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公开(公告)号:US20200181537A1
公开(公告)日:2020-06-11
申请号:US16316266
申请日:2017-07-05
Applicant: BASF SE
Inventor: Marta REINOSO GARCIA , Michael Klemens MUELLER , Carsten SUELING , Verena MORMUL
Abstract: Process for manufacturing granules of salts of at least two aminopolycarboxylic acids (A), com-prising the steps of (a) providing an aqueous solution of (A1) at least one alkali metal salt of a mixture of L- and D-enantiomers of methyl glycine diacetic acid (MGDA), said mixture containing predominantly the respective L-isomer with an enantiomeric excess (ee) in the range of from 10 to 95%, (A2) at least one alkali metal salt of L- and D-enantiomers of glutamic acid diacetic acid (GLDA) or of enantiomerically pure L-GLDA, the weight ratio of (A1) and (A2) being in the range of from 1:9 to 9:1, (b) spray granulating said solution with a gas inlet temperature of at least 125° C. Additionally, the present invention relates to granules and to their use.
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公开(公告)号:US20190127668A1
公开(公告)日:2019-05-02
申请号:US16086931
申请日:2017-03-29
Applicant: BASF SE
Inventor: Thomas SCHMIDT , Marta REINOSO GARCIA , Carsten SUELING , Verena MORMUL
Abstract: The present invention is directed towards mixtures comprising (A) 90 to 99.999% by weight of racemic methyl glycine diacetic acid (MGDA) or of MGDA with predominantly the L-isomer in an enantiomeric excess of up to 9.5% or their respective mono-, di- or trialkali metal or mono-, di- or triammonium salts, and (B) in total 0.001 to 10% by weight of the diacetic acid derivative of aspartate as free acid or as mono-, di-, tri- or tetraalkali metal salt or as mono-, di-, tri- or tetraammonium salt, percent ages referring to the sum from (A) and (B).
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公开(公告)号:US20180287154A1
公开(公告)日:2018-10-04
申请号:US15524400
申请日:2015-11-02
Applicant: BASF SE
Inventor: Ivana KRKLJUS , Aleksei VOLKOV , Carsten SUELING
IPC: H01M4/58 , H01M10/0525 , H01M4/36 , H01M10/0569 , H01M2/16 , H01M4/62
CPC classification number: H01M4/5825 , H01M2/164 , H01M4/364 , H01M4/623 , H01M4/625 , H01M10/0525 , H01M10/0569 , H01M2004/021 , Y02T10/7011
Abstract: Electrode material comprising (a) at least one compound of general formula (I) LiFe(1-y)M1yPO4 (I) y is in the range of from zero to 0.4 M1 is at least one element selected from Co, Mn, Ni, V, Mg, Nd, Zn and Y, that contains at least one further iron-phosphorous compound, and in the range of from 0.05 to 0.25% by weight of sulphur and in the range of from 0.003 to 0.5% by weight of Ti, (b) carbon in electrically conductive modification.
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公开(公告)号:US20180065919A1
公开(公告)日:2018-03-08
申请号:US15554492
申请日:2016-03-01
Applicant: BASF SE
Inventor: Constanze FRANZKE , Frank JAEKEL , Carsten SUELING
IPC: C07C227/18 , C07C229/16 , C11D3/33 , C11D3/00
CPC classification number: C07C227/18 , C07B2200/07 , C07C229/16 , C11D3/0047 , C11D3/33
Abstract: The present invention is directed towards mixtures comprising (A) 90 to 99.9% by weight of a mixture of L- and D-enantiomers of methyl glycine diacetic acid (MGDA) or its respective mono-, di- or trialkali metal or mono-, di- or triammonium salts, said mixture containing predominantly the respective L-enantiomer with an enantiomeric excess (ee) in the range of from 10 to 99%, and (B) in total 0.1 to 10% by weight of the diacetic acid derivative of at least one amino acid selected from valine, leucine, isoleucine, and tyrosine, as free acids or respective mono-, di- or trialkali metal or mono-, di- or triammonium salts, percentages referring to the sum from (A) and (B).
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公开(公告)号:US20160233488A1
公开(公告)日:2016-08-11
申请号:US15023046
申请日:2014-09-16
Applicant: BASF SE
Inventor: Ivana KRKLJUS , Aleksei VOLKOV , Carsten SUELING
CPC classification number: H01M4/364 , C01D15/02 , C01G49/009 , C01G53/50 , C01P2002/50 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , H01M4/131 , H01M4/136 , H01M4/505 , H01M4/525 , H01M4/5805 , H01M4/5825 , H01M4/625 , H01M10/0525 , H01M2004/028 , H01M2220/20
Abstract: Electrode materials comprising (a) at least one compound of general formula (I) Li(1+x)[NiaCObMncM1d](1-x)O2 (I) the integers being defined as follows: x is in the range of from 0.01 to 0.05, a is in the range of from 0.3 to 0.6, b is in the range of from zero to 0.35, c is in the range of from 0.2 to 0.6, d is in the range of from zero to 0.05, a+b+c+d=1 M1 is at least one metal selected from Ca, Zn, Fe, Ti, Ba, Al, (b) at least one compound of general formula (II) LiFe(1-x)M2yPO4 (II) y is in the range of from zero to 0.8 M2 is at least one element selected from Ti, Co, Mn, Ni, V, Mg, Nd, Zn and Y, that contains at least one further iron-phosphorous compound, in form of a solid solution in compound (b) or in domains, (c) carbon in electrically conductive modification.
Abstract translation: 包括(a)至少一种通式(I)的化合物Li(1 + x)[NiaCObMncM1d](1-x)O 2(I))的电极材料,整数定义如下:x在0.01至 0.05时,a在0.3〜0.6的范围内,b在0〜0.35的范围内,c在0.2〜0.6的范围内,d在0〜0.05的范围内,a + b + c + d = 1 M1是选自Ca,Zn,Fe,Ti,Ba,Al中的至少一种金属,(b)至少一种通式(II)的化合物LiFe(1-x)M2yPO4(II)y是 在0至0.8的范围内,M2是选自Ti,Co,Mn,Ni,V,Mg,Nd,Zn和Y中的至少一种元素,其含有至少一种另外的铁 - 磷化合物,其形式为固体 化合物(b)或结构域中的溶液,(c)导电改性中的碳。
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