer or mixture thereof. The titanium catalyst is tetraalkoxy titan((R'O)_4Ti), titanium halide(TiX_4, TiX_3, X= F,Cl,Br), alkoxytitanium halide((R'O)_4-xTiXx, X= F,Cl,Br, x= 1 - 3), titanium acetyl acetonate, or alkoxide acetyl acetonate.

Abstract translation: 目的：提供一种使用能够由乳酸酯直接生产的催化剂制备丙交酯的方法。 构成：在钛催化剂或含有钛催化剂的催化剂混合物的存在下，通过酯交换化学式1的乳酸酯制备丙交酯。 乳酸作为起始剂含有20重量％的乳酸，乳酸低聚物或其混合物。 钛催化剂是四烷氧基钛（（R'O）4 Ti），卤化钛（TiX_4，TiX_3，X = F，Cl，Br），烷氧基钛卤化物（（R'O）4-xTiXx，X = F，Cl，Br ，x = 1-3），乙酰丙酮钛或乙酰丙酮盐酸盐。