公开(公告)号：MY116967A

公开(公告)日：2004-04-30

申请号：MYPI9704170

申请日：1997-09-09

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  VOIT GUIDO ,  LUYKEN HERMANN ,  FLICK KLEMENS ,  BABLER PETER

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A PROCESS FOR COPRODUCTION OF 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE STARTING FROM A MIXTURE COMPRISING A PHOSPHORUS-CONTAINING COMPOUND AND ESSENTIALLY ADIPONITRILE AND OBTAINED BY REACTION OF BUTADIENE WITH HYDROCYANIC ACID IN THE PRESENCE OF A CATALYST COMPRISING A PHOSPHORUS-CONTAINING COMPOUND COMPRISES (1)REDUCING THE WEIGHT PROPORTION OF PHOSPHORUS-CONTAINING COMPOUND, CALCULATED AS PHOSPHORUS, IN THE MIXTURE, (2)PARTIALLY HYDROGENATING THE RESULTING MIXTURE IN THE PRESENCE OF A CATALYST TO FORM AN (ALPHA),( )-AMINONITRILE, AND (3)REMOVING 6-AMINOCAPRONITRILE AND HEXAMETHYLENEDIAMINE FROM THE MIXTURE.