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    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS
    11.
    发明公开
    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的催化剂组分

    公开(公告)号：EP2029277A1

    公开(公告)日：2009-03-04

    申请号：EP07729982.4

    申请日：2007-06-07

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： COLLINA, Gianni ,  DI DIEGO, Maria ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  VINCENZI, Paolo

    IPC: B01J27/135 ,  B01J27/138 ,  C08F4/642 ,  C08F10/00

    CPC classification number: C08F10/00 ,  C08F210/06 ,  C08F4/6545 ,  C08F4/651 ,  C08F2/001 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and an electron donor is obtained by a batch process comprising: (A) A first step comprising reacting an adduct of formula MgCl2(ROH)n, where R is a C1-C10 alkyl group, and n is from 0.5 to 6, in a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature ranging from 0°C to 80°C and then removing the liquid medium; (B) A subsequent step comprising reacting the solid product obtained in (A) in a liquid medium comprising an electron donor ED selected from ethers, esters, ketones, silanes, amines, nitriles and amides, and a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C and then, after removing the liquid medium; (C) A subsequent step comprising reacting the solid product coming from (B) with a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C.

    Abstract translation: 包括Mg，Ti，卤素和电子给体的烯烃聚合的催化剂组分通过间歇方法获得，该方法包括：（A）第一步，该方法包括使式MgCl 2（ROH）n的加合物（其中R为C 1 -C 10 烷基，并且n为0.5-6，在包含至少具有Ti-Cl键的钛化合物的液体介质中，在0℃至80℃的温度范围内，然后除去液体介质; （B）随后的步骤包括使在（A）中获得的固体产物在包含选自醚，酯，酮，硅烷，胺，腈和酰胺的电子给体ED的液体介质中与具有至少一个Ti -Cl键的温度高于80℃，然后除去液体介质后， （C）随后的步骤包括使来自（B）的固体产物与包含至少具有Ti-Cl键的钛化合物的液体介质在高于80℃的温度下反应。

    HIGHLY STEREOREGULAR POLYPROPYLENE WITH IMPROVED PROPERTIES
    17.
    发明公开
    HIGHLY STEREOREGULAR POLYPROPYLENE WITH IMPROVED PROPERTIES 审中-公开
    具有改进的性能HIGHLY STEREO常规聚丙烯

    公开(公告)号：EP2222719A2

    公开(公告)日：2010-09-01

    申请号：EP08865031.2

    申请日：2008-12-09

    Applicant: Basell Poliolefine Italia S.R.L.

    Inventor： VINCENZI, Paolo ,  PATRONCINI, Giovanni

    IPC: C08F4/651 ,  C08F110/06

    CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/18 ,  C08F2500/24

    Abstract: Catalyst component having average particle size equal to or lower than 40 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 15 to 50% by mol with respect to the total amount of donors and selected from succinates of formula (I) below (I) in which the radicals R1 and R2, equal to, or different from, each other are a C1-C20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms; and the radicals R3 and R4 equal to, or different from, each other, are C1-C20 alkyl, C3-C20 cycloalkyl, C5-C20 aryl, arylalkyl or alkylaryl group with the proviso that at least one of them is a branched alkyl; said compounds being, with respect to the two asymmetric carbon atoms identified in the structure of formula (I), stereoisomers of the type (S, R) or (R, S) and at least another electron donor compound which is extractable, under the test of extractability disclosed in the characterization section, for more than 30% by mol.

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