ISOXAZOLYL-BENZOYLDERIVATE
    15.
    发明公开
    ISOXAZOLYL-BENZOYLDERIVATE 失效
    异恶唑,BENZOYLDERIVATE

    公开(公告)号:EP0810999A1

    公开(公告)日:1997-12-10

    申请号:EP96904760.0

    申请日:1996-02-13

    CPC classification number: C07D413/10 A01N43/80 C07D261/08 C07D417/10

    Abstract: The invention concerns isoxazol-4-yl-benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)mR7 or -(Y)¿n-CO-R?8 group; Z represents a five to six-membered heterocyclic saturated or unsaturated group which contains one to three heteroatoms selected from the group comprising oxygen, sulphur or nitrogen and can optionally be substituted by halogen, cyano, nitro, an -CO-R8 group, C¿1?-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can be present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide, or a C1-C4 alkyl halide, form a bicyclic system; Y represents O or NR?9¿; n is 0 or 1; m is 0, 1 or 2; R7 represents C¿1?-C4 alkyl, C1-C4 alkyl halide or NR?9R10; R8¿ represents C¿1?-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR?9R10; R9¿ represents hydrogen or C¿1?-C4 alkyl; R?10¿ represents C¿1?-C4 alkyl; Q represents an isoxazole ring connected at position 4 and of formula (II) in which R?1¿ represents hydrogen or -CO¿2R?3, R2 represents hydrogen, C¿1?-C4 alkyl or C3-C6 cycloalkyl which can optionally be substituted by one or more halogen atoms or C1-C4 alkyl, R?3¿ representing a C¿1?-C4 alkyl; J represents a carbonyl group CO or a -CHR?4¿ group, R4 representing an OH group, a hydroxyl group optionally acylated with C¿2?-C4 acyl, or a chlorine atom. The invention also concerns salts of compounds of formula (I) usually utilized in agriculture.

    HERBIZIDE BENZOYLDERIVATE
    20.
    发明授权
    HERBIZIDE BENZOYLDERIVATE 失效
    除草剂苯甲酰

    公开(公告)号:EP0811005B1

    公开(公告)日:1999-09-29

    申请号:EP96904761.2

    申请日:1996-02-13

    Abstract: The invention concerns benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)mR7 or -(Y)¿n-CO-R?8 group; Z represents a five to six-membered heterocyclic saturated or unsaturated group containing one to three heteroatoms selected from the group comprising oxygen, sulphur and nitrogen and which can optionally be substituted by halogen, cyano, nitro, a -CO-R8 group, C¿1?-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can be present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen or, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide or a C1-C4 alkyl halide, forms a bicyclic system; Y represents O or NR?9¿; n is 0 or 1; m is 0, 1 or 2; R7 represents C¿1?-C4 alkyl, C1-C4 alkyl halide or NR?9R10; R8¿ represents C¿1?-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR?9R10; R9¿ represents hydrogen or C¿1?-C4 alkyl; R?10¿ represents C¿1?-C4 alkyl; Q represents a cyclohexane-1,2-dione ring connected at position 2 and of formula (II) in which R?1, R2, R4 and R6¿ represent hydrogen or C¿1?-C4 alkyl, R?5¿ represents hydrogen, C¿1?-C4 alkyl or a -COOR?10¿ group, R3 represents hydrogen, C¿1?-C4 alkyl, C3-C6 cycloalkyl, these groups optionally including one to three of the following substituents: halogen, C1-C4 alkyl thio, C1-C4 alkoxy, or R?3¿ represents tetrahydropropanyl-3, tetrahydropropanyl-4 or tetrahydrothiopyranyl-3, or R?3 and R5¿ together form a bond or a three to six-membered carbocyclic ring. The invention also concerns standard agricultural salts of compounds of formula (I) usually utilized in agriculture.

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