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公开(公告)号:DE19807502A1
公开(公告)日:1999-09-16
申请号:DE19807502
申请日:1998-02-21
Applicant: BASF AG
Inventor: FUNK RUEDIGER , FRENZ VOLKER , RIEGEL ULRICH , WEISMANTEL MATTHIAS , ENGELHARDT FRITZ , DANIEL THOMAS
IPC: C07D263/20 , A61L15/00 , A61L15/60 , C08F8/30 , C08J3/24 , B65D65/42 , B65D81/20 , C08F220/06 , D06M15/19
Abstract: The invention relates to a method for the gel-phase or surface secondary cross-linking of water-absorbent polymers, characterized in that the polymer is treated with a solution for surface secondary cross-linking, during or after treatment undergoes secondary cross-linking by temperature elevation and is then dried. Dissolved in an inert solvent the cross-linking agent contains a compound of formula (I), where R and R independently of each other are H, hydroxy, phenyl or C1-C6-alkyl, R is hydrogen, C1-C12-alkyl, C1-C12-alkenyl or C6-C12-aryl and R and R independently of each other are C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl, hydroxy, C1-C12-alkoxy or hydrogen. The invention also relates to water-absorbent polymers obtained according to the above method, and to their use in hygiene articles, packaging materials and non-woven materials.
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公开(公告)号:AU2927199A
公开(公告)日:1999-09-06
申请号:AU2927199
申请日:1999-02-19
Applicant: BASF AG
Inventor: FUNK RUDIGER , FRENZ VOLKER , RIEGEL ULRICH , WEISMANTEL MATTHIAS , ENGELHARDT FRITZ , DANIEL THOMAS
IPC: C07D263/20 , A61L15/00 , A61L15/60 , C08F8/30
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公开(公告)号:CA2316342A1
公开(公告)日:1999-07-29
申请号:CA2316342
申请日:1999-01-20
Applicant: BASF AG
Inventor: RIEGEL ULRICH , WEISMANTEL MATTHIAS , FUNK RUDIGER , ENGELHARDT FRITZ , DANIEL THOMAS , HERFERT NORBERT
IPC: C08J7/04 , B01J13/02 , B01J20/26 , C08F251/00 , C08F251/02 , C08J3/12 , C08L51/00 , C08L51/02
Abstract: The invention relates to a hydrogel, comprising a hydrophilic hydrogel with a high swelling capacity which is reversibly coated with a material which delays or prevents the uptake of water or aqueous fluids. The invention also relates to a method for producing the hydrogel and to a method for releasing said hydrophilic hydrogel with a high swelling capacity.
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公开(公告)号:AT328910T
公开(公告)日:2006-06-15
申请号:AT99958068
申请日:1999-11-18
Applicant: BASF AG
Inventor: RIEGEL ULRICH , WEISMANTEL MATTHIAS , FRENZ VOLKER , DANIEL THOMAS , ENGELHARDT FRITZ
IPC: A21B1/22 , A21B1/44 , A61F13/53 , A61L15/60 , C08F8/30 , C08J3/24 , C08K5/353 , C08L101/00 , D04H1/42 , D06M15/263
Abstract: Liquid-absorbent polymers are prepared by a process for the gel and/or surface postcrosslinking of water-absorbent polymers by the polymer being treated with a surface postcrosslinking solution and being postcrosslinked and dried during and after the treatment by raising the temperature, wherein the surface postcrosslinking solution comprises as crosslinker a compound of the formula IwhereR1, R2, R3 and R4 are independently hydrogen, C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl or C1-C12-alkoxy,R5 is C1-C16-alkyl, C1-C4-hydroxyalkyl, C6-C12-aryl, C1-C16-alkenyl or a group of the formula -(CH2)n-COOH or -(CH2)n-SO3H in the form of the acid or a respective metal salt, ammonium salt or triethanolammonium salt thereof or -(CH2-CH2-O-)m-R6,R6 is hydrogen or C1-C16-alkyl,n is from 1 to 10,m is from 1 to 20dissolved in an inert solvent,and are used in hygiene articles, packaging materials and nonwovens.
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公开(公告)号:DE19807502B4
公开(公告)日:2004-04-08
申请号:DE19807502
申请日:1998-02-21
Applicant: BASF AG
Inventor: FUNK RUEDIGER , FRENZ VOLKER , RIEGEL ULRICH , WEISMANTEL MATTHIAS , ENGELHARDT FRITZ , DANIEL THOMAS
IPC: C07D263/20 , A61L15/00 , A61L15/60 , C08F8/30 , C08J3/24 , B65D65/42 , B65D81/20 , C08F220/06 , D06M15/19
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公开(公告)号:DE59908601D1
公开(公告)日:2004-03-25
申请号:DE59908601
申请日:1999-11-23
Applicant: BASF AG
Inventor: RIEGEL ULRICH , WEISMANTEL MATTHIAS , FRENZ VOLKER , DANIEL THOMAS , ENGELHARDT FRITZ
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/00 , C08F8/30 , C08J3/24 , C08K5/357 , C08L101/00
Abstract: Liquid-absorbent polymers are prepared by a process for the gel and/or surface postcrosslinking of water-absorbent polymers by the polymer being treated with a surface postcrosslinking solution and being postcrosslinked and dried during and after the treatment by raising the temperature, wherein the crosslinker comprises a compound of the formula Iwhere R is hydrogen, C1-C4-alkyl, C1-C4-hydroxyalkyl, trialkylsilyl or acetyl and R , R , R , R , R , R are each independently hydrogen, C1-C12-alkyl, C2-C12-alkenyl or C6-C12-aryl, dissolved in an inert solvent, and are used in hygiene articles, packaging materials and nonwovens.
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公开(公告)号:AT259834T
公开(公告)日:2004-03-15
申请号:AT99963322
申请日:1999-11-23
Applicant: BASF AG
Inventor: RIEGEL ULRICH , WEISMANTEL MATTHIAS , FRENZ VOLKER , DANIEL THOMAS , ENGELHARDT FRITZ
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/00 , C08F8/30 , C08J3/24 , C08K5/357 , C08L101/00
Abstract: Liquid-absorbent polymers are prepared by a process for the gel and/or surface postcrosslinking of water-absorbent polymers by the polymer being treated with a surface postcrosslinking solution and being postcrosslinked and dried during and after the treatment by raising the temperature, wherein the crosslinker comprises a compound of the formula Iwhere R is hydrogen, C1-C4-alkyl, C1-C4-hydroxyalkyl, trialkylsilyl or acetyl and R , R , R , R , R , R are each independently hydrogen, C1-C12-alkyl, C2-C12-alkenyl or C6-C12-aryl, dissolved in an inert solvent, and are used in hygiene articles, packaging materials and nonwovens.
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公开(公告)号:BR9908078A
公开(公告)日:2000-10-24
申请号:BR9908078
申请日:1999-02-18
Applicant: BASF AG
Inventor: FUNK RUEDIGER , FRENZ VOLKER , STUEVEN UWE , ENGELHARDT FRITZ , DANIEL THOMAS
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公开(公告)号:BR9908006A
公开(公告)日:2000-10-24
申请号:BR9908006
申请日:1999-02-19
Applicant: BASF AG
Inventor: FUNK RUEDIGER , FRENZ VOLKER , RIEGEL ULRICH , WEISMANTEL MATTHIAS , ENGELHARDT FRITZ , DANIEL THOMAS
IPC: C07D263/20 , A61L15/00 , A61L15/60 , C08F8/30
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公开(公告)号:CA2347897A1
公开(公告)日:2000-06-02
申请号:CA2347897
申请日:1999-11-23
Applicant: BASF AG
Inventor: DANIEL THOMAS , WEISMANTEL MATTHIAS , ENGELHARDT FRITZ , RIEGEL ULRICH , FRENZ VOLKER
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/00 , C08F8/30 , C08J3/24 , C08K5/357 , C08L101/00
Abstract: The invention relates to a method for the secondary cross-linking of gels or surfaces of water-absorbing polymers by treating the polymer with a surface secondary cross-linking agent and subsequently subjecting it to a secondary cross-linking reaction during or after the treatment by raising the temperature and drying the polymer. According to the invention, the cross- linking agent is a compound of formula (I), wherein R1 is hydrogen, C1-C4 alkyl, C1-C4 hydroxyalkyl, trialkylsilyl or acetyl and R2, R2', R3, R3', R4, R4' independently is hydrogen, C1-C12 alkyl, C2-C12 alkenyl or C6-C12 aryl, dissolved in an inert solvent. The invention also relates to the liquid- absorbing polymers obtained by said method, to their use in hygiene items, packaging material and nonwovens.
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