TRICYCLIC CYCLOHEXANEDIONE DERIVATIVES
    12.
    发明申请
    TRICYCLIC CYCLOHEXANEDIONE DERIVATIVES 审中-公开
    三环环己二酮衍生物

    公开(公告)号:WO0059911A2

    公开(公告)日:2000-10-12

    申请号:PCT/EP0002565

    申请日:2000-03-23

    CPC classification number: C07D495/04 A01N43/90

    Abstract: The invention relates to tricyclic cyclohexanedione derivatives of formula (I) in which the substituents have the following meaning: R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6 alkyl, C1-C6 alkoxy, C1-C6 haloalkyl, C1-C6 haloalkoxy, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano, nitro or C1-C3 alkylsulfonyl or phenylsulfonyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R , R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, NR R , C2-C6 alkoxyalkyl, C1-C6 alkoxycarbonyl, C1-C6 alkylcarbonyl, halogen, cyano, nitro, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4 alkyl; R is hydrogen, C1-C6 alkyl or halogen; R is hydrogen or C1-C6 alkyl; R is C1-C6 alkyl or C1-C6 alkoxy; 1 is 0, 1 or 2; n is 1 or 2; R is substituted (3-oxo-1-cyclohexene-2-yl)carbonyl or substituted (1,3-dioxo-2-cyclohexyl)methylidene. The invention also relates to the agriculturally useful salts of the compounds (I), to methods for producing said tricyclic cyclohexanedione derivatives and to the intermediates for their production. The invention encompasses agents containing the inventive compounds and the use of said derivatives or of agents containing them for weed control.

    Abstract translation: (I),式三环环己二酮衍生物,其中取代基具有以下含义:R t <1>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6 烷硫基,C1-C6卤代烷硫基,C1-C6烷基亚磺酰基,C1-C6卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,卤素,氰基或硝基; X是O或NR <2>; [R <2>的氢,C1-C6烷基,C1-C6-烷氧基,C1-C6卤代烷基,C1-C6-卤代烷氧基,任选地被C1-C3烷基,卤素,氰基,硝基或C1-C3烷基磺酰基取代的取代的 苯基或任选地被C1-C3烷基,卤素,氰基或硝基取代的苯磺酰基; [R <3>,R <4>为氢,C1-C6烷基,C1-C6卤代烷基,C1-C6-烷氧基,C1-C6卤代烷氧基,C1-C6烷硫基,C1-C6卤代烷硫基,C1-C6 烷基亚磺酰基,C1-C6-卤代烷基亚磺酰,C 1 -C 6 - 烷基磺酰基,C1-C6卤代烷基磺酰基,NR <7> - [R <8>,C2-C6烷氧基烷基,C1-C6烷氧羰基,C1-C6烷基羰基,卤素, 氰基,硝基,任选地被C1-C3烷基,卤素,氰基或硝基取代; [R <5>是氢或C1-C4烷基; [R <6>为氢,C1-C6烷基或卤素; [R <7>是氢或C1-C6烷基; [R <8> C1-C6烷基或C1-C6烷氧基; 1 0,1或2; n是1或2; [R <9>取代的(3-氧代-1-环己烯-2-基)羰基,或取代的(1,3-二氧代-2-环己基)亚甲基; 和化合物(I)的可农用盐,用于制备三环环己二酮衍生物以及中间体其制备方法,含有它们的组合物,以及使用这些衍生物或组合物的包含它们的用于控制杂草的方法。

    SYNERGISTICALLY ACTING HERBICIDAL MIXTURES
    14.
    发明申请
    SYNERGISTICALLY ACTING HERBICIDAL MIXTURES 审中-公开
    协同作用除草混合物

    公开(公告)号:WO2004008849A3

    公开(公告)日:2004-05-13

    申请号:PCT/EP0307992

    申请日:2003-07-22

    Abstract: A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula (I) in which the variables have the following meanings: R , R are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R is a optionally substituted heterocyclic radical se-lected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydro-isoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R is hydrogen, halogen or alkyl; R is alkyl; R is hydrogen or alkyl; or one of its environmentally compatible salts; and B) the compound of formula (II) or one of its environmentally compatible salts; and C) at least one further herbicidal compound from the group of the acetolactate synthase inhibitors (ALS), lipid biosynthesis inhibitors and photosynthesis inhibitors; in a synergistically effective amount. Compositions comprising these mixtures, processes for the prepa-ration of these compositions, and their use for controlling undesired plants.

    Abstract translation: 一种协同除草混合物,其包含A)至少一种式(I)的3-杂环基取代的苯甲酰基衍生物,其中所述变量具有以下含义:R 1,R 3为卤素,烷基,卤代烷基,烷氧基, 卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是选自以下的任选取代的杂环基:异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基,4,5-二氢 - 异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 和B)式(II)化合物或其与环境相容的盐之一; 和C)来自乙酰乳酸合酶抑制剂(ALS),脂质生物合成抑制剂和光合作用抑制剂的至少一种另外的除草化合物; 协同有效量。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于防治不期望的植物的用途。

    TRICYCLIC BENZOYLCYCLOHEXANEDIONE DERIVATIVES
    16.
    发明申请
    TRICYCLIC BENZOYLCYCLOHEXANEDIONE DERIVATIVES 审中-公开
    三环benzoylcyclohexanedione衍生物

    公开(公告)号:WO0073311A3

    公开(公告)日:2001-04-19

    申请号:PCT/EP0004806

    申请日:2000-05-26

    CPC classification number: C07D495/04

    Abstract: The invention relates to tricyclic benzoylcyclohexanedione derivatives of formula (I), wherein the variables have the following meanings: X is oxygen, sulphur, S=O, S(=O)2, CR R , NR or a bond; y forms a saturated, partially saturated or unsaturated 5- or 6-membered heterocycle with the two carbons to which it is bonded; R , R , R , R is hydrogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is halogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R is hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, C1-C6- alkylthio halide, alkylsulfinyl, alkylsulfinyl halide, alkylsulfonyl, alkylsulfonyl halide, optionally substituted aminosulfonyl, or optionally substituted sulfonylamino; R is hydrogen, alkyl or halogen; m is 0, 1 or 2; R is hydrogen, alkyl, alkyl halide, alkylcarbonyl, formyl, alkoxycarbonyl, alkoxycarbonyl halide, alkylsulfonyl or alkylsulfonyl halide; and R is substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl)-methylidene; and to agriculturally useable salts thereof. The invention also relates to a method for producing the tricyclic benzoylcyclohexanedione derivatives, to products containing them and to the use of said derivatives or said products containing them for combating unwanted vegetation.

    Abstract translation: 式(I),其中各变量具有以下含义的三环benzoylcyclohexanedione衍生物:X是氧,硫,S = O,S(= O)2,CR <6> - [R <7>,NR <8>或键 ; Y共同与两个碳其所结合的,饱和,部分饱和或不饱和5或6元杂环; [R <1>,R <2>,R <6> - [R <7>是氢,烷基,卤代烷基,烷氧基或卤代烷氧基; [R <3>为卤素,烷基,卤代烷基,烷氧基或卤代烷氧基; [R <4>为氢,硝基,卤素,氰基,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,C1-C6卤代烷硫基,烷基亚磺酰基,卤代烷,烷基磺酰基,卤代烷基磺酰基,任选子氨基磺酰基,磺酰氨基或可能子..; [R <5>是氢,烷基或卤素; m是0,1或2; [R <8>是氢,烷基,卤代烷基,烷基羰基,甲酰基,烷氧基羰基,卤代烷氧基羰,烷基磺酰基或卤代烷基磺酰基; [R <9>取代的(3-氧代-1-环己烯-2-基) - 羰基,或取代的(1,3-二氧代-2-环己基)亚甲基; 及其可农用盐; 一种用于三环benzoylcyclohexanedione衍生物的制备方法; 含有它们并使用这些衍生物或包含它们用于控制不希望的植物的组合物的组合物。

    BENZYLIDENE PYRAZOLONES, PRODUCTION AND USE THEREOF
    18.
    发明申请
    BENZYLIDENE PYRAZOLONES, PRODUCTION AND USE THEREOF 审中-公开
    BENZYLIDENPYRAZOLONE,生产和使用

    公开(公告)号:WO9926930A2

    公开(公告)日:1999-06-03

    申请号:PCT/EP9807099

    申请日:1998-11-06

    Abstract: The invention relates to benzylidene pyrazolones of formula (I), wherein the substituents and index n have the following meanings: R = optionally substituted C1-C6 alkyl; R = optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, halogen, nitro, cyano; R = hydrogen, halogen, nitro, cyano, a group NR R , OCOR , NR COR ,CO2R , -COSR , -CONR R , C1-C4-alkoxyiminoalkyl, C1-C6 alkoxycarbonyl, optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, optionally substituted C1-C6 alkylthio, optionally substituted C2-C6 alkenyl, optionally substituted phenyl, optionally substituted phenoxy, an optionally substituted 5- or 6-membered saturated or unsaturated heterocycle which can contain up to 4 nitrogen atoms and/or up to 2 oxygen or sulphur atoms as ring members; R = C1-C6 alkyl, C1-C4 halogen alkyl; or R and R = an optionally substituted saturated or unsaturated 2- or 3-membered bridge which can contain one sulphur atom which can be oxidized into sulfoxide or sulfone, R = hydrogen or optionally substituted C1-C6 alkyl; R = hydrogen, C1-C6 alkyl or C1-C4 halogenalkyl; n = 0, 1 or 2; X = hydrogen, chlorine or bromine. The compounds to which claim is laid are available in both a trans and a cis form or can be a mixture of these isomers.

    Abstract translation: 式(I)的Benzylidenpyrazolone其中取代基和指数n具有以下含义:R t <1>是未取代的或取代的。 C1-C6烷基; [R <2>是未取代的或取代的。 C1-C6烷基,未取代或取代的。 C1-C6烷氧基,卤素,硝基,氰基; [R <3>是氢,卤素,硝基,氰基,基团NR <5> - [R <6>,OCOR <5>,NR <5> COR <6>,CO 2 <5>,-COSR <5>,-CONR <5> - [R <6>,C1-C4-alkoxyiminoalkyl,C1-C6烷基羰基,未取代的或取代的。 C1-C6烷基,未取代或取代的。 C1-C6烷氧基,未取代的或取代的。 C1-C6烷硫基,未取代或取代的。 C2-C6链烯基,未取代的或取代的。 C2-C6炔基,未取代的或取代的。 苯基,未取代的或取代的。 苯氧基,未取代的或取代的。 5-或6-元饱和或可含有至多4个氮原子和/或至多2个氧或硫原子作为环成员的不饱和的杂环; [R <4> C1-C6-烷基,C1-C4卤代烷基; 或R <3>,R <4>为可以含有可被氧化为亚砜或砜硫原子的任选取代的饱和或不饱和2-或3-元桥; [R <5>为氢或未取代或取代的。 C1-C6烷基; [R <6>是未取代的或取代的。 C1-C6烷基; [R <7>是氢,C1-C6烷基或C1-C4卤代烷基; n为0.1或2; X是氢,氯或溴; 其中要求保护的化合物在跨及在所述顺式 - 形式两者呈现,或者可以是这些异构体的混合物。

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