公开(公告)号：JP2009029929A

公开(公告)日：2009-02-12

申请号：JP2007195230

申请日：2007-07-26

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： IRISAWA MASAFUKU

IPC: C08F20/10 ,  C08F2/50 ,  C09K19/38 ,  G02B1/04

Abstract: PROBLEM TO BE SOLVED: To provide a polymerizable composition which has good solvent solubility and excels in orientation controllability, optical properties, and photocurability. SOLUTION: The polymerizable composition comprises a polymerizable liquid crystal compound having, as a polymerizable group, a (meth)acryloyl group which may be substituted with a halogen and a compound having a carbazole skeleton and an acyloxime ester as a radical photopolymerization initiator. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 解决问题：提供溶剂溶解性好，取向控制性，光学特性，光固化性优异的聚合性组合物。 解决方案：可聚合组合物包含具有作为可聚合基团的可被卤素取代的（甲基）丙烯酰基和具有咔唑骨架的化合物和酰肟酯作为自由基光聚合引发剂的聚合性液晶化合物 。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008179654A

公开(公告)日：2008-08-07

申请号：JP2007001727

申请日：2007-01-09

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： HAMADA RIEKO ,  IRISAWA MASAFUKU ,  MURATA SEI

IPC: C08F20/30 ,  C07C67/08 ,  C07C69/757 ,  G02B5/30

CPC classification number: C09K19/322 ,  C08F232/08 ,  C09K19/3861 ,  C09K2019/0448 ,  G02B5/305 ,  G02B5/3083 ,  G02F1/1335 ,  G02F2202/023 ,  Y10T428/10

Abstract: PROBLEM TO BE SOLVED: To provide a polymerizable compound which has large optical (refractive index) anisotropy, exhibits liquid crystal phase at temperatures near to room temperature, and is excellent in solvent solubility, and to provide a polymerizable composition. SOLUTION: This polymerizable compound is represented by formula (1), wherein Z 1 and Z 2 are each (meth)acryloyloxy; X 1 and X 2 are each independently a single bond, a 1-8C alkylene, an ether bond, -COO-, -OCO-, -OCOO-, a six-membered ring which may have one or more substituents, or their combination; R 1 is -R', -OR', -CO-R' or -OCO-R'; R' is a halogen atom, a 1-8C alkyl or a six-membered cyclic which may have one or more substituents; L 1 and L 2 are each independently a single bond, -CH 2 CH 2 -, -CH=CH-, -C≡C-, -CH 2 O-, -OCH 2 -, -COO- or -OCO-; (m) is an integer of 1 to 4; the R 1 groups may be different each other. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供具有大的光学（折射率）各向异性的可聚合化合物，在接近室温的温度下显示液晶相，并且溶剂溶解性优异，并提供可聚合组合物。 解决方案：该可聚合化合物由式（1）表示，其中Z 1 和Z 2 分别为（甲基）丙烯酰氧基; X 1 和X 2 各自独立地为单键，1-8C亚烷基，醚键，-COO-，-OCO-，-OCOO-，六 其可以具有一个或多个取代基，或它们的组合; R SP 1是-R'，-OR'，-CO-R'或-OCO-R'; R'是卤素原子，可具有一个或多个取代基的1-8C烷基或六元环; L 1 和L 2 各自独立地是单键，-CH 2 SB 2，-CH = CH - ， - C≡C - ， - CH 2，-OCH 2 - ， - COO-或-OCO-; （m）为1〜4的整数， R 1 组可能彼此不同。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2014201531A

公开(公告)日：2014-10-27

申请号：JP2013077323

申请日：2013-04-03

Applicant: 株式会社Adeka ,  Adeka Corp ,  株式会社Adeka

Inventor： MATSUMOTO TAKESHI ,  IRISAWA MASAFUKU ,  OKADA MITSUHIRO

IPC: C07F7/18 ,  C08F20/20

Abstract: 【課題】シランカップリング剤として有用な新規重合性化合物を提供する。【解決手段】下記一般式(1)で表される重合性アルコキシシラン化合物。(式中、環A:置換基を有してもよいベンゼン環、シクロヘキサン環又はナフタレン環、X:H又はMe、Y:H又はC1〜5アルキル基、L1:単結合、−O−、−S−、−COO−、−OCO−、−SCO−、−OCOO−、−(CE2)p−、−(CE2)pO−、−(CE2)pS−、−(CE2)pCOO−、−(CE2)pOCO−、−(CE2)pSCO−、−(CE2)pOCOO−、−(CE2)pS(CE2)qS−又は−(CE2)pO(CE2)qO−、L2:−(CE2)p−、−(CE2)pO(CE2)q−、−(CE2)pS(CE2)q−又は−(CE2)pNY(CE2)q−、E:H、C1〜4アルキル基又はハロゲン原子、R:C1〜5アルキル基、n:1〜3、p:1〜20、q:1〜20)【選択図】なし

Abstract translation: 要解决的问题：提供可用作硅烷偶联剂的新型聚合性化合物。溶液：提供由以下通式（1）表示的可聚合烷氧基硅烷化合物。 （1）其中环A：需要时具有取代基的苯环，环己烷环或萘环，X：H或Me，Y：H或C1至5烷基，L：单键， - （CE）O-， - （CE） - ， - （CE）COO-， - （CE）OCO-， - （CE）SCO-， - （CE）OCOO-， - （CE）S（CE）S-或 - （CE）O（CE）O-，L :-（CE） ， - （CE）O（CE） - ， - （CE）S（CE） - 或 - （CE）NY（CE） - ，E：H，C1至4烷基或卤素原子，R：C1 5烷基，n：1〜3，p：1〜20，q：1〜20。

公开(公告)号：JP2013043947A

公开(公告)日：2013-03-04

申请号：JP2011183300

申请日：2011-08-25

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： TAKEUCHI YOSHITOMO ,  IRISAWA MASAFUKU

IPC: C08L67/00 ,  C08K5/00 ,  C08L101/00 ,  G03G5/05

Abstract: PROBLEM TO BE SOLVED: To provide a resin composition with which a resin thin film with fully satisfactory gas barrier properties and abrasion resistance is easily formed even when subjected to a heat drying step.SOLUTION: The resin composition contains a polyester (A), a resin (B) other than the polyester (A), and a charge transport material (C). The polyester (A) is obtained by a reaction of a polybasic acid, a polyhydric alcohol, and a stopper forming a terminal of the polyester (A) with one another. The stopper is at least one selected from acetic acid, an ether alcohol, and benzoic acid which is optionally replaced with an alkyl group.

Abstract translation: 要解决的问题：为了提供即使经受加热干燥步骤也容易形成具有完全令人满意的阻气性和耐磨性的树脂薄膜的树脂组合物。 解决方案：树脂组合物含有聚酯（A），除聚酯（A）以外的树脂（B）和电荷输送材料（C）。 聚酯（A）通过多元酸，多元醇和形成聚酯（A）的末端的塞子的反应而获得。 塞子是选自乙酸，醚醇和任选被烷基取代的苯甲酸中的至少一种。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：JP2012107133A

公开(公告)日：2012-06-07

申请号：JP2010257650

申请日：2010-11-18

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： YANAGISAWA TOMOHITO ,  IRISAWA MASAFUKU ,  OZAKI YASUNORI

IPC: C08F220/36 ,  B32B27/34 ,  H01L31/042

CPC classification number: Y02E10/50

Abstract: PROBLEM TO BE SOLVED: To provide an infrared reflecting layer which selectively reflects only needless heat rays (infrared rays) and passes useful light, and further, to provide a photoelectric conversion device (particularly, a solar cell) which can prevent temperature rise in an element such as a photoelectric conversion element and a device itself and maintain power generating efficiency.SOLUTION: As the infrared reflecting layer, a polymer obtained by polymerizing a polymerizable composition comprising: a polymerizable optically active imide compound (A) represented by general formula (1); a liquid crystal compound (B); and a radical polymerization initiator (C), and in which the content of the polymerizable optically active imide compound (A) provided that the total content of the polymerizable optically active imide compound (A) and the liquid crystal compound (B) is defined as 100 pts.mass is 0.1 to 10 pts.mass, is used.

Abstract translation: 要解决的问题：提供一种红外线反射层，其仅选择性地仅反射不需要的热射线（红外线）并通过有用的光，并且还提供可以防止温度的光电转换装置（特别是太阳能电池） 在诸如光电转换元件和器件本身的元件中上升并且保持发电效率。 解决方案：作为红外线反射层，是将聚合性组合物聚合而成的聚合物，该聚合性组合物包含：通式（1）表示的聚合性光学活性酰亚胺化合物（A） 液晶化合物（B）; 和自由基聚合引发剂（C），其中将聚合性光学活性酰亚胺化合物（A）和液晶化合物（B）的总含量定义为 100 pts.mass是0.1到10 pts.mass，被使用。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2011148761A

公开(公告)日：2011-08-04

申请号：JP2010246622

申请日：2010-11-02

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： YANAGISAWA TOMOHITO ,  IRISAWA MASAFUKU

IPC: C07D303/22 ,  C07D305/06 ,  C09K19/38 ,  C09K19/54 ,  G02F1/1335

Abstract: PROBLEM TO BE SOLVED: To provide a polymerizable liquid crystal compound exhibiting a liquid crystal phase near room temperature (having a wide temperature range to develop the liquid crystal phase) to prevent crystal precipitation, quickly curable by UV irradiation in air and giving a polymer having excellent heat-resistance. SOLUTION: There is provided the polymerizable liquid crystal compound expressed by formula (I). In formula (I), rings A 1 to A 4 are each a benzene ring, naphthalene ring or the like; S 1 and S 2 are each 1-8C alkylene; X 1 is H or methyl; Z 1 to Z 4 are each direct bond, -O-CO-, -CO-O- or the like; Y 1 to Y 4 are each 1-6C alkyl or the like; a to d are each 0-8; n is 1 or 2; and G is either one of substituents of formulas (1) to (4). COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：为了提供在室温附近呈现液晶相（具有宽的温度范围以形成液晶相）以防止结晶沉淀的可聚合液晶化合物，可以通过在空气中的紫外线照射快速固化并给出 具有优异的耐热性的聚合物。 提供由式（I）表示的聚合性液晶化合物。 在式（I）中，环A 1 至A 4 分别为苯环，萘环等; S 1 和S 2 分别为1-8C亚烷基; X 1 是H或甲基; Z 1 至Z 4 均为直接键合，-O-CO-，-CO-O-等; Y 1 至Y 4 分别为1-6C烷基等; a到d都是0-8; n为1或2; 并且G是式（1）至（4）的取代基之一。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2009102245A

公开(公告)日：2009-05-14

申请号：JP2007274053

申请日：2007-10-22

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： SHINANO HIROKATSU ,  IRISAWA MASAFUKU ,  HAMADA RIEKO

IPC: C07C39/38 ,  C07C43/23 ,  C07C69/54 ,  C07C69/653 ,  C08G61/00 ,  G02F1/1337

Abstract: PROBLEM TO BE SOLVED: To provide a polymerizable compound having excellent solvent solubility, orientation control ability and optical properties and a polymerizable composition.
SOLUTION: The compound is represented by general formulas I and II [wherein ring A and ring B are each a benzene ring or a naphthalene ring and at least one of them is a naphthalene ring; X is a halogen atom or an alkoxy group; and R is a substituent group represented by formula III (Z
1 is a direct bond, -L
0 -, -OL
0 CO-, -OL
1 - or -OL
1 OCO-; and L
0 and L
1 are each an alkylene group, and methylene part of the alkylene group may be interrupted by S, COO, OCO, OCOO or CH(OH))].
COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供溶剂溶解性，取向控制能力和光学性能优异的聚合性化合物以及聚合性组合物。 解决方案：该化合物由通式I和II表示[其中环A和环B各自为苯环或萘环，并且其中至少一个为萘环; X是卤原子或烷氧基; 和R是由式III表示的取代基（Z 1 是直接键，-L 0 - ，-OL 0 CO-， -OL 1 或-OL 1 OCO-; L 0 和L 1 分别为亚烷基 ，亚烷基的亚甲基部分可被S，COO，OCO，OCOO或CH（OH））中断）。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2009020052A

公开(公告)日：2009-01-29

申请号：JP2007184450

申请日：2007-07-13

Applicant: Adeka Corp ,  National Institute Of Advanced Industrial & Technology ,  株式会社Adeka ,  独立行政法人産業技術総合研究所

Inventor： FUKUDA TAKASHI ,  IBARADA DAISUKE ,  USHIJIMA YOJI ,  IRISAWA MASAFUKU ,  OTSUKA TAKAHIRO

IPC: G01N21/88 ,  G01N21/21 ,  G07D7/20

Abstract: PROBLEM TO BE SOLVED: To provide an appraisal method remotely determining the authenticity of an anti-counterfeit medium having a latent image using optical anisotropy difficult to be visually recognized without being known by a third person. SOLUTION: This appraisal method is used for remotely determining the authenticity of a verifying object that is the anti-counterfeit medium having the latent image using optical anisotropy or another medium having no latent image. The verifying object is irradiated with light of an invisible light area having polarization of one direction, the reflected light reflected by the verifying object is made to transmit through a polarizing plate arranged on the optical path, and the light having transmitted through the polarizing plate is observed or photographed, thereby remotely determining the authenticity of the verifying object. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供一种使用光学各向异性远程确定具有潜像的防伪介质的真实性的评估方法，其难以被第三者知道而难以视觉识别。 解决方案：该评估方法用于远程确定使用光学各向异性的具有潜像的防伪介质的验证对象的真实性或不具有潜像的另一介质。 用具有一个方向的偏振的不可见光区域的光照射验证对象，使由验证对象反射的反射光透过设置在光路上的偏振片透射，并且透过偏振片的光是 观察或拍摄，从而远程确定验证对象的真实性。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2007291046A

公开(公告)日：2007-11-08

申请号：JP2006123612

申请日：2006-04-27

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： IRISAWA MASAFUKU ,  MATSUMOTO TAKESHI

IPC: C07C69/94 ,  C07C255/55 ,  C09K19/12 ,  C09K19/14 ,  C09K19/20 ,  C09K19/30 ,  C09K19/32 ,  G02F1/13

Abstract: PROBLEM TO BE SOLVED: To provide a compound having good compatibility and keeping a liquid crystal phase even at a low temperature and provide a liquid crystal composition containing the compound. SOLUTION: The invention provides a compound expressed by formula (1) (X is alkyl or alkoxy which may be substituted with halogen atom; Y is oxygen atom or alkylene group which may be interrupted with oxygen; Z is -CH 2 -, -CO-, -COO-, -OCO-, single bond or the like; the ring A is a 4-20C cyclic group; n is 1-3; and R 1 is hydrogen, alkyl or phenyl), and a liquid crystal composition containing the compound. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供即使在低温下具有良好相容性和保持液晶相的化合物，并提供含有该化合物的液晶组合物。 解决方案：本发明提供式（1）表示的化合物（X为可被卤素原子取代的烷基或烷氧基; Y为氧原子或可被氧中断的亚烷基; Z为-CH 1 < / SB>是氢，烷基或苯基）和含有该化合物的液晶组合物。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007119415A

公开(公告)日：2007-05-17

申请号：JP2005315699

申请日：2005-10-31

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： IRISAWA MASAFUKU ,  KOBAYASHI TATSUNORI ,  HASEGAWA MINEKI

IPC: C07C69/94 ,  C08F20/26 ,  C09K19/32 ,  C09K19/38

CPC classification number: C09K19/3861 ,  C08F222/1006 ,  C09K19/32 ,  C09K19/322 ,  C09K2019/0448 ,  Y10T428/10

Abstract: PROBLEM TO BE SOLVED: To provide a polymerizable liquid crystal compound exhibiting a liquid crystal phase at room temperature without precipitating a crystal even having high optical anisotropy, having excellent solubility in an organic solvent, excellent coatability and excellent orienting properties, and providing excellent transparency after polymerization; and to provide homo- and co-polymers of the polymerizable liquid crystal compound. SOLUTION: The polymerizable liquid crystal compound is represented by general formula (1) [wherein, R 1 and R 2 are each a hydrogen atom, a methyl group or a halogen atom; rings A to C are each a benzene ring, a naphthalene ring or the like, with the proviso that at least one of the rings A to C is a condensed ring; X to Z are each a 1-6C alkyl group or the like; L 1 to L 3 are each -COO-, -OCO-, -O(CH 2 ) j - (j is 1-8), or the like; n is 0 or 1; (a) to (c) are each a number showing that at least one of X, Y and Z is present in the polymerizable liquid crystal compound]. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：为了提供在室温下呈现出液晶相的可聚合液晶化合物，而不析出具有高光学各向异性的结晶，在有机溶剂中的溶解性优异，涂布性优异，取向性优异，并提供 聚合后透明度好; 并提供可聚合液晶化合物的均聚物和共聚物。 解决方案：可聚合液晶化合物由通式（1）表示[其中，R SB 1和/或SB 2各自为氢原子，甲基或 卤素原子; 环A至C各自为苯环，萘环等，条件是至少一个环A至C为稠环; X至Z各自为1-6C烷基等; L 1 至L 3 分别为-COO-，-OCO-，-O（CH 2 ） - （j为1-8）等; n为0或1; （a）〜（c）分别表示X，Y，Z中的至少一个存在于聚合性液晶化合物中]。 版权所有（C）2007，JPO＆INPIT