New 4-azo- and 4-hydrazino-pyrimidine compounds

    公开(公告)号:DE19650378A1

    公开(公告)日:1998-06-10

    申请号:DE19650378

    申请日:1996-12-05

    Applicant: BASF AG

    Abstract: Pyrimidyl compounds of formula (I) are new. R = N(R4)NR5R6, N=NR6 or N(R6)NHR4; R1 = H, halo, alkyl or 3-8C cycloalkyl; R2, R3 = halo, CN, 1-8C alkyl, haloalkyl, 1-8C alkoxy, alkylthio, alkylthioalkyl, haloalkoxy, alkoxyalkyl, alkoxycarbonyl, alkoxycarbonylalkyl, 3-8C cycloalkyl or 3-8C halocycloalkyl; or CR2R3 = Z; Z = 4-8 membered ring which may contain one or two O, S, NH or N-alkyl (optionally with C atoms mono- or di-substituted by halo, CN, alkyl, alkoxyalkyl, haloalkyl, alkoxy, 1-4C haloalkoxy, alkylthio, alkoxycarbonyl, aryl or aryloxy); R4 = H, alkyl, formyl, alkylcarbonyl or alkoxycarbonyl; R5 = H, formyl, 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl, 1-8C alkylcarbonyl, 3-7C cycloalkyl or 5-7C cycloalkenyl (all partially or fully halogenated), aryl or heteroaryl (both optionally substituted by 1-3 NO2, halo, CN, alkyl, haloalkyl, alkoxy, haloalkoxy, 1-4C alkoxyalkyl, alkylthio, alkylamino, dialkylamino, alkylsulphonyl, alkylsulphonyloxy, alkylsulphoxy, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl, aryl or aryloxy; R6 = 1-8C alkyl, 2-8C alkenyl or 2-8C alkynyl (all partially or fully halogenated and/or substituted by 1-3 CN, alkoxy, haloalkoxy, alkylthio or Cyc), or 3-7C cycloalkyl or cycloalkenyl, (both partially or fully halogenated and optionally substituted by 1-3 CN, alkoxy, haloalkoxy, alkylthio, Cyc), Z, or aryl or heteroaryl, (both optionally substituted by 1-3 halo, CN, alkyl (optionally substituted by Ar'), 1-4C alkoxyalkyl, haloalkyl, alkoxy (optionally substituted by Ar'), haloalkoxy, alkylthio, Ar', OAr', 3-7C cycloalkyl optionally substituted by 1-3 Rc), alkylamino, dialkylamino, alkylsulphonyl, alkylsulphonyloxy, haloalkylsulphonyl, alkylsulphoxy, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl or cyanoalkyl); Ar' = aryl or heteroaryl (both optionally substituted by 1-3 Rc); Cyc = 3-7C cycloalkyl, 5-7C cycloalkenyl, aryl, aryloxy or heteroaryl (all optionally substituted by 1-3 Rc); Rc = halo, CN, alkyl, 1-4C alkoxyalkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, aryl, aryloxy or heteroaryl; alkyl, alkoxy have 1-4C unless specified otherwise. The use of a compound (Ic) is also claimed.

    DERIVATIVE OF CARBAMOYLCARBOXYLIC ACID AMIDE, PROCESS OF ITS PREPARATION AND THE USE THEREOF

    公开(公告)号:CZ64097A3

    公开(公告)日:1998-02-18

    申请号:CZ64097

    申请日:1995-08-19

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03303 Sec. 371 Date Mar. 3, 1997 Sec. 102(e) Date Mar. 3, 1997 PCT Filed Aug. 19, 1995 PCT Pub. No. WO96/07638 PCT Pub. Date Mar. 14, 1996Carbamoylcarboxamides of the general formula I (I) and their salts (R1 is unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl or an unsubstituted or substituted nonaromatic carbo- or heterocycle; R2 is H or unhalogenated or halogenated alkyl or cycloalkyl; R3 is unsubstituted or substituted alkyl, cycloalkyl or phenylalkyl; R4 is H or one of the radicals R3 or R3 and R4, together with the C atom to which they are bonded, are an unsubstituted or substituted carbo- or heterocycle; R5 independently of these is one of the radicals R2; X independently of one another is hydrogen, unsubstituted or substituted alkyl and/or alkenyl; Y independently of one another and of these is one of the radicals X; p,q independently of one another are 0, 1 or 2; R6 is halogen, cyano, nitro or unsubstituted or substituted alkyl, alkoxy, alkylthio or an unsubstituted or substituted phenyl group bonded via oxygen or sulfur; r is 0, 1, 2 or 3), and compositions containing them, processes for preparation, and the use of the compounds I and the compositions are described.

    15.
    发明专利
    未知

    公开(公告)号:DE19543746A1

    公开(公告)日:1997-05-28

    申请号:DE19543746

    申请日:1995-11-24

    Applicant: BASF AG

    Abstract: Disclosed is a fungicidal mixture containing the following components: a) a p-hydroxyaniline derivative of formula (I) in which R is H or optionally substituted alkyl, cycloalkyl, cycloalkenyl, bicycloalkyl, bicycloalkenyl; R and R independently of one another represent halogen, alkyl, alkyl halide, alkoxy, alkoxy halide; Z is H, R -(CO)- where R is optionally substituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, OR , or NR R , R and R independently of one another being optionally substituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, R being H, alkyl; and b) an active substance of formula (IIA) or (IIB), in which .... stands for a double or single bond and the index and substituents have the meanings indicated in the description, in a synergistically effective quantity. Also disclosed is the use of said mixture for controlling harmful fungi.

    New 4-aryl-hydrazino- and 4-aryl-azo-quinoline derivs.

    公开(公告)号:DE19533653A1

    公开(公告)日:1997-03-13

    申请号:DE19533653

    申请日:1995-09-12

    Applicant: BASF AG

    Abstract: 4-Arylhydrazino-quinolines of formula (I) and 4-arylazo-quinolines of formula (II) and the N-oxides and acid-addn. salts of (I) are new. R1-R4 = H, OH, NO2, halo, 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C alkylthio, 1-4C haloalkoxy, 1-4C haloalkylthio or 2-5C alkoxyalkyl; R5, R6 = H, halo, 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkoxy or 1-4C alkylthio; R7 = H, 1-4C alkyl, CHO, 2-5C alkanoyl or 2-5C alkoxycarbonyl; R8 = H, CHO, opt. halogenated 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl, 2-9C alkanoyl or 3-7C cycloalkyl; aryl or heteroaryl opt. substd. by 1-3 of NO2, halo, CN, 1-4C (halo)alkyl, 1-4C (halo)alkoxy, 1-4C alkylthio, mono and di(1-4C alkyl)amino, 1-4C alkylsulphonyl, 1-4C alkylsulphoxy (sic), 1-4C alkylsulphonyloxy, 2-5C alkanoyl, 2-5C alkanoyloxy, 2-5C alkoxycarbonyl, aryl or aryloxy,;or R7+R8 = a bond; R9 = aryl or heteroaryl opt. substd. by 1-3 of NO2, halo, CN, 1-4C (halo)alkyl, 1-4C (halo)alkoxy, 1-4C alkylthio, mono- and di(1-4C alkyl)amino, 1-4C alkylsulphonyl, 1-4C alkylsulphoxy (sic), 1-4C alkylsulphonyloxy, 2-5C alkanoyl, 2-5C alkanoyloxy, 2-5C alkoxycarbonyl, aryl and aryloxy, where aryl and aryloxy are opt. substd. by 1-3 of NO2, of halo, CN, 1-4C (halo)alkyl, 1-4C(halo)alkoxy, 1-4C alkylthio, mono- and di)1-4C alkyl)amino, 1-4C alkylsulphonyl, 1-4C alkylsulphoxy (sic), 1-4C alkylsulphonyloxy, 2-5C alkanoyl, 2-5C alkanoyloxy, 2-5C alkoxycarbonyl, aryl or aryloxy. Cpds. (I) with the following substits. are excluded (substits. not mentioned are H): R9 = phenyl, 4-chlorophenyl (an its N-oxide and HCl salt), 2,4-dichlorophenyl (and N-oxide and HCl salt), 2,4-dibromophenyl; R9 = 4-bromophenyl (HBr salt); R5 = Me, R7 = H or Me and R9 = phenyl; R2 ,R5 = Me, and R9 = phenyl; R1 = OMe, R5 = Me, R9 = phenyl (HCl salt); R2 = Me, R9 = 4-nitrophenyl(and N-oxide and HCl salt); R3 = Cl, R9 = 4-nitrophenyl or 4-chlorophenyl; R5 = Cl, R9 = 4-chlorophenyl or 2,4-dichlorophenyl, R3= 4-quinolyl (and di-N-oxide); R5 = Me, R9 = 4-quinolyl (di-N-oxide); Q, R9 = phenyl, 4-chlorophenyl, 4-bromophenyl, 2,4-dichlorophenyl, 2,4-dibromophenyl or 4-dimethylaminophenyl (and N-oxides); R2, R4 = OMe or OEt, R5 = Me, R7 = undefined, and R9 = phenyl; R5 = Ce (sic), Q, and R9 = phenyl, 4-chlorophenyl or 2,4-dichlorophenyl; R3 = Cl, Q, and R9 = phenyl; R5 = Me, R7 and R8 undefined, and R9 = phenyl; R5,R6 = Me, Q, R9 = phenyl, R1, R5 = Me, Q, R9 = phenyl; R2,R5 = Me, Q, R9 = phenyl; R5 = Me, Q, R9 = phenyl; R1,R3, R5 = Me, Q, R9 = phenyl; R2, R4, R5 = Me, Q, R9 = phenyl; Q = R7 and R8 are not defined.

    New fungicidal cpds. used for plant protection

    公开(公告)号:DE4407021A1

    公开(公告)日:1995-09-07

    申请号:DE4407021

    申请日:1994-03-03

    Applicant: BASF AG

    Abstract: Carbamoyl carboxylic acid amide derivs. of formula (I) and their salts are new. R1 = R or N=CW1W2: R1 = 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl, 3-7C cycloalkyl or 3-7C cycloalkenyl, A', aryl or heteroaryl (all opt. substd.); A' = a non-aromatic 4-8 membered ring (opt. contg. 1 or 2 additional heteroatoms); W1 = R; W2 = H or R; R2, R5 = H, 1-8C alkyl or 3-7C cycloalkyl (these last 2 gps. each opt. partially or completely halogenated); R3 = 1-8C alkyl, 3-7C cycloalkyl (opt. substd.); R4 = H or R3; or CR3R4 = A'; X = independently 1-8C alkyl, 2-8C alkenyl, 3-7C cycloalkyl or 3-7C cycloalkenyl (all opt. substd.); m = 0-2; A = CY1Y2; Y1 = 3-7C cycloalkyl or 3-7C cycloalkenyl (both opt. substd.); Y2 = 1-8C alkyl, 2-8C alkenyl or aryl (all opt. substd.), Y1 or H; R6 = aryl or heteroaryl (both opt. substd.).

    19.
    发明专利
    未知

    公开(公告)号:DK0910948T3

    公开(公告)日:2001-11-19

    申请号:DK98123302

    申请日:1995-12-05

    Applicant: BASF AG

    Abstract: Fungicidal mixt. comprises a synergistic amt. of a cpd. of formula (I) (or an N-oxide or salt), (II), (III) (or a salt), (IV) or (V) (sic). Ar = phenyl (opt. substd. by 1-3 OH, CN, NO2, halo, 1-7C alkyl (opt. substd. by OH or halo), 1-7C alkoxy, 1-7C haloalkoxy, 1-7C alkylthio, 1-7C haloalkylthio, 2-4C acyl, Ar' or OAr'; Ar' = aryl (opt. substd. by 1-3gps. CN, NO2, halo, OR or SR); R1-R4 = H, halo, OH, NO2, OR or SR; R8 = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy), or pyrimidyl (opt. substd. by a 1-3C alkyl and/or OPh); Ph = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy); A = O or CH2; X = CH or N; Y = O or NR5; R5 = H, 1-3C alkyl or 1-3C alkoxy; R9 = Me, propyn-1-yl or cyclopropyl; R' = F or Cl; R" = CF3 or Cl; or R'+R" = OCF2O; R = 1-4C alkyl (opt. substd. by halo). Also claimed is a process for combating harmful fungi by treatment with one cpd. (I) and one of the cpds. (II)-(V), applied together or separately.

    20.
    发明专利
    未知

    公开(公告)号:AT207294T

    公开(公告)日:2001-11-15

    申请号:AT98123304

    申请日:1995-12-05

    Applicant: BASF AG

    Abstract: Fungicidal mixt. comprises a synergistic amt. of a cpd. of formula (I) (or an N-oxide or salt), (II), (III) (or a salt), (IV) or (V) (sic). Ar = phenyl (opt. substd. by 1-3 OH, CN, NO2, halo, 1-7C alkyl (opt. substd. by OH or halo), 1-7C alkoxy, 1-7C haloalkoxy, 1-7C alkylthio, 1-7C haloalkylthio, 2-4C acyl, Ar' or OAr'; Ar' = aryl (opt. substd. by 1-3gps. CN, NO2, halo, OR or SR); R1-R4 = H, halo, OH, NO2, OR or SR; R8 = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy), or pyrimidyl (opt. substd. by a 1-3C alkyl and/or OPh); Ph = phenyl (opt. substd. by 1-3 CN, halo, 1-4C alkyl, 1-2C haloalkyl or 1-4C alkoxy); A = O or CH2; X = CH or N; Y = O or NR5; R5 = H, 1-3C alkyl or 1-3C alkoxy; R9 = Me, propyn-1-yl or cyclopropyl; R' = F or Cl; R" = CF3 or Cl; or R'+R" = OCF2O; R = 1-4C alkyl (opt. substd. by halo). Also claimed is a process for combating harmful fungi by treatment with one cpd. (I) and one of the cpds. (II)-(V), applied together or separately.

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