ACRYLATE-BASED MONOMERS FOR USE AS REACTIVE DILUENTS IN PRINTING FORMULATIONS

    公开(公告)号:US20200377746A1

    公开(公告)日:2020-12-03

    申请号:US16484914

    申请日:2018-02-09

    Applicant: BASF SE

    Abstract: The invention relates to compositions, comprising a) 1.00 to 65.00% by weight of at least one compound of formula (I), wherein R1, R2 are each independently H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; R3, R4, R5 are each independently H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; R6 is H or C1-C6-alkyl; k is 1, 2, 3, 4 or 5, as component A; b) 1.00 to 60.00% by weight of at least one monomer having two (meth)acrylate groups and 1 having a molecular weight Mw of no more than 500 Dalton, as component B; c) 0 to 25% by weight of at least one monomer having at least three (meth)acrylate groups and having a molecular weight Mw of no more than 600 Dalton, as component C; and d) 1.00 to 30.00% by weight of at least one polymer having at least two (meth)acrylate groups and having a molecular weight Mw of at least 700 Dalton, as component D; with the proviso that the amount of components A+B is at least 50% by weight, as well as the use of these compositions as printing inks, in particular inkjet printing inks.

    CURABLE COMPOSITIONS
    18.
    发明申请

    公开(公告)号:US20180201722A1

    公开(公告)日:2018-07-19

    申请号:US15742675

    申请日:2016-06-22

    Applicant: BASF SE

    Abstract: A curable composition comprises a) at least one epoxide compound E having at least two epoxide groups; b) at least one amine A having at least two amine hydrogens; and c) at least one acrylic ester U; wherein the epoxide compound E comprises at least one epoxide compound E′, the amine A comprises at least one amine A′, and the acrylic ester U comprises at least one acrylic ester U′ whose Hansen solubility parameters for the dipole forces δp and for the specific interactions δh satisfy the following conditions: √{square root over ((δp(U′)−δp(E′))2+(δh(U′)−δh(E′))2)}≥1.5 and √{square root over ((δp(U′)2−δh(U′)2))}−√{square root over ((δp(A′)2+δh(A′)2))}≥0. A suitable choice of the Hansen solubility parameters of the constituents ensures that the acrylic ester is incorporated covalently into the curing material, preventing subsequent evaporation of the diluent.

    PROCESS FOR PREPARING HEONONE (METH)ACRYLATE
    19.
    发明申请
    PROCESS FOR PREPARING HEONONE (METH)ACRYLATE 有权
    制备丙烯酸(甲基)丙烯酸酯的方法

    公开(公告)号:US20160152580A1

    公开(公告)日:2016-06-02

    申请号:US14953854

    申请日:2015-11-30

    Applicant: BASF SE

    CPC classification number: C07D263/22 C07D263/38

    Abstract: The invention relates to a process for preparing heonone (meth)acrylate by transesterification of alkyl (meth)acrylate with heonone, which comprises the steps: (i) reaction of alkyl (meth)acrylate with heonone in the presence of a catalyst comprising titanium(IV) or zirconium(IV) and a stabilizer in the presence of an entrainer which forms an azeotrope with the alcohol bound in the alkyl (meth)acrylate, (ii) continuous removal by distillation of the azeotrope of entrainer and alcohol, with steps (i) and (ii) being carried out simultaneously until heonone has been essentially completely reacted, (iii) addition of water to the product mixture comprising heonone (meth)acrylate obtained in steps (i) and (ii) and removal of the hydrolyzate of the catalyst comprising titanium(IV) or zirconium(IV) by filtration, (iv) distillation of unreacted alkyl (meth)acrylate and entrainer from the product mixture, (v) distillation of water from the product mixture, with step (iv) also being able to be carried out before step (iii) and steps (iv) and (v) also being able to be carried out in a distillation step, wherein steps (i) and (ii) are carried out in the presence of an inorganic or organic acid.

    Abstract translation: 本发明涉及一种通过(甲基)丙烯酸烷基酯与保护剂的酯交换制备苯乙烯(甲基)丙烯酸酯的方法,该方法包括以下步骤:(i)(甲基)丙烯酸烷基酯与保护剂在含钛的催化剂 IV)或锆(IV)和稳定剂,其在与(甲基)丙烯酸烷基酯中结合的醇形成共沸物的夹带剂存在下,(ii)通过蒸馏除去夹带剂和醇的共沸物, i)和(ii)同时进行直到恒酮基本上完全反应,(iii)向包含在步骤(i)和(ii)中获得的(甲基)丙烯酸氢醌的产物混合物中加入水,并除去水解产物 催化剂通过过滤包括钛(IV)或锆(IV),(iv)从产物混合物中蒸馏未反应的(甲基)丙烯酸烷基酯和夹带剂,(v)从产物混合物中蒸馏水,与步骤(iv) 能够成为 在步骤(iii)之前进行,步骤(iv)和(v)也可以在蒸馏步骤中进行,其中步骤(i)和(ii)在无机或有机酸的存在下进行。

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