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公开(公告)号:BG101907A
公开(公告)日:1998-05-29
申请号:BG10190797
申请日:1997-09-24
Applicant: BASF AG
Inventor: LANGGUTH ERNST , SCHNEIDER REGINA , LIPPERT FERDINAND , HOEHN ARTHUR
Abstract: The invention concerns the production of 3-pentenic acidesters by carbonylation of alkoxybutenes in the presence of acatalyst and a solvent at high temperature and pressure: at leastone C1-C10 alkoxybutene, in which the alkoxy group is in the allylposition relative to the double bond, is converted with carbonmonoxide at a temperature in the 60-140oC range and a carbonmonoxide partial pressure in the 3-30 MPa range, in the presenceof a palladium-based catalyst.4 claims
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公开(公告)号:TR199700998T1
公开(公告)日:1998-01-21
申请号:TR9700998
申请日:1996-03-15
Applicant: BASF AG
Inventor: LANGGUTH ERNST , SCHNEIDER REGINA , LIPPERT FERDINAND , HOHN ARTUR
Abstract: PCT No. PCT/EP96/01123 Sec. 371 Date Sep. 16, 1997 Sec. 102(e) Date Sep. 16, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96/29300 PCT Pub. Date Sep. 26, 19963-Pentenoic esters are prepared by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at elevated temperature and elevated pressure, by reacting at least one C1-C10-alkoxybutene in which the alkoxy group is in the allyl position relative to the double bond with carbon monoxide at from 60 to 140 DEG C. and a carbon monoxide partial pressure in the range from 3 to 30 MPa in the presence of a catalyst based on palladium.
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公开(公告)号:PL322329A1
公开(公告)日:1998-01-19
申请号:PL32232996
申请日:1996-03-15
Applicant: BASF AG
Inventor: LANGGUTH ERNST , SCHNEIDER REGINA , LIPPERT FERDINAND , HOEHN ARTHUR
Abstract: PCT No. PCT/EP96/01123 Sec. 371 Date Sep. 16, 1997 Sec. 102(e) Date Sep. 16, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96/29300 PCT Pub. Date Sep. 26, 19963-Pentenoic esters are prepared by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at elevated temperature and elevated pressure, by reacting at least one C1-C10-alkoxybutene in which the alkoxy group is in the allyl position relative to the double bond with carbon monoxide at from 60 to 140 DEG C. and a carbon monoxide partial pressure in the range from 3 to 30 MPa in the presence of a catalyst based on palladium.
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公开(公告)号:NO974340A
公开(公告)日:1997-09-19
申请号:NO974340
申请日:1997-09-19
Applicant: BASF AG
Inventor: LANGGUTH ERNST , SCHNEIDER REGINA , LIPPERT FERDINAND , HOEHN ARTHUR
CPC classification number: C07C67/37 , C07C69/533
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公开(公告)号:CA2214381A1
公开(公告)日:1996-09-26
申请号:CA2214381
申请日:1996-03-15
Applicant: BASF AG
Inventor: LANGGUTH ERNST , H HN ARTHUR , LIPPERT FERDINAND , SCHNEIDER REGINA
Abstract: The invention concerns the production of 3-pentenic acid esters by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at high temperature and pressure: at least one C1-C10 alkoxybutene, in which the alkoxy group is in the allyl position relative to the double bond, is converted with carbon monoxide at a temperature in the 60-140 ~C range and a carbon monoxide partial pressure in the 3-30 MPa range, in the presence of a palladium-based catalyst.
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公开(公告)号:CA2195479A1
公开(公告)日:1996-02-01
申请号:CA2195479
申请日:1995-07-08
Applicant: BASF AG
Inventor: EBEL KLAUS , SCHNEIDER REGINA , MELDER JOHANN-PETER , TELES JOAQUIM HENRIQUE
IPC: B01J31/02 , C07B61/00 , C07C45/00 , C07C45/72 , C07C47/56 , C07C49/17 , C07C49/487 , C07C49/493 , C07C49/83 , C07C49/84 , C07C67/293 , C07C67/343 , C07C69/67 , C07D213/50 , C07D249/08 , C07D307/52
Abstract: A process is proposed for producing acyloines of general formula (I) in which Ra and Rb are identical or different and represent hydrogen or a C1-C20 alkyl, a C6-C10 aryl, a C7-C12 aralkyl, a heteroaryl, or a heterocycloalkyl group, these groups being substituted if appropriate, with the exception of formaldehyde autocondensation products. In the proposed process, an aldehyde of formula (II) RaCHO is allowed to react with an aldehyde of formula (III) RbCHO, in which Ra and Rb have the meanings indicated above and at least one of the groups Ra and Rb represents a group other than hydrogen, in the presence of catalysts produced using an auxiliary base from triazolium salts of formula (IV) in which R1 and R3 are identical or different and represent aliphatic groups with 1-30 carbon atoms, or, if appropriate, aryl groups, aralkyl groups and/or heteroaryl groups, these groups being substituted if appropriate; R2 represents hydrogen or the group RbCH(OH); and A is the equivalent of a singly or multiply negatively charged anion for the electrical neutralisation of the triazolium cation charge.
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公开(公告)号:ES2148740T3
公开(公告)日:2000-10-16
申请号:ES96908048
申请日:1996-03-15
Applicant: BASF AG
Inventor: LANGGUTH ERNST , SCHNEIDER REGINA , LIPPERT FERDINAND , HOHN ARTHUR
Abstract: PCT No. PCT/EP96/01123 Sec. 371 Date Sep. 16, 1997 Sec. 102(e) Date Sep. 16, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96/29300 PCT Pub. Date Sep. 26, 19963-Pentenoic esters are prepared by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at elevated temperature and elevated pressure, by reacting at least one C1-C10-alkoxybutene in which the alkoxy group is in the allyl position relative to the double bond with carbon monoxide at from 60 to 140 DEG C. and a carbon monoxide partial pressure in the range from 3 to 30 MPa in the presence of a catalyst based on palladium.
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18.
公开(公告)号:BG62848B1
公开(公告)日:2000-09-29
申请号:BG10190797
申请日:1997-09-24
Applicant: BASF AG
Inventor: LANGGUTH ERNST , SCHNEIDER REGINA , LIPPERT FERDINAND , HOEHN ARTHUR
IPC: B01J23/44 , C07B61/00 , C07C67/36 , C07C67/37 , C07C69/33 , C07C69/533 , C07C69/587 , B01J27/10
Abstract: The invention relates to a method for the preparation of esters of the 3-pentene acid by which alkoxybutenes are carbonylized in the presence of a catalyst and solvent at elevated temperature and pressure. These esters are intermediate compounds for the preparation of adipinic acid, caprolactam and caprolactone. The process occurs by the reaction between at least one C1-C10-alkoxybutene where the alkoxygroup is found in allyl position to the double bond with carbon monoxide at temperatures ranging from 60 to 140 deg.C, partial pressure of the carbon monoxide from 3 to 30 MPa and in the presence of a catalyst based on palladium. 4 claims
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公开(公告)号:AT193881T
公开(公告)日:2000-06-15
申请号:AT96908048
申请日:1996-03-15
Applicant: BASF AG
Inventor: LANGGUTH ERNST , SCHNEIDER REGINA , LIPPERT FERDINAND , HOEHN ARTHUR
Abstract: PCT No. PCT/EP96/01123 Sec. 371 Date Sep. 16, 1997 Sec. 102(e) Date Sep. 16, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96/29300 PCT Pub. Date Sep. 26, 19963-Pentenoic esters are prepared by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at elevated temperature and elevated pressure, by reacting at least one C1-C10-alkoxybutene in which the alkoxy group is in the allyl position relative to the double bond with carbon monoxide at from 60 to 140 DEG C. and a carbon monoxide partial pressure in the range from 3 to 30 MPa in the presence of a catalyst based on palladium.
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公开(公告)号:SK126997A3
公开(公告)日:1998-05-06
申请号:SK126997
申请日:1996-03-15
Applicant: BASF AG
Inventor: LANGGUTH ERNST , SCHNEIDER REGINA , LIPPERT FERDINAND , HOHN ARTHUR
Abstract: PCT No. PCT/EP96/01123 Sec. 371 Date Sep. 16, 1997 Sec. 102(e) Date Sep. 16, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96/29300 PCT Pub. Date Sep. 26, 19963-Pentenoic esters are prepared by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at elevated temperature and elevated pressure, by reacting at least one C1-C10-alkoxybutene in which the alkoxy group is in the allyl position relative to the double bond with carbon monoxide at from 60 to 140 DEG C. and a carbon monoxide partial pressure in the range from 3 to 30 MPa in the presence of a catalyst based on palladium.
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