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公开(公告)号:MXPA02012323A
公开(公告)日:2003-04-25
申请号:MXPA02012323
申请日:2001-07-04
Applicant: BASF AG
Inventor: ERNST BAUMANN
IPC: C07C45/42 , C07B61/00 , C07C17/00 , C07C45/27 , C07C45/29 , C07C45/67 , C07C49/433 , C07C49/443 , C07C255/47
Abstract: Procedimiento para la obtencion de 1,3-dicetonas biciclicas de la formula general I; (ver formula) en donde R1, R2, R3 y R4 significan hidogeno, C1-C4-alquilo, C1-C4-alcoxicarbonilo, halogeno, ciano, nitro, C1-C4-alquiltio, C1-C4-alquilsulfenilo y C1-C4-alquilsulfonilo y Z significa C1-C4-alquileno, O, S, N-R5 significando R5 C1-C4-alquilo y C1-C4-alquilcarbonilo en donde a) se hace reaccionar una olefina biciclicas de la formula II con haloformo en presencia de una base, dando un producto de anillo ampliado de la formula III, (Ver formula II y III) en donde R1-R4 y Z tienen los significados arriba indicados y X es halogeno. b) se hidroliza el halogeno alilico del compuesto de la formula III, dando el alcohol alilico de la formula IV (ver formula IV) c) se oxida el alcohol alilico de la formula IV, dando una cetona no saturada de la formula V (ver formula V) d) se transforma la cetona de la formula V con un ion Y- nucleofilo, estabilizador de carga negativa, dando la cetona de la formula VI; (ver formula VI) e) se hidroliza la cetona de la formula VI, dando la 1,3-di-cetona de la formula I. nuevos productos intermedios, asi como nuevos procedimientos para la obtencion de estos productos intermedios.
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公开(公告)号:ZA200704388B
公开(公告)日:2008-07-30
申请号:ZA200704388
申请日:2007-05-29
Applicant: BASF AG
Inventor: MICHAEL HOFMANN , ERNST BAUMANN , WOLFGANG VON DEYN , MARKUS KORDES , LIVIO TEDESCHI , TREACY MICHAEL F , CULBERTSON DEBORAH L , TONI BUCCI , HONG-MING SHIEH , ROBERT AROTIN , NICOLE JOHNSON
IPC: A01N20090101 , A01P20090101 , C07D20090101
Abstract: The present invention relates to new azine compounds which are useful combating animal pests, in particular insects and nematodes and to the salts thereof. The invention also relates to a method for combating insects, nematodes and arachnids. The azine compounds of the invention are described by the general formula (I) wherein . . . is absent or a covalent bond; n is 0 or 1, in particular 0; A is an optionally substituted cyclic radical selected from phenyl and a 5- or 6-membered heterocyclic radical with 1, 2, 3, or 4 heteroatoms; Ar is an optionally substituted aromatic radical selected from phenyl, pyridyl, pyrimidyl, furyl and thienyl, x is selected from halogen, OR 7 , SR 7 , SOR 7 , SO 2 R 7 , C 1 -C 4 -alkyl and C 1 -C 4 -haloalkyl; and wherein R 1 to R 4 and R 7 are as described in the claims and the specification.
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公开(公告)号:ZA200603329B
公开(公告)日:2007-07-25
申请号:ZA200603329
申请日:2006-04-26
Applicant: BASF AG
Inventor: WOLFGANG VON DEYN , ERNST BAUMANN , MICHAEL HOFMANN , MARKUS KORDES , MICHAEL PUHL , THOMAS SCHMIDT , LIVIO TEDESCHI , MICHAEL RACK , TONI BUCCI , CULBERTSON DEBORAH L , TUYL COTTER HENRY VAN , HASSAN OLOUIMI-SADEGHI
IPC: A01N20090101 , A01N41/06 , C07C20090101 , C07C311/16 , C07C311/17 , C07C311/18 , C07C311/19 , C07C311/20 , C07C311/29 , C07C311/48 , C07C317/28 , C07C323/49
Abstract: The invention relates to 2-cyanobenzene-sulfonamide compounds of the formula (I) where the variables R 1 to R 5 are as defined in claim 1 and/or to their agriculturally useful salts. Moreover, the present invention relates to the use of compounds (I) and/or their salts for combating animal pests; agricultural compositions comprising such an amount of at least one compound of the general formula (I) and/or at least one agriculturally useful salt of I and at least one inert liquid and/or solid agronomically acceptable carrier that it has a pesticidal action and, if desired, at least one surfactant; and a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one 2-cyanobenzenesulfonamide compound of the general formula I and/or at least one agriculturally acceptable salt thereof.
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公开(公告)号:CR8462A
公开(公告)日:2007-06-08
申请号:CR8462
申请日:2006-06-16
Applicant: BASF AG
Inventor: MARKUS KORDES , MICHAEL HOFMANN , MICHAEL PUHL , NORBERT GITZ , MICHAEL RACK , ERNST BAUMANN , WOLFGANG VON DEYN , THOMAS SCHMIDT , LIVIO TEDESCHI , MICHAEL F TREACY , DEBORAH L CULBERTSON , TONI BUCCI , DAVID G KUHN
IPC: A01N43/76 , A01N43/78 , C07D263/28 , C07D277/18
Abstract: Compuestos de 1-(azolin-2-il)amino-1,2-difeniletano de la formula general I en donde A es un radical de las formulas A1 o A2 y en donde m es 0,1 2, 3, 4 o 5, n es 0, 1, 2, 3, 4 o 5, X es azufre u oxigeno, y en donde las variables R1, R2, R3, R4, R5a, R5b, R5c, R5d son tal como se definieron en las reivindicaciones, y a sus sales aceptables en agricultura. Un metodo para combatir plagas animales, seleccionadas de inssectos, aracnidos y nematodos y a un metodo para proteger los cultivos del ataque o la infestacion de insectos, aracnidos o nematodos, que comprende poner en contacto un cultivo con una cantidad de eficacia plaguicida de un compuesto de 1-(azolin-2-il)amino-1,2-difeniiletano de la formula general I y/o al menos una de sus sales.
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公开(公告)号:ZA200508106B
公开(公告)日:2007-01-31
申请号:ZA200508106
申请日:2005-10-07
Applicant: BASF AG
Inventor: GERD STEINER , THOMAS SCHMIDT , MARKUS KORDES , WOLFGANG VON DEYN , MICHAEL HOFMANN , ERNST BAUMANN , MICHAEL PUHL , GAVIN HEFFERNAN , CULBERTSON DEBORAH L , TREACY MICHAEL F
IPC: A01N20090101 , A01N43/60 , A01N43/72
Abstract: Use of compounds Formula (I), A=a 5- to 7-membered ring which may contain 1-3 heteroatoms and which may be saturated or partially or completely unsaturated; R 1 -OH, SH, NH 2 , CN, NO 2 , halogen, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl; C 1 -C 6 -alkoxy, C 1 -C 6 -haloalkoxy, C 1 -C 6 -alkylthio, C 1 -C 6 -haloalkylthio, C 2 -C 6 -alkenyl, C 2 -C 6 alkenyloxy, C 2 -C 6 -alkenylthio, C 2 -C 6 -alkynyl, C 2 -C 6 -alkynyloxy, C 2 -C 6 -alkynylthio, C 1 -C 6 -alkylsulfonyl, C 1 -C 6 -alkylsulfoxyl, C 2 -C 6 -alkenylsulfonyl, C 2 -C 6 -alkylsulfoxyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -aklylcarbonyloxy; R 2 -C 1 -C 6 -alkyl or a mono- or bicyclic 5- to 10-membered aromatic ringsystem which may contain 1 to 4 heteroatoms and which is either bonded directly or through an O, S, C 1 -C 6 -alkylene or C 1 -C 6 -alkyleneoxy linkage to A or fused to A and which may be substituted; R 3 , R 4 -H, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, C 1 -C 6 -alkyl-amino, C 1 -C 6 -alkoxy, C 3 -C 6 -cycloalkyl, or R 3 and R 4 together with the nitrogen atom to which they are attached form a saturated or partially saturated mono- or bicyclic 5- to 10-membered ring system containing 1 to 3 heteroatoms or a 5-membered hetaryl containing 1 to 4 nitrogen atoms, wherein the carbon and/or nitrogen atoms in the ring systems may be substituted or phenyl or benzyl which may be substituted; or R 3 and R 4 together form the chains -(CH 2 ) 2 N + (O-)(CH 2 ) 2 - or -(CH 2 ) 3 N + (O - )(CH 2 ) 2 -; m=0 to 4; n is 0 to 4; and the enantiomers, diastereomers, cis/trans isomers or salts thereof for combatting insects, arachnids or nematodes, methods for the control of these pests and of protecting growing plants attack or infestation by these pests by applying a pesticidally effective amount of a compound of formula (I), processes for preparing them, and compositions comprising them.
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公开(公告)号:CR8296A
公开(公告)日:2006-07-14
申请号:CR8296
申请日:2006-03-16
Applicant: BASF AG
Inventor: WOLFANG VON DEYN , ERNST BAUMANN , MICHAEL HOFMANN , MARKUS KORDES , MICHAEL PUHL , THOMAS SCHMIDT , LIVO TEDESCHI , MICHAEL RACK , TONI BUCCI , DEBORAH L CULBERTSON , HENRY VAN TUYL COTTER , HASSAN OLOUMI-SADEGHI
IPC: A01N41/06 , C07C311/16 , C07C311/17 , C07C311/18 , C07C311/19 , C07C311/20 , C07C311/29 , C07C311/48 , C07C317/28 , C07C323/49
Abstract: Compuestos de 2- cianobencenosulfonamida de la formula I en la que las variables R1 a R5 son como se las define en la reivindicacion 1, y/o a sus sales utiles en agricultura.
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