12.
    发明专利
    未知

    公开(公告)号:BRPI0707139A2

    公开(公告)日:2011-04-19

    申请号:BRPI0707139

    申请日:2007-01-12

    Applicant: BASF SE

    Abstract: The invention provides a process for the simultaneous preparation of 4,4′-diphenylmethanediamine and also diphenylmethane diisocyanate and polyphenylenepolymethylene polyisocyanates, which comprises the steps a) preparation of a mixture of diphenylmethanediamine and polyphenylenepolymethylenepolyamines by acid condensation of aniline and formaldehyde and subsequent work-up of the mixture, b) splitting-off of part of the mixture prepared in step a), c) distillation of the mixture separated off in step b) in a column, d) recirculation of the bottom product from step c) to the end product from step a) and condensation of the overhead product from step c), e) distillation of the overhead product from step c) in a column, f) recirculation of the overhead product from step e) to the end product from step a), g) isolation of the 4,4′-diphenylmethanediamine obtained as bottom product in step e), h) reaction of the mixture from step a) with phosgene and subsequent work-up of the reaction product.

    Procedimiento para la preparación de isocianatos

    公开(公告)号:ES2753382T3

    公开(公告)日:2020-04-08

    申请号:ES05752554

    申请日:2005-05-21

    Applicant: BASF SE

    Abstract: Procedimiento para la preparación de isocianatos mediante reacción de aminas con fosgeno, en el que el flujo de fosgeno, que se alimenta al mezclado de amina y fosgeno, (i) está esencialmente libre de isocianatos y (ii) presenta un contenido en masa de cloruro de hidrógeno inferior al 0,4 % en masa, en el que la cantidad necesaria de HCl en el flujo de producto de partida que contiene fosgeno (11) se facilita mediante adición de HCl en el fosgeno fresco (1) o se ajusta en el flujo de fosgeno reconducido (10) mediante procesamiento en el procesamiento de fosgeno (IX) con consideración de la cantidad alimentada de fosgeno fresco (1).

    16.
    发明专利
    未知

    公开(公告)号:AT488494T

    公开(公告)日:2010-12-15

    申请号:AT03789264

    申请日:2003-12-13

    Applicant: BASF SE

    Abstract: The invention relates to a process for the partial or complete separation of a mixture comprising hydrogen chloride and phosgene, possibly solvents and possibly low boilers and inerts as are typically obtained in the preparation of isocyanates by reaction of amines with phosgene, which comprises firstly carrying out a partial or complete condensation of phosgene, then a distillation or stripping step in a column to remove the hydrogen chloride from the bottom product phosgene and subsequently a scrub of the top product hydrogen chloride by means of the process solvent to absorb the phosgene in the process solvent. An after-purification by means of adsorption on activated carbon or by another suitable method can subsequently be carried out to remove solvent residues.

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