公开(公告)号：KR1020040031969A

公开(公告)日：2004-04-14

申请号：KR1020020061271

申请日：2002-10-08

Applicant: 한국화학연구원 ,  여천엔씨씨 주식회사

Inventor： 김형록 ,  이정호 ,  한요한 ,  황승철 ,  안정현 ,  박일남 ,  국순재 ,  송기석 ,  하종재 ,  김종생

IPC: B01J31/34

CPC classification number: B01J31/181 ,  B01J31/143 ,  B01J2531/62 ,  C07C2/02

Abstract: PURPOSE: Provided are catalyst and a method for ethylene oligomerization. The method can produce olefin with high reaction activity and selectivity by using pyridine derivatives as ligand in catalyst comprised of Cr compound, ligand and alkyl aluminum. CONSTITUTION: The catalyst is consisted of Cr compounds, 3-coordinative pyridine structure ligand, and alkyl aluminum, wherein the ligand is expressed as the formula 1, where R is hydrogen or C1-C6 alkyl group, -X1 and -X2 are =N and -P, respectively, wherein if the X1 or X2 is N(nitrogen), n is 1 whereas if X1 or X2 is P, n is 2, and wherein Ph is phenyl group or replaced phenyl group, and if the Ph is replaced phenyl group, the substituent is selected from a group being consisted of C1-C6 alkyl group and C1-C6 alkoxy group.

Abstract translation: 目的：提供催化剂和乙烯低聚方法。 该方法可以通过使用吡啶衍生物作为配体在由Cr化合物，配体和烷基铝组成的催化剂中，产生具有高反应活性和选择性的烯烃。 构成：催化剂由Cr化合物，3-配位吡啶结构配体和烷基铝组成，其中配体由式1表示，其中R是氢或C1-C6烷基，-X1和-X2是= N 和-P，其中如果X1或X2是N（氮），n是1，而如果X1或X2是P，n是2，并且其中Ph是苯基或取代的苯基，并且如果Ph被替换 苯基，取代基选自由C 1 -C 6烷基和C 1 -C 6烷氧基组成的基团。

公开(公告)号：KR1020030037474A

公开(公告)日：2003-05-14

申请号：KR1020010068514

申请日：2001-11-05

Applicant: 한국화학연구원 ,  여천엔씨씨 주식회사

Inventor： 김형록 ,  이정호 ,  한요한 ,  황승철 ,  김종승 ,  송기석 ,  하종재 ,  김종생

IPC: C08F4/69

CPC classification number: C08F4/622 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16

Abstract: PURPOSE: Provided is a chrome-calixarene-organoaluminum catalyst which has excellent catalytic activity and is stable in polymerizing olefin. The catalyst is simple to synthesize and reproducible. It can be used in making specific polymers different from polymers made by usual Ziegler-Natta or chrome supported catalysts in molecular weight distribution and the degree of crystallinity and unsaturation. CONSTITUTION: The catalyst comprises 1 mole of chrome(III) compound, 0.5-2 moles of calixarene compound and 10-1000 moles of organic aluminum compound. The polymerization is carried out with the catalyst at 30-200deg.C under 3-50 atm and the catalyst is either added with molecular chrome-calixarene and organic aluminum respectively or in one shot of the mixed component.

Abstract translation: 目的：提供一种具有优异催化活性并在烯烃聚合中稳定的铬 - 杯芳烃 - 有机铝催化剂。 催化剂易于合成和再生。 它可以用于制造与通常的齐格勒 - 纳塔或铬载体催化剂在分子量分布和结晶度和不饱和度方面制备的聚合物不同的特定聚合物。 构成：催化剂包含1摩尔铬（III）化合物，0.5-2摩尔杯芳烃化合物和10-1000摩尔有机铝化合物。 聚合反应在30〜200℃，3-50大气压下进行，催化剂分别加入分子铬 - 杯芳烃和有机铝，或分别加入混合组分。