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公开(公告)号：WO2007014842A1
公开(公告)日：2007-02-08
申请号：PCT/EP2006/064346
申请日：2006-07-18
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , BIGIAVI, Daniele , PENZO, Giuseppe
Inventor： BIGIAVI, Daniele , PENZO, Giuseppe
CPC classification number: C08F10/00 , C08F110/08 , C08F2/06
Abstract: A solution process for polymerizing one or more α-olefins of formula CH 2 =CHR, where R is H or an alkyl radical C 1-12 , to produce a polymer that is soluble in the reaction medium, the process comprising: (a) polymerizat ion in a solution phase of one or more α-olefins in the presence of an organo-aluminum compound and a catalyst system comprising a transition metal compound as the catalyst component; (b) the polymeric solution obtained from step a) is then pressurized and transferred by means of a screw pump to a successive step for removing the unreacted monomers from the polymer; wherein the pumping capacity of said screw pump is kept constant by adding the polymeric solution with water at a feeding point upstream the screw pump.
Abstract translation: 用于聚合一种或多种式CH 2 CH 2的α-烯烃的溶液方法，其中R是H或烷基C 1-12，以产生聚合物， 所述方法包括：（a）在有机铝化合物和包含过渡金属化合物作为催化剂组分的催化剂体系的存在下，在一种或多种α-烯烃的溶液相中聚合; （b）然后通过螺杆泵将从步骤a）获得的聚合物溶液加压并转移到从聚合物中除去未反应单体的连续步骤; 其中所述螺杆泵的泵送能力通过在螺杆泵上游的进料点处加入聚合物溶液而保持恒定。
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公开(公告)号：WO2012031986A1
公开(公告)日：2012-03-15
申请号：PCT/EP2011/065210
申请日：2011-09-02
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , SOFFRITTI, Silvia , RINALDI, Riccardo , DORINI, Maurizio , PENZO, Giuseppe
Inventor： SOFFRITTI, Silvia , RINALDI, Riccardo , DORINI, Maurizio , PENZO, Giuseppe
CPC classification number: B01J8/0085 , B01J8/0055 , B01J8/1827 , B01J8/388 , B01J8/44 , B01J2208/00274 , B01J2208/00292 , B01J2208/00557 , B01J2208/00584 , B01J2208/00681 , B01J2208/0069 , B01J2208/00707 , B01J2219/0077 , C08F10/02 , C08F110/06 , C08F210/06 , C08F2/34 , C08F2/001 , C08F2500/12 , C08F2500/24 , C08F210/16
Abstract: A gas-phase polymerization reactor having interconnected polymerization zones comprising: - a riser through which the polymer particles flow upwards under fast fluidization conditions or transport conditions; -a dowcomer through which the polymer particles flow downward in a densified form under the action of gravity, the bottom of said downcomer being connected to the lower region of said riser by means of a transport section, said transport section being designed as a bend descending from the downcomer to the riser.
Abstract translation: 一种具有互连聚合区的气相聚合反应器，包括： - 提升管，聚合物颗粒在快速流化条件或运输条件下向上流动; 聚合物颗粒在重力作用下以致密化形式向下流动的下沉器，所述降液管的底部通过传送部分连接到所述提升管的下部区域，所述传送部分被设计为弯曲下降 从降液到冒口。
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公开(公告)号：WO2009144144A1
公开(公告)日：2009-12-03
申请号：PCT/EP2009/055916
申请日：2009-05-15
Applicant: Basell Poliolefine Italia s.r.l. , RINALDI, Riccardo , MAZZUCCO, Antonio , BALESTRA, Enrico , PENZO, Giuseppe , DORINI, Maurizio , MEI, Gabriele
Inventor： RINALDI, Riccardo , MAZZUCCO, Antonio , BALESTRA, Enrico , PENZO, Giuseppe , DORINI, Maurizio , MEI, Gabriele
CPC classification number: B01J19/2435 , B01J19/2465 , B01J2219/00087 , C08F10/00 , C08F110/02 , C08F110/06 , Y10S526/901 , C08F2/34 , C08F2/001 , C08F2/01 , C08F2500/05 , C08F2500/15
Abstract: A process for the polymerisation of olefins carried out in a gas-phase reactor having interconnected polymerization zones, where the growing polymer particles flow upward through a first polymerization zone (riser) under fast fluidization or transport conditions, leave said riser and enter a second polymerization zone (downcomer) through which they flow downward under the action of gravity, leave said downcomer and are reintroduced into the riser, a gas recycle stream being withdrawn from said first polymerisation zone, subjected to cooling below its dew point and then returned to said first polymerisation zone, the process being characterised in that said gas recycle stream is cooled at a temperature Tc ranging from 0.05°C to 3°C below its dew point.
Abstract translation: 在具有相互连接的聚合区的气相反应器中进行烯烃聚合的方法，其中生长的聚合物颗粒在快速流化或输送条件下向上流过第一聚合区（提升管），离开所述提升管并进入第二聚合 （下降管），通过它们在重力作用下向下流动，离开所述下降管并重新引入提升管，从所述第一聚合区域排出的气体循环物流经历其低于其露点的冷却，然后返回到所述第一 聚合区，其特征在于所述气体再循环流在低于露点的0.05℃至3℃的温度Tc下冷却。
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14.发明申请METHOD AND APPARATUS FOR GAS-SOLID SEPARATION, APPLICATION TO POLYMERIZATION REACTIONS 审中-公开用于气固分离的方法和装置，应用于聚合反应
公开(公告)号：WO2009071414A1
公开(公告)日：2009-06-11
申请号：PCT/EP2008/065054
申请日：2008-11-06
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： RINALDI, Roberto , PENZO, Giuseppe
CPC classification number: B01D45/14 , B01J8/0055 , B01J8/18 , B01J19/2435 , B01J2208/00274 , B01J2208/00761 , B01J2219/00006 , B01J2219/00094 , B01J2219/00105 , B04C5/13 , B04C9/00 , B04C2009/007 , C08F6/005 , C08F10/00 , C08F2/001
Abstract: Method and apparatus for the gas-solid separation comprising a separation chamber provided with a rotating hollow body, mounted at the top wall of said separation chamber. The rotating hollow body comprises a plurality of spaced-apart blades defining openings for the passage of gas, but rejecting solid particles entrained by the gas. The apparatus comprises also a cylindrical baffle surrounding the rotating hollow body to further deviate a mixed-phase gas-solids stream entering the separation chamber, and to promote settling of solid particles. The gas-solid separation method can be used to separate a gas-polymer mixture produced in a polymerization process.
Abstract translation: 用于气固分离的方法和装置包括安装在所述分离室的顶壁处的设置有旋转中空体的分离室。 旋转中空体包括多个间隔开的叶片，其限定用于气体通过的开口，但是排出由气体夹带的固体颗粒。 该设备还包括围绕旋转中空体的圆柱形挡板，以进一步偏离进入分离室的混合气体 - 固体物流，并促进固体颗粒的沉降。 气固分离方法可用于分离在聚合过程中产生的气体 - 聚合物混合物。
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公开(公告)号：WO2009037080A1
公开(公告)日：2009-03-26
申请号：PCT/EP2008/061234
申请日：2008-08-27
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , DORINI, Maurizio , PENZO, Giuseppe , RINALDI, Riccardo
Inventor： DORINI, Maurizio , PENZO, Giuseppe , RINALDI, Riccardo
CPC classification number: B01J8/1809 , B01J19/2435 , B01J2208/00212 , B01J2208/0061 , B01J2219/0004 , C08F10/06 , C08F110/06 , C08F210/16 , C08F2/34 , C08F2/001 , C08F2500/12 , C08F210/08
Abstract: A process for the multistage polymerization of olefins in a sequence of an upstream slurry reactor and a downstream gas-phase reactor, the transfer of polymer from the upstream reactor to the downstream reactor comprising the following steps: a) heating the slurry of polyolefin particles to evaporate the liquid polymerization medium; b) separating the polyolefin particles from the obtained gaseous phase in at least a separation chamber; c) transferring the polyolefin particles to said downstream reactor by means of a couple of lock hoppers working intermittently in parallel, where one of said lock hoppers is continuously filled with the polymer coming from said separation chamber, while simultaneously the other one is continuously pressurized by means of a gas comprising the reaction mixture coming from said downstream reactor.
Abstract translation: 一种用于上游浆料反应器和下游气相反应器的顺序的烯烃多段聚合的方法，将聚合物从上游反应器转移到下游反应器，包括以下步骤：a）将聚烯烃颗粒的浆料加热至 蒸发液体聚合介质; b）在至少分离室中从所获得的气相中分离聚烯烃颗粒; c）通过一对间歇地并行工作的一对锁定料斗将聚烯烃颗粒转移到所述下游反应器，其中一个所述锁定料斗连续地填充有来自所述分离室的聚合物，同时另一个由 包括来自所述下游反应器的反应混合物的气体的方法。
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Patent Agency Ranking
公开(公告)号：EP2613873B1
公开(公告)日：2018-03-14
申请号：EP11751905.8
申请日：2011-09-02
Applicant: Basell Poliolefine Italia S.r.l.
Inventor： SOFFRITTI, Silvia , RINALDI, Riccardo , DORINI, Maurizio , PENZO, Giuseppe
CPC classification number: B01J8/0085 , B01J8/0055 , B01J8/1827 , B01J8/388 , B01J8/44 , B01J2208/00274 , B01J2208/00292 , B01J2208/00557 , B01J2208/00584 , B01J2208/00681 , B01J2208/0069 , B01J2208/00707 , B01J2219/0077 , C08F10/02 , C08F110/06 , C08F210/06 , C08F2/34 , C08F2/001 , C08F2500/12 , C08F2500/24 , C08F210/16
Abstract: A gas-phase polymerization reactor having interconnected polymerization zones comprising:—a riser through which the polymer particles flow upwards under fast fluidization conditions or transport conditions;—a downcomer through which the polymer particles flow downward in a densified form under the action of gravity, the bottom of said downcomer being connected to the lower region of said riser by means of a transport section, said transport section being designed as a bend descending from the downcomer to the riser.
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17.发明授权APPARATUS AND PROCESS FOR THE LIQUID-PHASE POLYMERIZATION OF OLEFINS 有权DEVICE AND METHOD FOR烯烃在液相聚合
公开(公告)号：EP2109498B1
公开(公告)日：2016-11-16
申请号：EP08708269.9
申请日：2008-01-28
Applicant: Basell Poliolefine Italia S.r.l.
Inventor： DORINI, Maurizio , PENZO, Giuseppe , SABBIONI, Sergio
IPC: B01J8/38 , B01J19/18 , B01J19/24 , C08F2/01 , C08F2/14 , C08F10/00 , C08F210/06 , C08F210/16
CPC classification number: C08F10/00 , B01J8/386 , B01J19/1837 , B01J19/2435 , B01J2219/00006 , B01J2219/0004 , C08F210/06 , C08F2/14 , C08F2/001 , C08F2/01 , C08F210/16
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18.发明公开PROCESS AND APPARATUS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS 有权VERFAHREN UND VORRICHTUNG ZUR GASPHASENPOLYMERISATION VON OLEFINEN
公开(公告)号：EP2613873A1
公开(公告)日：2013-07-17
申请号：EP11751905.8
申请日：2011-09-02
Applicant: Basell Poliolefine Italia S.r.l.
Inventor： SOFFRITTI, Silvia , RINALDI, Riccardo , DORINI, Maurizio , PENZO, Giuseppe
CPC classification number: B01J8/0085 , B01J8/0055 , B01J8/1827 , B01J8/388 , B01J8/44 , B01J2208/00274 , B01J2208/00292 , B01J2208/00557 , B01J2208/00584 , B01J2208/00681 , B01J2208/0069 , B01J2208/00707 , B01J2219/0077 , C08F10/02 , C08F110/06 , C08F210/06 , C08F2/34 , C08F2/001 , C08F2500/12 , C08F2500/24 , C08F210/16
Abstract: A gas-phase polymerization reactor having interconnected polymerization zones comprising:—a riser through which the polymer particles flow upwards under fast fluidization conditions or transport conditions;—a downcomer through which the polymer particles flow downward in a densified form under the action of gravity, the bottom of said downcomer being connected to the lower region of said riser by means of a transport section, said transport section being designed as a bend descending from the downcomer to the riser.
Abstract translation: 具有相互连通的聚合区的气相聚合反应器包括： - 提升管，其中聚合物颗粒在快速流化条件或输送条件下向上流动; - 降液管，聚合物颗粒在重力作用下以致密化形式向下流动， 所述降液管的底部借助于运输部分连接到所述提升管的下部区域，所述输送部分被设计成从降液管下降到提升管的弯道。
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公开(公告)号：EP2190889B1
公开(公告)日：2012-03-14
申请号：EP08787527.4
申请日：2008-08-27
Applicant: Basell Poliolefine Italia S.r.l.
Inventor： DORINI, Maurizio , PENZO, Giuseppe , RINALDI, Riccardo
CPC classification number: B01J8/1809 , B01J19/2435 , B01J2208/00212 , B01J2208/0061 , B01J2219/0004 , C08F10/06 , C08F110/06 , C08F210/16 , C08F2/34 , C08F2/001 , C08F2500/12 , C08F210/08
Abstract: A process for the multistage polymerization of olefins in a sequence of an upstream slurry reactor and a downstream gas-phase reactor, the transfer of polymer from the upstream reactor to the downstream reactor comprising the following steps: a) heating the slurry of polyolefin particles to evaporate the liquid polymerization medium; b) separating the polyolefin particles from the obtained gaseous phase in at least a separation chamber; c) transferring the polyolefin particles to said downstream reactor by means of a couple of lock hoppers working intermittently in parallel, where one of said lock hoppers is continuously filled with the polymer coming from said separation chamber, while simultaneously the other one is continuously pressurized by means of a gas comprising the reaction mixture coming from said downstream reactor.
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公开(公告)号：EP2225022B1
公开(公告)日：2011-06-08
申请号：EP08863810.1
申请日：2008-12-17
Applicant: Basell Poliolefine Italia S.r.l.
Inventor： MAZZUCCO, Antonio , RINALDI, Riccardo , SOFFRITTI, Silvia , BALESTRA, Enrico , PENZO, Giuseppe , MEI, Gabriele
CPC classification number: B01J19/2435 , B01J2219/00164 , B01J2219/00166 , B01J2219/00173 , C08F10/00 , C08F110/06 , C08F210/06 , C08F2/34 , C08F2/001 , C08F2500/05 , C08F210/16
Abstract: A process for the gas-phase polymerization of α-olefms carried out in two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, the process being characterized in that: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid stream LB having a composition different from the gaseous mixture present in the riser; (b) the ratio R between the flow rate Fp of polymer circulated between said downcomer and said riser and the flow rate LB of said liquid being adjusted in a range from 10 to 50.
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