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公开(公告)号:US10478674B2
公开(公告)日:2019-11-19
申请号:US15936500
申请日:2018-03-27
Applicant: Acushnet Company
Inventor: David A. Bulpett , Robert Blink , Mark L. Binette , Brian Comeau , Michael J. Sullivan
Abstract: A golf ball including a core; an inner cover layer formed from a thermoplastic composition and having a thickness of about 0.005 inches to 0.40 inches and a surface hardness of about 60 Shore D or greater; and an outer cover layer formed from a thermoset material and having a thickness of about 0.01 inches to 0.05 inches and a surface hardness of about 60 Shore D or less. The thermoplastic composition has a first melt flow index at 280° C. under a 10-kg load of less than about 35 g/10 min and a second melt flow index at 265° C. under a 5-kg load of less than about 10 g/10 min.
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12.
公开(公告)号:US20190321690A1
公开(公告)日:2019-10-24
申请号:US15955779
申请日:2018-04-18
Applicant: Acushnet Company
Inventor: David A. Bulpett , Brian Comeau , Robert Blink
Abstract: Golf ball incorporating layer(s) of a mixture consisting of: i) ionomer(s); ii) ethylene propylene rubber(s)(EPR(s)); iii) polymeric epoxy crosslinker(s); and iv) compatibilizing polymer(s). The ionomer(s) and EPR(s) may be included in a blend in a wt % ratio of from about 85:15 to 55:45; the at least one polymeric epoxy crosslinker and compatibilizing polymer may be included in amounts, based on 100 parts of the blend, of from about 2.0 to about 10.0 parts; and from about 1.0 to about 10.0 parts, respectively. Each ionomer, EPR, polymeric epoxy crosslinker, and compatibilizing polymer has a density less than 1.0 g/cm3. The mixture is melt processable/moldable without meanwhile sacrificing target CoR, DCM compression, Shore D hardness, and Shore C hardness.
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公开(公告)号:US10343019B2
公开(公告)日:2019-07-09
申请号:US15896171
申请日:2018-02-14
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Derek A. Ladd , Mark L. Binette , Brian Comeau , Michael Michalewich , Shawn Ricci
Abstract: Multi-piece golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The outer core layer is preferably formed from a non-foamed thermoset composition such as polybutadiene rubber. The inner and outer core layers can have different hardness gradients. Preferably, the specific gravity (density) of the foam inner core is less than the density of the outer core layer. The ball further includes a cover of at least one layer and may include at least one casing layer. The core structure and resulting ball have relatively good resiliency.
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公开(公告)号:US10300343B2
公开(公告)日:2019-05-28
申请号:US15953619
申请日:2018-04-16
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , David A. Bulpett , Robert Blink , Mark L. Binette , Brian Comeau
Abstract: The present invention is directed to golf balls consisting of a multi-layer core and a cover. The multi-layer core includes at least one layer formed from a relatively soft or low modulus HNP composition and at least one layer formed from a relatively hard or high modulus HNP composition.
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公开(公告)号:US10300341B2
公开(公告)日:2019-05-28
申请号:US15903149
申请日:2018-02-23
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Mark L. Binette , Robert Blink , David A. Bulpett , Brian Comeau , Douglas S. Goguen
Abstract: Multi-layered golf balls containing a two or three-layered cover assembly are provided. In one embodiment, the cover assembly includes a relatively hard inner cover and relatively soft outer cover. Alternatively, the cover assembly may include a relatively soft inner cover with a relatively hard outer cover. Three-layered covers comprising an inner cover, intermediate cover, and outer cover layer also may be prepared. Preferably, at least one of the layers is formed from a thermoplastic composition that preferably comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. The cover assembly has good impact durability and helps provide the ball with relatively high resiliency at given compressions.
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16.
公开(公告)号:US20190143179A1
公开(公告)日:2019-05-16
申请号:US16186856
申请日:2018-11-12
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Brian Comeau , Michael Michalewich
IPC: A63B37/00
Abstract: Golf ball incorporating thermoplastic blend of (i) ionomer(s); (ii) different thermoplastic polymer(s) selected from thermoplastic polyurethane(s), thermoplastic urea(s), thermoplastic urea-urethane hybrid(s), or combinations thereof; and (iii) polymethyl (meth)acrylate-based copolymer(s) and/or core-shell polymer(s) having a core and/or a shell containing polymethyl (meth)acrylate-based copolymer(s). Ionomer(s) are present in thermoplastic blend in amount of about 45 wt % or greater. Different thermoplastic polymer present in blend in amount of: from about 8 wt % to about 50 wt %; or greater than 20 wt %, or from about 25 wt % to about 45 wt %; or from about 35 wt % to about 50 wt %. In a particular embodiment, amount of ionomer(s) is greater than thermoplastic polyurethane amount. Component (iii) may be present in an amount of about 2 wt % to about 35 wt %, and in a specific embodiments, polymethyl (meth)acrylate-based copolymer(s) and/or core-shell polymer(s) included in blend in amount of from about 15 wt % to about 35 wt %.
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17.
公开(公告)号:US20190143178A1
公开(公告)日:2019-05-16
申请号:US16186806
申请日:2018-11-12
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Brian Comeau , Michael Michalewich
IPC: A63B37/00
Abstract: Golf ball incorporating thermoplastic blend of (i) ionomer(s); (ii) different thermoplastic polymer(s) selected from thermoplastic polyurethane(s), thermoplastic urea(s), thermoplastic urea-urethane hybrid(s), or combinations thereof; and (iii) polymethyl (meth)acrylate-based copolymer(s) and/or core-shell polymer(s) having a core and/or a shell containing polymethyl (meth)acrylate-based copolymer(s). Ionomer(s) are present in thermoplastic blend in amount of about 45 wt % or greater. Different thermoplastic polymer present in blend in amount of: from about 8 wt % to about 50 wt %; or greater than 20 wt %, or from about 25 wt % to about 45 wt %; or from about 35 wt % to about 50 wt %. In a particular embodiment, amount of ionomer(s) is greater than thermoplastic polyurethane amount. Component (iii) may be present in an amount of about 2 wt % to about 35 wt %, and in a specific embodiments, polymethyl (meth)acrylate-based copolymer(s) and/or core-shell polymer(s) included in blend in amount of from about 15 wt % to about 35 wt %.
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公开(公告)号:US20190118041A1
公开(公告)日:2019-04-25
申请号:US16220016
申请日:2018-12-14
Applicant: Acushnet Company
Inventor: Mark L. Binette , Michael J. Sullivan , Derek A. Ladd , Brian Comeau , Michael Michalewich , Shawn Ricci , Douglas S. Goguen
IPC: A63B37/00
CPC classification number: A63B37/0056 , A63B37/0039 , A63B37/0043 , A63B37/0044 , A63B37/0045 , A63B37/0047 , A63B37/0051 , A63B37/0058 , A63B37/0062 , A63B37/0063 , A63B37/0064 , A63B37/0066 , A63B37/0075 , A63B37/0076 , A63B37/0078 , A63B37/0091 , A63B37/0092 , A63B37/0094 , A63B45/00 , C08G18/10 , C08G18/42 , C08G18/44 , C08G18/48 , C08G18/6204 , C08G2101/00 , C08G2101/0083
Abstract: Multi-layered, golf balls having a core made of a foamed composition are provided. The core preferably has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition comprising secondary blowing agents that are activated by heat is used to form the foam center. Non-foamed thermoset materials such as polybutadiene rubber may be used to form the outer core layer. The core layers have different hardness gradients and specific gravity values. The foam cores have good resiliency, thermal stability, and durability over a wide temperature range. The ball further includes a cover that may be multi-layered.
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19.
公开(公告)号:US10252115B2
公开(公告)日:2019-04-09
申请号:US16033299
申请日:2018-07-12
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Brian Comeau , Michael Michalewich , Mark L. Binette
Abstract: Golf ball comprising a core having a hardness gradient and an outer cover layer having a microhardness gradient and being formed from a thermoset polyurethane material throughout, and having: i) a treated region that is contacted with a thermoset polyurethane microhardness-increasing solution consisting of an isocyanate portion and at least one non-aqueous solvent; and ii) an untreated region that is not contacted with the thermoset polyurethane microhardness-increasing solution. The treated region comprises the isocyanate portion, whereas the untreated region does not comprise the isocyanate portion. Treated region has a microhardness M1 that is greater than microhardness M2 of untreated region to define the outer cover layer positive microhardness gradient ΔM=M1−M2. The treated region may have a depth Dtr that extends inward from the cover outer surface and in some embodiments is less than a thickness of the untreated region. Treated region may alternatively extend from the inner surface toward outer surface.
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公开(公告)号:US20190054351A1
公开(公告)日:2019-02-21
申请号:US16167782
申请日:2018-10-23
Applicant: Acushnet Company
Inventor: Michael J. Sullivan , Mark L. Binette , Brian Comeau , Shawn Ricci , Michael Michalewich , John D. Farrell , Douglas S. Goguen
Abstract: Multi-layered, golf balls having a core made of a particle-based polyurethane foam composition are provided. The ball includes a dual-layered core having a foam inner core (center) and surrounding outer core layer. The surrounding outer core layer is preferably made from a foamed composition. In one embodiment, pre-expanded thermoplastic polyurethane foam beads containing a blowing agent are used to form the foam center and outer core. In another embodiment, pre-formed polyurethane foam particles are used in both core layers. The foam cores have good resiliency, thermal stability, and durability over a wide temperature range. The ball further includes a cover that may be multi-layered.
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