Abstract:
The present invention relates to a comb copolymer comprising in polymerized form a PIB macromonomer of the formula (I) and an acry late monomer of the formula (II). The invention further relates to a method of preparing the PIB macromonomer of the formula (I) where a polyisobutene phenol of the formula (III) is reacted with (meth)acrylic acid anhydride; and to a lubricant comprising a base oil, the comb copolymer, and further lubricant additives; and to a use of the comb copolymer for improving the viscosity index of a lubricating oil.
Abstract:
The present invention relates to a comb copolymer comprising in polymerized form up to 40 wt % of a PIB macromonomer of the formula (I) and a hydrophobic monomer of the formula (II). The invention further relates to a method of preparing the PIB macromonomer of the formula (I) where a polyisobutene amine of the formula (IV) is reacted with (meth)acrylic acid anhydride; and to a lubricant comprising a base oil, the comb copolymer, and further lubricant additives; and to a use of the comb copolymer for improving the viscosity index of a lubricating oil.
Abstract:
The invention relates to a process for preparing a compound of the formula (I), in which R is H or C1-C6 alkyl, by reaction of at least one compound of the formula (II) in which R has the same definition as in the formula (I) and in which R1 is H, C1-C12 alkyl or C3-C12 cycloalkyl, with a compound of the formula (III) in which R2 is H or C(O)R3, in which R3 is H or C1-C12 alkyl, in the presence of at least one enzyme suitable for transesterification.
Abstract:
The present invention relates to a phosphorus containing alcohol, obtainable or obtained by a process comprising the reaction of at least one alcohol with a phosphorus containing compound of the general formula (I) as defined herein, as well as the process for preparing a phosphorus containing alcohol, comprising the reaction of at least one alcohol with a phosphorus containing compound of the general formula (I). Furthermore, the present invention relates to the use of a phosphorus containing alcohol as disclosed herein as a flame retardant, to a process for the preparation of a polyurethane and the polyurethane as such.
Abstract:
An aqueous polymer latex obtainable by polymerizing, optionally in the presence of a seed latex, a monomer composition M by radical emulsion polymerization, wherein the monomer composition M comprises, based on the total weight of the monomer composition M: a) 0.5 to 30% by weight of 2-octyl acrylate, b) 25 to 55% by weight of n-butyl acrylate, c) 35 to 65% by weight of methyl methacrylate, d) 0 to 5% by weight of one or more monoethylenically unsaturated carboxylic acids, e) 0 to 5% by weight of one or more monoethylenically unsaturated carboxylic acid amides, f) 0 to 10% by weight of one or more further ethylenically unsaturated non-ionic monomers different from monomers a), b), c), d) and e).
Abstract:
Described is a pressure-sensitive adhesive composition in the form of an aqueous polymer dispersion comprising a dispersed pressure-sensitive adhesive polymer formed by emulsion polymerization of isobutyl acrylate, 2-ethylhexyl acrylate and/or 1-octyl acrylate and styrene, monomers having at least one acid group and optionally further monomers. The pressure-sensitive adhesive composition may be used to produce self-adhesive articles such as self-adhesive labels, self-adhesive tapes or self-adhesive films.
Abstract:
The invention relates to compositions, comprising a) 1.00 to 65.00% by weight of at least one compound of formula (I), wherein R1, R2 are each independently H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; R3, R4, R5 are each independently H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; R6 is H or C1-C6-alkyl; k is 1, 2, 3, 4 or 5, as component A; b) 1.00 to 60.00% by weight of at least one monomer having two (meth)acrylate groups and 1 having a molecular weight Mw of no more than 500 Dalton, as component B; c) 0 to 25% by weight of at least one monomer having at least three (meth)acrylate groups and having a molecular weight Mw of no more than 600 Dalton, as component C; and d) 1.00 to 30.00% by weight of at least one polymer having at least two (meth)acrylate groups and having a molecular weight Mw of at least 700 Dalton, as component D; with the proviso that the amount of components A+B is at least 50% by weight, as well as the use of these compositions as printing inks, in particular inkjet printing inks.
Abstract:
A curable composition comprises a) at least one epoxide compound E having at least two epoxide groups; b) at least one amine A having at least two amine hydrogens; and c) at least one acrylic ester U; wherein the epoxide compound E comprises at least one epoxide compound E′, the amine A comprises at least one amine A′, and the acrylic ester U comprises at least one acrylic ester U′ whose Hansen solubility parameters for the dipole forces δp and for the specific interactions δh satisfy the following conditions: √{square root over ((δp(U′)−δp(E′))2+(δh(U′)−δh(E′))2)}≥1.5 and √{square root over ((δp(U′)2−δh(U′)2))}−√{square root over ((δp(A′)2+δh(A′)2))}≥0. A suitable choice of the Hansen solubility parameters of the constituents ensures that the acrylic ester is incorporated covalently into the curing material, preventing subsequent evaporation of the diluent.
Abstract:
The invention relates to a process for preparing heonone (meth)acrylate by transesterification of alkyl (meth)acrylate with heonone, which comprises the steps: (i) reaction of alkyl (meth)acrylate with heonone in the presence of a catalyst comprising titanium(IV) or zirconium(IV) and a stabilizer in the presence of an entrainer which forms an azeotrope with the alcohol bound in the alkyl (meth)acrylate, (ii) continuous removal by distillation of the azeotrope of entrainer and alcohol, with steps (i) and (ii) being carried out simultaneously until heonone has been essentially completely reacted, (iii) addition of water to the product mixture comprising heonone (meth)acrylate obtained in steps (i) and (ii) and removal of the hydrolyzate of the catalyst comprising titanium(IV) or zirconium(IV) by filtration, (iv) distillation of unreacted alkyl (meth)acrylate and entrainer from the product mixture, (v) distillation of water from the product mixture, with step (iv) also being able to be carried out before step (iii) and steps (iv) and (v) also being able to be carried out in a distillation step, wherein steps (i) and (ii) are carried out in the presence of an inorganic or organic acid.