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    Oxidation of Cycloalkanes
    18.
    发明专利
    Oxidation of Cycloalkanes 未知

    公开(公告)号：GB1164011A

    公开(公告)日：1969-09-10

    申请号：GB92467

    申请日：1967-01-06

    Applicant: BASF AG

    Inventor： HORNBERGER PAUL ,  SUESSENGUTH HERMANN ,  TRITSCHLER HEINRICH

    IPC: C07C29/50 ,  C07C45/33

    Abstract: 1,164,011. Continuous oxidation of cycloalkanes. BADISCHE ANILIN- & SODAFABRIK A.G. 6 Jan., 1967 [7 Jan., 1966], No. 924/67. Heading C2C. In a process for the continuous oxidation of cycloalkanes in liquid phase at elevated temperature and superatmospheric pressure and in the presence of catalysts by distributing oxygen or a gas containing oxygen in molecular form and by producing an internal circulation within the reaction vessel by means of a circulation pipe, some of the gas and/or liquid is introduced in the lower portion of the oxidation chamber in such a way that the flow is directed along the bottom of the reaction vessel or against the bottom and the adjacent wall, the products separating in the liquid during the reaction and any catalyst thus being kept in motion.

    Production of diamines
    20.
    发明专利
    Production of diamines 未知

    公开(公告)号：GB1027508A

    公开(公告)日：1966-04-27

    申请号：GB596563

    申请日：1963-02-14

    Applicant: BASF AG

    Inventor： WINDERL SIEGFRIED ,  HAARER ERICH ,  CORR HUBERT ,  HORNBERGER PAUL

    IPC: B01J23/38 ,  B01J23/70 ,  C07C209/16 ,  C07C211/10 ,  C07C211/11 ,  C07C211/12

    Abstract: Catalysts for the production of diamines (see Division C2) comprise at least one of the metals silver, copper, iron, cobalt and nickel prepared by sintering the metal powder or by reducing the sintered metal oxide or hydroxide, carbonate, nitrate or nitrite before or after shaping. Examples employ sintered Co, (Co + Ni), and (Co + Cu) or Ni. The powdered metal is sintered in admixture with a carrier such as pumice, alumina, corundum, diatomaceous earth, silica gel, silicon carbide, silicates, porcelain or quartz. Promoters such as alkali metal compounds, alkaline earth metal compounds, titanium dioxide, antimony, bismuth, or compounds of Group V or V1 of the Periodic System may also be added.ALSO:Open-chain diamines are prepared by passing a dihydric aliphatic alcohol, an alkanolamine, alkylene oxide or hexamethyleneimine or mixtures thereof, with a stoichiometric excess of ammonia or a primary or secondary amine, in the presence of at least 2 litres of hydrogen per mole of alcohol, alkanolamine, alkylene oxide or hexamethyleneimine, in the presence or absence of water, at 150-300 DEG C. at a pressure of at least 10 atmospheres, over a catalyst containing at least one of the metals silver, copper, iron, cobalt and nickel, said catalyst having been prepared by sintering. Examples prepare (1) ethylene diamine and piperazine from ethylene glycol and ammonia, and 1,2-diaminopropane similarly from 1,2-propanediol; (2) ethylene diamine and piperazine from ethanolamine, diethanolamine and ammonia, or from ethylene oxide and ammonia; (3), (4), (5) 1,6-hexamethylenediamine and hexamethyleneimine from 1,6-hexanediol and ammonia or hexamethyleneimine and ammonia; (6) N,N,N1,N1 - tetra ethyl ethylenediamine and N,N-diethylethanolamine from ethylene glycol and diethylamine; and (7) N-isopropyl-1,3-diaminopropane from 1,3-propanolamine and isopropylamine. Other reactants are listed.ALSO:Catalysts for the production of diamines (see Division C2) contain at least one of the metals silver, copper, iron, cobalt and nickel and are prepared by sintering the powdered metal in admixture with a carrier such as pumice, alumina, corundum, diatomaceous earth, silica gel, silicon carbide, silicates, porcelain or quartz, or by sintering oxides of the metal or compounds converted into oxides at sintering temperature, such as hydroxides, carbonates, nitrates and nitrites, in the presence of a carrier as above and/or a promoter such as alkali metal compounds, alkaline earth metal compounds, titanium dioxide, antimony, bismuth, or compounds of metals of Group V or VI of the Periodic System, and then reducing the sintered oxide with hydrogen.

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