公开(公告)号：US20150141595A1

公开(公告)日：2015-05-21

申请号：US14406390

申请日：2013-05-13

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Alessandro Mignogan ,  Simona Esposito ,  Simona Guidotti ,  Giampiero Morini ,  Joachim T.M. Pater ,  Fabrizio Piemontesi ,  Gianni Vitale

IPC: C08F110/08

CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

Abstract: Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I) In which the R groups equal to or different from each other, are C1-C15 hydrocarbon groups, the R1-R2 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor

Abstract translation: 在催化剂存在下进行丁烯-1的聚合方法，包括（a）包含Mg，Ti和下式（I）的电子给体化合物的固体催化剂组分：其中R基团等于或不同于 彼此是C1-C15烃基，R1-R2基彼此相同或不同，是氢，卤素或C1-C15烃基，任选地含有选自卤素，P，S，N和Si的杂原子 ，n和m为0〜3的整数，条件是它们中的至少一个不同于0; （b）烷基铝助催化剂和（c）外电子给体

公开(公告)号：US12286504B2

公开(公告)日：2025-04-29

申请号：US17642460

申请日：2020-08-27

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Fabrizio Piemontesi ,  Alessandro Mignogna ,  Dario Liguori ,  Giampiero Morini ,  Tiziano Dall'Occo ,  Gianni Vitale

IPC: C08F4/76 ,  C08F4/654 ,  C08F10/06

Abstract: A solid catalyst component for the polymerization of olefins made from or containing a magnesium halide, a titanium compound having at least a Ti-halogen bond, a first electron donor compound selected from 1,3 diethers (DE), and a second electron donor compound selected from dicarbamates (DC), wherein the first and second electron donor compounds are present in a molar ratio DE:DC ranging from 4.5:1 to 20:1.

公开(公告)号：US20240218091A1

公开(公告)日：2024-07-04

申请号：US18285835

申请日：2022-03-24

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Dario Liguori ,  Tiziano Dall'occo ,  Giampiero Morini ,  Gianni Vitale

IPC: C08F10/02

CPC classification number: C08F10/02

Abstract: A pre-polymerized catalyst component for the polymerization of olefins made from or containing (a) a solid catalyst component made from or containing Ti, Mg, and a halogen and optionally, a bidentate electron donor compound (BE) in an amount such that the molar ratio (BE)/Ti ranges from 0 to 0.3, and (b) an ethylene (co)polymer in an amount ranging from 0.1 g up to less than 30 g per g of the solid catalyst component, and having an intrinsic viscosity, measured in tetraline at 135° C., of at least 3.0 dL/g, wherein the pre-polymerized catalyst component has a porosity measured by mercury method in the range 0.1 to 1 cm3/g.

公开(公告)号：US11028259B2

公开(公告)日：2021-06-08

申请号：US15750799

申请日：2016-07-19

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Caroline Cathelin ,  Claudio Cavalieri ,  Marco Ciarafoni ,  Andrea Felisati ,  Angelo Ferraro ,  Giampiero Morini ,  Fabrizio Piemontesi ,  Gianni Vitale

IPC: C08L23/14 ,  B32B27/32 ,  B32B27/08

Abstract: A multilayer film made from or containing a skin layer made from or containing a polyolefin composition made from or containing:
A) from 19 wt % to 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and
B) from 50 wt % to 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt % to 6.0 wt % and 1-butene derived units content of between 4.8 wt % to 12.4 wt %;
the sum of the amount of component A) and B) being 100;
the composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; the creep and recovery curve measured on the polymer fuse at 200° C. shows a maximum value between 600 and 1200 seconds, lower than 53×10−5 1/Pa.

公开(公告)号：US10730974B2

公开(公告)日：2020-08-04

申请号：US15750469

申请日：2016-08-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Giampiero Morini ,  Massimo Covezzi ,  Tiziano Dall'occo ,  Dario Liguori ,  Fabrizio Piemontesi ,  Gianni Vitale

IPC: C08F110/06 ,  C08F4/654 ,  C08F4/655 ,  C08F4/656 ,  C08F4/651 ,  C08F10/06 ,  C08F110/02 ,  C08F2/34 ,  C08F4/649

Abstract: A gas-phase process for the homopolymerization or copolymerization of propylene with other olefins, including carrying out the polymerization in the presence of a catalyst system made from or containing: (a) a solid catalyst component made from or containing Mg, Ti, halogen, an electron donor selected from 1.3-diethers and an olefin polymer in a specific amount; (b) an aluminum alkyl compound and (c) an external electron donor (ED) compound, wherein components (b) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from about 2 to about 200.

公开(公告)号：US09676883B2

公开(公告)日：2017-06-13

申请号：US15309042

申请日：2015-05-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Fabrizio Piemontesi ,  Caroline Cathelin ,  Simona Guidotti ,  Dario Liguori ,  Giampiero Morini ,  Davide Tartari ,  Gianni Vitale

IPC: C08L23/00 ,  C08F2/00 ,  C08F210/00 ,  C08F210/06

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/6574

Abstract: The present disclosure relates to propylene-ethylene copolymers comprising an ethylene content of 0.1-10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 3.0 and a xylene soluble (XS) fraction content defined by values that fall below the line given by the equation XS=1.0296·e0.435C2. The propylene-ethylene copolymers advantageously exhibit high transparency and low melting temperatures.

公开(公告)号：US11466107B2

公开(公告)日：2022-10-11

申请号：US16967587

申请日：2019-01-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Simona Guidotti ,  Dario Liguori ,  Giampiero Morini ,  Gianni Vitale

IPC: C08F4/02 ,  C08F4/20 ,  C08F4/646 ,  C08F110/06 ,  C08F4/657

Abstract: A solid catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, a halogen and an electron donor.

公开(公告)号：US11407844B2

公开(公告)日：2022-08-09

申请号：US17312264

申请日：2019-12-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Alessandro Mignogna ,  Dario Liguori ,  Giampiero Morini ,  Gianni Vitale

IPC: C08F4/651 ,  C08F10/06 ,  C08F4/659

Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from diphenol derivatives.

公开(公告)号：US11149101B2

公开(公告)日：2021-10-19

申请号：US16632175

申请日：2018-07-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Caroline Cathelin ,  Claudio Cavalieri ,  Marco Ciarafoni ,  Roberto Pantaleoni ,  Giampiero Morini ,  Gianni Vitale ,  Fabrizio Piemontesi ,  Gianni Collina ,  Benedetta Gaddi

IPC: C08F210/06 ,  C08F210/14 ,  C08J5/18

Abstract: A propylene 1-hexene copolymer containing from 5.7 to 7.7% by weight of 1-hexene derived units, based upon the total weight of the propylene 1-hexene copolymer, having:
a) a solubility in xylene at 25° C. ranging from 7.0 wt % to 15.0 wt %, based upon the total weight of the propylene 1-hexene copolymer;
b) a melting temperature, measured by DSC ranging from 143.0° C. to 148.0° C.;
c) a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230° C./2.16 kg) from 3.5 to 8.0 g/10 min.; and
d) a content of 1-hexene derived units in the fraction soluble in xylene at 25° C. ranging from 13.5 wt % to 18.5 wt %, based upon the total weight of the soluble fraction.

公开(公告)号：US10894849B2

公开(公告)日：2021-01-19

申请号：US15750123

申请日：2016-07-19

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Fabrizio Piemontesi ,  Gianni Vitale ,  Caroline Cathelin ,  Giampiero Morini ,  Claudio Cavalieri ,  Marco Ciarafoni ,  Roberto Pantaleoni

IPC: C08J9/00 ,  C08F210/06 ,  C08J5/18 ,  C08L23/14

Abstract: A polyolefin composition made from or containing: A) from about 19 wt % to about 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt % B) from about 50 wt % to about 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt % and 1-butene derived units content between about 4.8 wt % and about 12.4 wt %; the sum of the amount of component A) and B) being 100; the polyolefin composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than about 4.0; the creep and recovery curve measured on the polymer fuse at 200° C. shows a maximum value between 600 and 1200 seconds, lower than about 53×10−4 1/Pa.