公开(公告)号：ES2112071T3

公开(公告)日：1998-03-16

申请号：ES96104479

申请日：1996-03-21

Applicant: BASF AG

Inventor： GUNTHERBERG NORBERT DR ,  HOFMANN JURGEN ,  MAILAHN ELMAR ,  OHLIG HILMAR ,  GRABOWSKI SVEN DR ,  CZAUDERNA BERNHARD DR

IPC: B29B7/48 ,  B29B7/58 ,  B29B7/88 ,  B29B13/06 ,  B29C48/395 ,  B29C48/76 ,  C08J3/20 ,  C08L9/00 ,  C08L21/00 ,  C08L25/04 ,  C08L27/06 ,  C08L33/04 ,  C08L33/12 ,  C08L51/00 ,  C08L51/04 ,  B29C47/38 ,  B29C47/76

Abstract: A process is claimed for the prodn. of impact-modified thermoplastics (I) by mixing a moist elastomer component (A) contg. up to 60 wt% residual water with a thermoplastic polymer (B) and other polymers (C) and additives (D) in a screw machine, with mechanical dehydration of component (A). The process is carried out in a synchronous twin screw extruder with the following sequence of sections in the direction of feed: (1) metering section(s) for introducing component (A) into the extruder by means of a metering device, (2) squeezing section(s) for removing the water, with accumulator element(s) and associated water outlet(s), (3) section(s) in which polymer (B) is added as a melt, (4) section(s) fitted with mixing, kneading and/or other plasticising elements, (5) degassing section(s) with gas outlets, in which residual water is removed as vapour, and (7) a discharge zone. The water emerging from the outlets in section (2) is partly or completely in the liq. phase; components (C) and/or (D) are added in one or more of the above sections, either together or separately and together with or apart from (A) and/or (B). Also claimed are impact-modified thermoplastic moulding materials (I) obtd. by this process.

公开(公告)号：ES2112003T3

公开(公告)日：1998-03-16

申请号：ES95114707

申请日：1995-09-19

Applicant: BASF AG

Inventor： GUNTHERBERG NORBERT DR ,  WEBER MARTIN DR ,  GRUBER FREDDY DR ,  LINDENSCHMIDT GERHARD DR

IPC: B29C45/00 ,  B29C48/03 ,  B29C48/305 ,  C08F265/06 ,  C08L9/06 ,  C08L21/00 ,  C08L25/02 ,  C08L25/04 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L71/02

Abstract: Thermoplastic moulding materials (I) contain: (A) 30-98 wt.% of a graft copolymer of: (ak) 30-90 wt.% rubber-elastic grafting core, obtd. by copolymerisation of: (ak1) 80-99.99 wt.% (1-10C alkyl) acrylate, (ak2) 0.01-20 wt.% crosslinking monomer, and (ak3) 0-40 wt.% other comonomer(s); and (as) 10-70 wt.% of a grafted shell derived from: (as1) 50-100 wt.% styrene cpd. of formula (a); and (as2) 0-50 wt.% other comonomer(s); (B) 1-50 wt.% of a thermoplastic polymer of: (b1) 50-100 wt.% styrene and/or alpha -methylstyrene (AMS), (b2) 0-50 wt.% acrylonitrile, and (b3) 0-50 wt.% other comonomer(s); and (C) 1-70 wt.% of a copolymer of: (c1) 30-90 wt.% styrene and AMS, (c2) 10-70 wt.% butadiene, and (c3) 0-30 wt.% other comonomer(s); comprising: (i) block X obtd. by polymerising (c2) and opt. (c3) and block Y by polymerising (c1) and opt. (c3), or (ii) a polymer with a butadiene-rich initial segment, increasing amts. of styrene along the chain, and a terminal segment of homo-polystyrene (PS); or (iii) a star-shaped polymer obtd. by linking several polymer chains contg. (c1)-(c3) with polyfunctional mols., and in which the olefinic double bonds are completely or almost completely hydrogenated. Also claimed are films and moulded prods. obtd. from (I). R , R = H or 1-8C alkyl, and/or (1-8C alkyl) (meth)acrylate.