RECOVERY OF ISOBUTYLENE FROM MIXTURES CONTAINING THE SAME AND BUTADIENE

    公开(公告)号:CA929961A

    公开(公告)日:1973-07-10

    申请号:CA76135

    申请日:1970-02-27

    Applicant: BASF AG

    Abstract: 1290072 Recovering isobutylene and butadiene BADISCHE ANILIN- & SODA-FABRIK AG 27 Feb 1970 [1 March 1969] 9508/70 Heading C5E Isobutylene and butadiene are recovered from C 4 -hydrocarbon mixture containing inter alia isobutylene and 0À01-60 wt. per cent butadiene by the following steps:- (a) contact at 25-35‹ C. with an absorption mixture containing 2-25 wt. per cent tert.- butanol, 30-45 wt. per cent sulphuric acid and 30-55 wt. per cent water, whereby isobutylene is hydrated to form more tert.-butanol, most of the butadiene being recovered as raffinate gas; (b) distilling the resulting mixture to obtain an azeotrope of tert.-butanol with about 12% of water; (c) fractionating the azeotrope to obtain a pure fraction comprising not more than 0À03 wt. per cent of impurities; and (d) dehydrating tert.-butanol contained in said pure fraction by contact with active alumina.

    CONTINUOUS PRODUCTION OF PROPYLENE CHLOROHYDRIN

    公开(公告)号:CA923146A

    公开(公告)日:1973-03-20

    申请号:CA109520

    申请日:1971-04-02

    Applicant: BASF AG

    Abstract: 1339650 Propylene chlorohydrin BADISCHE ANILIN- & SODA-FABRIK AG 10 May 1971 [11 May 1970] 13961/71 Heading C2C Propylene chlorohydrin is continuously produced in aqueous solution by reaction of propylene with an aqueous solution of chlorine, the make-up water or the recycled reaction solution or a mixture thereof being loaded with gaseous and/or liquid chlorine in such an amount that that solubility limit is not exceeded, the propylene being metered at 2 to 20 atm. absolute and 10-80‹ C. into the chlorine-laden solution, the reaction mixture being allowed to react to completion in one or more parallel reaction tubes with turbulent flow in the same pressure range with a residence time of not more than ten seconds, the pressure then being released and the by-produets separated if desired, some of the propylene chlorohydrin being withdrawn as product and the remainder being recycled, the process being characterized by the introduction of the chlorine and propylene at a velocity of 2 to 100 m/sec. through one or more nozzles into a mixing zone extending in the direction of flow whose diameter is 1À5 to 50 times the mean outlet diameter of the liquid nozzles and whose length is 3 to 30 times its hydraulic diameter.

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