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公开(公告)号:DE2840124A1
公开(公告)日:1980-03-27
申请号:DE2840124
申请日:1978-09-15
Applicant: BASF AG
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公开(公告)号:DE2928510A1
公开(公告)日:1981-01-29
申请号:DE2928510
申请日:1979-07-14
Applicant: BASF AG
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公开(公告)号:DE2928509A1
公开(公告)日:1981-01-29
申请号:DE2928509
申请日:1979-07-14
Applicant: BASF AG
Inventor: VOLKAMER KLAUS DIPL CHEM DR , LINDNER ALFRED DIPL CHEM DR , MERGER FRANZ DIPL CHEM DR , WAGNER ULRICH DIPL PHYS DR , BRUNNER ERWIN DIPL PHYS DR , SANDROCK GERHARD DIPL CHEM DR , STROHMEYER MAX DIPL CHEM DR
IPC: C07C41/05 , C07C1/00 , C07C7/148 , C07C11/09 , C07C41/00 , C07C41/06 , C07C43/04 , C07C67/00 , C07C11/08
Abstract: A process for conjointly preparing methyl tert.-butyl ether and obtaining isobutene from an isobutene-containing C4-hydrocarbon mixture. In the process the C4-hydrocarbon mixture is reacted, in one or more etherification stages, with methanol and a primary C3- or C4-alcohol in the presence of an acid condensing agent, the resulting reaction mixture or mixtures are then separated into a fraction containing the unconverted hydrocarbons, the methyl tert.-butyl ether and a fraction containing the C3- or C4-alkyl tert.-butyl ether. Thereafter, the C3- or C4-alkyl tert.-butyl ether is decomposed at an elevated temperature, in the presence of an acid catalyst, into isobutene and primary C3- or C4-alcohol.
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公开(公告)号:DE2802198A1
公开(公告)日:1979-07-26
申请号:DE2802198
申请日:1978-01-19
Applicant: BASF AG
Inventor: BRUNNER ERWIN DIPL PHYS DR , SCHUBERT ECKART DIPL CHEM DR , LINDNER ALFRED DIPL CHEM DR , MERGER FRANZ DIPL CHEM DR , VOLKAMER KLAUS DIPL CHEM DR , STROHMEYER MAX DIPL CHEM DR , SANDROCK GERHARD DIPL CHEM DR
IPC: B01J31/00 , C07B61/00 , C07C1/00 , C07C7/148 , C07C11/09 , C07C41/36 , C07C41/42 , C07C67/00 , C07C11/08 , C07C7/01
Abstract: A process for obtaining isobutene from a C4-hydrocarbon mixture containing isobutene, by reacting the mixture with a primary alcohol in the presence of an acid condensing agent and decomposing the resulting tertiary ether in the presence of an acid catalyst at an elevated temperature, wherein a primary C3- or C4-alcohol is used.
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公开(公告)号:DE2705538A1
公开(公告)日:1978-08-17
申请号:DE2705538
申请日:1977-02-10
Applicant: BASF AG
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