公开(公告)号：CA2116175A1

公开(公告)日：1994-09-12

申请号：CA2116175

申请日：1994-02-22

Applicant: AYDIN ORAL ,  NEUTZNER JOSEF ,  MAECHTLE WALTER ,  BASF AG

Inventor： AYDIN ORAL DR ,  NEUTZNER JOSEF DR ,  MAECHTLE WALTER DR

IPC: C08F2/22 ,  C08F2/24 ,  C08F265/06 ,  C08F291/00 ,  C09D151/00 ,  C09D151/06 ,  C09J151/06 ,  C09J153/00 ,  C08F2/20

Abstract: In a process for preparing a final aqueous polymer dispersion having a solids volume concentration of 50% by volume or more, free-radically polymerizable monomers other than vinyl or vinylidene halides are subjected to a free radical aqueous emulsion polymerization by the feed stream addition process in the presence of an aqueous starting polymer dispersion whose dispersed starting polymer particles have a certain minimum diameter.

公开(公告)号：DE4206429A1

公开(公告)日：1993-09-02

申请号：DE4206429

申请日：1992-02-29

Applicant: BASF AG

Inventor： DAEUMER BERND DR ,  DRAGON ANDREE ,  BECKERLE WILHELM FRIEDRICH ,  FRANZMANN GERNOT DR ,  NEUTZNER JOSEF DR ,  WISTUBA ECKEHARDT DR

IPC: C04B24/26 ,  C04B28/02 ,  C08F2/30

Abstract: Aq. polymer dispersions (I) are claimed. (I) are obtd. by aq. emulsion polymerisation of a mixt. of (a) 50-80 wt.% vinyl 1-18C alkanoate(s) (unbranched), (b) 5-40 wt.% vinyl 1-20C alkanoate(s) (branched), (c) 0-45 wt.% 1-18C alkyl ester(s) of 2-6C alpha, beta-mono-unsatd. carboxylic acid and (d) 0-5 wt.% other comonomers, in the presence of dispersants (II) and radical initiators (III). (II) comprises (A) 0.5-3 wt.% polyether(s) derived from ethylene oxide (EO) and propylene oxide (PO), (B) 0.5-4 wt.% ethoxylated alkylphenol(s), (C) 0.5-3 wt.% ethoxylated polysaccharide(s) and (D) 0-4 wt.% sulphate half-ester(s) of ethoxylated alkylphenols and/or water soluble salts thereof (% w.r.t. monomer mixt.). USE/ADVANTAGE - Used in aq. or spray-dried form as additives for mineral constructional binders, esp. based on cement (claimed). Also claimed are mineral binders contg. polymer powder obtd. by spray drying (I).

公开(公告)号：ES2150953T3

公开(公告)日：2000-12-16

申请号：ES94103275

申请日：1994-03-04

Applicant: BASF AG

Inventor： AYDIN ORAL DR ,  NEUTZNER JOSEF DR ,  MAECHTLE WALTER DR

IPC: C08F2/22 ,  C08F2/24 ,  C08F265/06 ,  C08F291/00 ,  C09D151/00 ,  C09D151/06 ,  C09J151/06 ,  C09J153/00

公开(公告)号：DE19707221A1

公开(公告)日：1998-08-27

申请号：DE19707221

申请日：1997-02-24

Applicant: BASF AG

Inventor： RUPANER ROBERT DR ,  LEY GREGOR DR ,  ZELLER DIETER DR ,  GEBHARDT NORBERT DR ,  MENDERA PETER ,  HEINZ GERHART ,  NEUTZNER JOSEF DR ,  BAUER GERHARD DR

IPC: A01N25/10 ,  A01N59/16 ,  A01N59/20 ,  C09D5/02 ,  C08J3/20 ,  A01N37/02 ,  C08K5/098

Abstract: In order to prepare an antibacterial and fungicidal polymer dispersion, a polymer dispersion is mixed with an amount of a protective polymer which is dispersible in the polymer dispersion, said amount being sufficient to attain an antibacterial and fungicidal effect. The protective polymer comprises: between 3 and 60 wt %, relative to the total weight of components a) and b) without metallic ions, of at least one C3 to C7 alpha, beta-monoethylenically unsaturated mono or dicarboxylic acid which is partially or completely neutralized or can be present as an anhydride, as component a); between 97 and 40 wt %, relative to the total weight of components a) and b) without metallic ions, of at least one C1 to C20 alkyl(meth)acrylate, of a C1 to C20 carboxylic acid vinyl ester, of a vinyl aromatic containing up to 20 carbon atoms, of an ethylenically unsaturated C3 to C6 nitrile, of a vinyl halide or a non-aromatic C4 to C8 hydrocarbon and at least two conjugated double bonds or ethylene or propylene as component b); between 0 and 50 wt %, relative to the total weight of components a) and b) without metallic ions, of at least one further ethylenically unsaturated monomer, as component c); and between 0 and 20 wt %, relative to the total weight of components a), b) and c) without metallic ions, of at least one cross-linking polyfunctional monomer, as component d). Between 1 and 100 mol % of the acid groups are converted into salts of at least one antibacterial and/or fungicidal metallic ion.

公开(公告)号：DE59303925D1

公开(公告)日：1996-10-31

申请号：DE59303925

申请日：1993-04-06

Applicant: BASF AG

Inventor： BAUER GERHARD DR ,  AYDIN ORAL DR ,  NEUTZNER JOSEF DR

IPC: C08F2/24 ,  C08F265/00 ,  C08F265/06

Abstract: Aqueous polymer dispersions which are obtainable by polymerising free-radical-polymerisable monomers by the process of free-radical aqueous emulsion polymerisation with addition of an aqueous dispersion of a starting polymer.

公开(公告)号：DE59303713D1

公开(公告)日：1996-10-17

申请号：DE59303713

申请日：1993-04-08

Applicant: BASF AG

Inventor： AYDIN ORAL DR ,  PORTUGALL MICHAEL DR ,  NEUTZNER JOSEF DR ,  MAECHTLE WALTER DR

IPC: C08F2/22 ,  C08F2/24 ,  C08F2/44 ,  C08F265/06 ,  C08F291/00

Abstract: An aqueous polymer dispersion having a solids volume concentration of at least 50% by volume which is obtainable by polymerisation of monomers by free-radical aqueous emulsion polymerisation with addition of at least one aqueous starting polymer dispersion with fine particles and at least one with coarse particles.

公开(公告)号：ES2090755T3

公开(公告)日：1996-10-16

申请号：ES93105832

申请日：1993-04-08

Applicant: BASF AG

Inventor： AYDIN ORAL DR ,  PORTUGALL MICHAEL DR ,  NEUTZNER JOSEF DR ,  MAECHTLE WALTER DR

IPC: C08F2/22 ,  C08F2/24 ,  C08F2/44 ,  C08F265/06

Abstract: An aqueous polymer dispersion having a solids volume concentration of 50% by volume or more, obtained by free-radical aqueous emulsion polymerisation of free-radical-polymerisable monomers other than vinyl and vinylidine halides, with addition of an aqueous starting polymer dispersion having a certain diameter distribution of the starting polymer particles present therein, by the feed process.

公开(公告)号：ES2087587T3

公开(公告)日：1996-07-16

申请号：ES93102290

申请日：1993-02-13

Applicant: BASF AG

Inventor： DAEUMER BERND DR ,  DRAGON ANDREE ,  BECKERLE WILHELM FRIEDRICH ,  FRANZMANN GERNOT DR ,  NEUTZNER JOSEF DR ,  WISTUBA ECKEHARDT DR

IPC: C04B24/26 ,  C04B28/02 ,  C08F2/30 ,  C06B26/26

公开(公告)号：FI941173A0

公开(公告)日：1994-03-11

申请号：FI941173

申请日：1994-03-11

Applicant: BASF AG

Inventor： AYDIN ORAL DR ,  NEUTZNER JOSEF DR ,  MAECHTLE WALTER DR

IPC: C08F2/22 ,  C08F2/24 ,  C08F265/06 ,  C08F291/00 ,  C09D151/00 ,  C09D151/06 ,  C09J151/06 ,  C09J153/00 ,  C08F

公开(公告)号：DE4213968A1

公开(公告)日：1993-11-04

申请号：DE4213968

申请日：1992-04-29

Applicant: BASF AG

Inventor： AYDIN ORAL DR ,  PORTUGALL MICHAEL DR ,  NEUTZNER JOSEF DR ,  MAECHTLE WALTER DR

IPC: C08F2/22 ,  C08F2/24 ,  C08F2/44 ,  C08F265/06 ,  C08F291/00 ,  C08F20/12 ,  C08F12/08 ,  C08F14/06 ,  C08F36/06 ,  C08L51/00 ,  C09D151/00 ,  C09D5/02 ,  C09J151/00

Abstract: An aqueous polymer dispersion having a solids volume concentration of at least 50% by volume which is obtainable by polymerisation of monomers by free-radical aqueous emulsion polymerisation with addition of at least two starting polymer dispersions, of which one is both particularly finely divided and contains coarse polymer particles.