12.
    发明专利
    未知

    公开(公告)号:TR199700998T1

    公开(公告)日:1998-01-21

    申请号:TR9700998

    申请日:1996-03-15

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/01123 Sec. 371 Date Sep. 16, 1997 Sec. 102(e) Date Sep. 16, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96/29300 PCT Pub. Date Sep. 26, 19963-Pentenoic esters are prepared by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at elevated temperature and elevated pressure, by reacting at least one C1-C10-alkoxybutene in which the alkoxy group is in the allyl position relative to the double bond with carbon monoxide at from 60 to 140 DEG C. and a carbon monoxide partial pressure in the range from 3 to 30 MPa in the presence of a catalyst based on palladium.

    METHOD OF PRODUCING ACYLOINES
    16.
    发明专利

    公开(公告)号:CA2195479A1

    公开(公告)日:1996-02-01

    申请号:CA2195479

    申请日:1995-07-08

    Applicant: BASF AG

    Abstract: A process is proposed for producing acyloines of general formula (I) in which Ra and Rb are identical or different and represent hydrogen or a C1-C20 alkyl, a C6-C10 aryl, a C7-C12 aralkyl, a heteroaryl, or a heterocycloalkyl group, these groups being substituted if appropriate, with the exception of formaldehyde autocondensation products. In the proposed process, an aldehyde of formula (II) RaCHO is allowed to react with an aldehyde of formula (III) RbCHO, in which Ra and Rb have the meanings indicated above and at least one of the groups Ra and Rb represents a group other than hydrogen, in the presence of catalysts produced using an auxiliary base from triazolium salts of formula (IV) in which R1 and R3 are identical or different and represent aliphatic groups with 1-30 carbon atoms, or, if appropriate, aryl groups, aralkyl groups and/or heteroaryl groups, these groups being substituted if appropriate; R2 represents hydrogen or the group RbCH(OH); and A is the equivalent of a singly or multiply negatively charged anion for the electrical neutralisation of the triazolium cation charge.

    17.
    发明专利
    未知

    公开(公告)号:ES2148740T3

    公开(公告)日:2000-10-16

    申请号:ES96908048

    申请日:1996-03-15

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/01123 Sec. 371 Date Sep. 16, 1997 Sec. 102(e) Date Sep. 16, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96/29300 PCT Pub. Date Sep. 26, 19963-Pentenoic esters are prepared by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at elevated temperature and elevated pressure, by reacting at least one C1-C10-alkoxybutene in which the alkoxy group is in the allyl position relative to the double bond with carbon monoxide at from 60 to 140 DEG C. and a carbon monoxide partial pressure in the range from 3 to 30 MPa in the presence of a catalyst based on palladium.

    19.
    发明专利
    未知

    公开(公告)号:AT193881T

    公开(公告)日:2000-06-15

    申请号:AT96908048

    申请日:1996-03-15

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/01123 Sec. 371 Date Sep. 16, 1997 Sec. 102(e) Date Sep. 16, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96/29300 PCT Pub. Date Sep. 26, 19963-Pentenoic esters are prepared by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at elevated temperature and elevated pressure, by reacting at least one C1-C10-alkoxybutene in which the alkoxy group is in the allyl position relative to the double bond with carbon monoxide at from 60 to 140 DEG C. and a carbon monoxide partial pressure in the range from 3 to 30 MPa in the presence of a catalyst based on palladium.

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