公开(公告)号：EP1049659A1

公开(公告)日：2000-11-08

申请号：EP99903236.0

申请日：1999-01-20

Applicant: AlliedSignal Inc.

Inventor： NALEWAJEK, David ,  BRADLEY, David ,  SCHABEL, John ,  BLOMQUIST, Robert

IPC: C07C43/17 ,  C07C69/63 ,  C07C309/63 ,  G02B6/00 ,  C08F16/12 ,  C09D11/02 ,  C09D129/10 ,  C09J4/00

CPC classification number: C09J129/10 ,  C07C43/17 ,  C07C43/172 ,  C07C69/63 ,  C07C309/73 ,  C08F8/18 ,  C09D11/101 ,  C09D129/10 ,  C09J4/00 ,  G11B7/2531 ,  G11B7/2533 ,  G11B7/2542 ,  G11B7/256 ,  C08F216/125

Abstract: Fluorine containing oxyvinyl compounds characterized by having one or more oxyvinyl groups separated from fluorine containing groups by at least one alkylene group having 2-8 carbon atoms and by at least one oxygen atom in addition to the oxygen on the oxyvinyl. In general the compounds of the invention have the generic formula: Rz(L)a(Ry)bOROCH=CH2. Where L is =CHCOOROCH=CH2; a is number of 0 to about 1; Ry is -CO-; b is a number of 0 to about 1; R is cycloalkane or (CH2)x-, where x is a number of about 2 through about 10; Rz is RfCnHm where Rf is a fluorinated alkylene moiety of about 1 to about 12 carbon atoms which may be linear or branch chained and may contain a further -OROCH=CH2 group; n is a integer of about 1 through about 6; and m is an integer of n to 2n. The compounds are suitable for use in optical devices such as fibers and waveguides, are readily radiation curable and curable by other means, and can be formulated to be of low viscosity when applied. The compounds are also suited for coatings, inks and adhesive and other applications. The invention includes methods for preparing and using the compounds and products employing the compounds. Intermediates to prepare the compounds and methods to prepare the intermediates are also included.

公开(公告)号：EP1019577A2

公开(公告)日：2000-07-19

申请号：EP98930202.1

申请日：1998-06-12

Applicant: AlliedSignal Inc.

Inventor： NALEWAJEK, David ,  STACHURA, Leonard, M. ,  ZYHOWSKI, Gary, J.

IPC: D06L1/00

CPC classification number: D06L1/04 ,  C07F9/098 ,  C07F9/12 ,  C11D1/006 ,  C11D3/24 ,  C11D3/245 ,  C11D3/43

Abstract: The invention provides a fluorinated surfactant for use with halocarbon and hydrofluoroether solvents. Additionally, the invention provides drying, dry cleaning, and soil repellency compositions containing a halocarbon or hydrofluoroether and a fluorinated surfactant.

公开(公告)号：EP0451155B1

公开(公告)日：1993-05-12

申请号：EP89912073.7

申请日：1989-10-05

Applicant: AlliedSignal Inc.

Inventor： THOMAS, Raymond, Hilton, Percival ,  WILSON, David, Paul ,  NALEWAJEK, David ,  PHAM, Hang, Thanh

IPC: C10M107/38

CPC classification number: C10M171/008 ,  C10M105/50 ,  C10M107/38 ,  C10M111/04 ,  C10M2203/06 ,  C10M2203/10 ,  C10M2203/102 ,  C10M2203/104 ,  C10M2203/106 ,  C10M2203/108 ,  C10M2205/00 ,  C10M2205/026 ,  C10M2205/04 ,  C10M2207/021 ,  C10M2207/026 ,  C10M2207/027 ,  C10M2207/028 ,  C10M2207/125 ,  C10M2207/129 ,  C10M2207/144 ,  C10M2207/146 ,  C10M2207/262 ,  C10M2207/28 ,  C10M2209/084 ,  C10M2209/086 ,  C10M2209/102 ,  C10M2211/003 ,  C10M2211/022 ,  C10M2211/06 ,  C10M2211/08 ,  C10M2213/00 ,  C10M2213/02 ,  C10M2213/023 ,  C10M2213/04 ,  C10M2213/043 ,  C10M2213/06 ,  C10M2213/0606 ,  C10M2213/062 ,  C10M2213/0623 ,  C10M2215/06 ,  C10M2215/065 ,  C10M2215/086 ,  C10M2215/28 ,  C10M2217/023 ,  C10M2217/028 ,  C10M2217/06 ,  C10M2219/02 ,  C10M2219/022 ,  C10M2219/024 ,  C10M2219/044 ,  C10M2219/046 ,  C10M2219/082 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2223/045 ,  C10M2223/047 ,  C10M2223/065 ,  C10M2225/00 ,  C10M2225/02 ,  C10M2227/09 ,  C10M2229/02 ,  C10M2229/05 ,  C10M2229/051 ,  C10N2210/06 ,  C10N2240/00 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66

Abstract: The present invention provides a novel lubricating composition comprising a polyoxyalkylene glycol having a cap of a fluorinated alkyl group on at least one end thereof. The composition has a molecular weight between 300 and 3,000, a viscosity of about 5 to about 150 centistokes at 37 DEG C., and a viscosity index of at least 20. The composition is miscible in combination with tetrafluoroethane in the range between -40 DEG C. and at least +20 DEG C. The novel lubricating composition is particularly useful with tetrafluoroethane in refrigeration and air-conditioning applications. As such, the present invention also provides a composition for use in refrigeration and air-conditioning comprising: (a) tetrafluoroethane; and (b) a sufficient amount to provide lubrication of at least one polyoxyalkylene glycol having a cap of fluorinated alkyl group on at least one end thereof. The lubricant has a molecular weight of about 300 to about 3,000, a viscosity of about 5 to about 150 centistokes at 37 DEG C., and a viscosity index of at least 20. The lubricant is miscible in combination with the tetrafluoroethane in the range between about -40 DEG C. and at least about +20 DEG C.

公开(公告)号：EP0797565A1

公开(公告)日：1997-10-01

申请号：EP95943041.0

申请日：1995-12-11

Applicant: AlliedSignal Inc.

Inventor： ZYHOWSKI, Gary, John ,  NALEWAJEK, David ,  STACHURA, Leonard, Michael

IPC: B01D12 ,  C07C211 ,  C07F9 ,  C11D1 ,  D06L1 ,  D06M13

CPC classification number: D06M13/463 ,  B01D12/00 ,  C07C211/63 ,  C07F9/11 ,  C07F9/12 ,  C11D1/006 ,  D06L1/04

Abstract: Novel surfactants and drying, drycleaning and soil repellency compositions containing such surfactants which utilize such surfactants. The surfactants are fluorine containing quaternary ammonium salts, and the drying, drycleaning and soil repellency compositions contain at least one halocarbon component and at least one of the fluorine containing surfactants. These compositions have the ability to remove water or aqueous films from the surfaces of a broad range of substrates and impart soil repellency to fabrics.

公开(公告)号：EP0740647A1

公开(公告)日：1996-11-06

申请号：EP95908552.0

申请日：1995-01-19

Applicant: AlliedSignal Inc.

Inventor： VAN DER PUY, Michael ,  BASU, Rajat, Subhra ,  NALEWAJEK, David ,  ELLIS, Lois, Anne

IPC: C07C19 ,  C11D7 ,  C23G5

CPC classification number: C07C19/08 ,  C11D7/5018 ,  C23G5/02803

Abstract: Hydrofluoroalkanes useful as solvents, especially for vapor degreasing and solvent cleaning, are one or many of the above mentioned formulae.

Abstract translation: 可用作溶剂的氢氟烷烃，特别是用于蒸汽脱脂和溶剂清洗的是一种或多种上述配方。

公开(公告)号：EP0471755B1

公开(公告)日：1993-11-18

申请号：EP90907683.8

申请日：1990-04-30

Applicant: AlliedSignal Inc.

Inventor： VAN DER PUY, Michael ,  NALEWAJEK, David ,  SHIA, George, Anthony ,  WAGNER, William, Joseph

IPC: C07D213/89

CPC classification number: C07D213/89 ,  C07F5/022

Abstract: The present invention provides a novel compound represented as (I). The present novel compound is prepared by reacting fluorine with pyridine-boron trifluoride and is useful as a fluorinating agent in the fluorination of organic compounds.

Abstract translation: 本发明提供了表示为（I）的新型化合物。 本发明的新化合物是通过使氟与吡啶 - 三氟化硼反应制备的并且可用作氟化有机化合物中的氟化剂。

公开(公告)号：EP0471755A1

公开(公告)日：1992-02-26

申请号：EP90907683.0

申请日：1990-04-30

Applicant: AlliedSignal Inc.

Inventor： VAN DER PUY, Michael ,  NALEWAJEK, David ,  SHIA, George, Anthony ,  WAGNER, William, Joseph

IPC: C07D213 ,  C07F5

CPC classification number: C07D213/89 ,  C07F5/022

Abstract: L'invention concerne un nouveau composé représenté par la formule (I). Ce nouveau composé est préparé par réaction de fluor avec du trifluorure de pyridine-bore et est utile en tant qu'agent de fluorination pour la fluorination de composés organiques.

Abstract translation: 本发明涉及由式（I）表示的新型化合物。 该新化合物通过氟与吡啶 - 三氟化硼的反应制备，并且可用作有机化合物氟化的氟化剂。