WHOLLY AROMATIC MESOMORPHIC POLYETHER ESTER IMIDES AND THE PREPARATION THEREOF

    公开(公告)号:CA1268292A

    公开(公告)日:1990-04-24

    申请号:CA524457

    申请日:1986-12-03

    Applicant: BASF AG

    Abstract: O.Z. 0050/38145 Wholly aromatic mesomorphic polyether ester imides which form a liquid-crystalline fiber-forming melt below 320.degree.C and are composed of a) from 5 to 35 mol% of repeat units of the formula I (I) b) from 5 to 35 mol% of repeat units of the formula II (II) where X is a chemical bond, -O-, -S-, -SO2-, -CO-, -CH2- or =C(CH3)2, and n is 0 or 1, c) from 15 to 30 mol% of repeat units of the formula III (III) d) a molar amount corresponding to the total amount of b) plus c) minus a) of repeat units of the formulae IV and/or V (IV) (V) e) repeat units of the formula VI (VI) the mole percentages of components a, b, c, d and e adding up to 100 mol% in each case, the preparation thereof and fibers, films and molding prepared therefrom.

    WHOLLY AROMATIC MESOMORPHIC POLYESTER AMIDE IMIDES AND THE PREPARATION THEREOF

    公开(公告)号:CA1268291A

    公开(公告)日:1990-04-24

    申请号:CA524456

    申请日:1986-12-03

    Applicant: BASF AG

    Abstract: Disclosed are wholly aromatic mesomorphic polyester amide imides which form a liquid-crystalline fiberforming melt below 320.degree.C and are composed of: a) from 5 to 35 mol% of repeat units of the formula (I) and/or (II): (I) (II) where X can be identical or different, each X being -O-, -S-, -SO2-, -CO-, -CH2- or =C(CH3)2, and n is 0 or 1, b) from 0 to 30 mol % of repeat units of the formulae (III) and/or (IV): (III) (IV) c) a molar amount corresponding to the total amount of components a) and b) of one or more of the repeat units (V), (VI), (VII), (VIII), (IX) or (X) in an amount of: c1) from 3 to 35 mol % of units of the formula (V): (V) c2) from 0 to 10 mol % of units of the formula (VI): (VI) c3) from 2 to 25 mol % of units of the formula (VII): (VII) c4) from 2 to 20 mol % of units of the formula (VIII): (VIII) c5) from 0 to 20 mol % of the units of the formula (IX): (IX) c6) from 2 to 20 mol % of units of the formula (X): (X) with the provisos that at least one of the repeat units of formulae (VI) or (VII) is allways present in the composition and that the total of the mole percentages of components c1), c2), c3), c4), c5) and c6) equals in each case the total of the mole percentages of components a) and b); d) not less that 10 mol % of repeat units of the formula (XI): (XI) e) from 0 to 25 mol % of one or more of the repeat units of the formula (XII), (XIII) or (XIV): ( X I I ) ( X I I I ) (XIV) the mole percentages of components a), b), c), d) and e) adding up to 100 mol % in each case. Also disclosed are the preparation thereof and fibers, films and moldings prepared therefrom.

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